Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length
© 2017 Elsevier Ltd Biobased short aliphatic diols and diethyl carboxylates were enzymatically (co)polymerized in solution at mild temperature using the immobilized form of Candida antarctica lipase B (CALB) as biocatalyst. The influence of the monomer structure on the CALB activity was investigated...
Published in: | European Polymer Journal |
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ftccsdartic:oai:HAL:hal-03114434v1 2023-05-15T13:47:30+02:00 Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length Debuissy, Thibaud Pollet, Eric Avérous, Luc Institut de chimie et procédés pour l'énergie, l'environnement et la santé (ICPEES) Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE) Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) 2017 https://hal.archives-ouvertes.fr/hal-03114434 https://doi.org/10.1016/j.eurpolymj.2017.10.028 en eng HAL CCSD Elsevier info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2017.10.028 hal-03114434 https://hal.archives-ouvertes.fr/hal-03114434 doi:10.1016/j.eurpolymj.2017.10.028 ISSN: 0014-3057 EISSN: 1873-1945 European Polymer Journal https://hal.archives-ouvertes.fr/hal-03114434 European Polymer Journal, Elsevier, 2017, 97, ⟨10.1016/j.eurpolymj.2017.10.028⟩ [CHIM.POLY]Chemical Sciences/Polymers info:eu-repo/semantics/article Journal articles 2017 ftccsdartic https://doi.org/10.1016/j.eurpolymj.2017.10.028 2021-12-12T00:50:38Z © 2017 Elsevier Ltd Biobased short aliphatic diols and diethyl carboxylates were enzymatically (co)polymerized in solution at mild temperature using the immobilized form of Candida antarctica lipase B (CALB) as biocatalyst. The influence of the monomer structure on the CALB activity was investigated. CALB showed a better affinity for 1,4-butanediol compared to 1,3-propanediol (1,3-PDO), whereas no preference was observed between diethyl succinate and diethyl adipate. In addition, two series of random copolyesters [poly(butylene succinate-ran-butylene adipate) (PBSA) and poly(propylene succinate-ran-butylene succinate) (PPBS)] were synthesized at different compositions to investigate the effect of the composition on copolyesters, which were fully characterized by various chemical and physico-chemical techniques including NMR, SEC, WAXS, DSC and TGA. Their compositions were similar to the feed ones, despite the activity difference of the monomers towards CALB. Nevertheless, this activity difference resulted in the decrease of the M w of PPBS from 24 to 11 kg/mol for 1,3-PDO content varying from 0 to 100 mol.%. Moreover, 1,3-PDO induced an increase of T g and a decrease of the crystallization rate until having an amorphous behavior for high 1,3-PDO content. On the other side, the reduction of the diethyl carboxylate chain length from diethyl adipate to diethyl succinate did not induce a clear tendency with M n varying from 22 to 12 kg/mol with the succinate content. Furthermore, T g increased with the succinate content and the good thermal stability of copolyesters were dependent on the diethyl carboxylates composition. Finally, both copolyesters exhibited an isodimorphic co-crystallization behavior. Article in Journal/Newspaper Antarc* Antarctica Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) European Polymer Journal 97 328 337 |
institution |
Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
[CHIM.POLY]Chemical Sciences/Polymers |
spellingShingle |
[CHIM.POLY]Chemical Sciences/Polymers Debuissy, Thibaud Pollet, Eric Avérous, Luc Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length |
topic_facet |
[CHIM.POLY]Chemical Sciences/Polymers |
description |
© 2017 Elsevier Ltd Biobased short aliphatic diols and diethyl carboxylates were enzymatically (co)polymerized in solution at mild temperature using the immobilized form of Candida antarctica lipase B (CALB) as biocatalyst. The influence of the monomer structure on the CALB activity was investigated. CALB showed a better affinity for 1,4-butanediol compared to 1,3-propanediol (1,3-PDO), whereas no preference was observed between diethyl succinate and diethyl adipate. In addition, two series of random copolyesters [poly(butylene succinate-ran-butylene adipate) (PBSA) and poly(propylene succinate-ran-butylene succinate) (PPBS)] were synthesized at different compositions to investigate the effect of the composition on copolyesters, which were fully characterized by various chemical and physico-chemical techniques including NMR, SEC, WAXS, DSC and TGA. Their compositions were similar to the feed ones, despite the activity difference of the monomers towards CALB. Nevertheless, this activity difference resulted in the decrease of the M w of PPBS from 24 to 11 kg/mol for 1,3-PDO content varying from 0 to 100 mol.%. Moreover, 1,3-PDO induced an increase of T g and a decrease of the crystallization rate until having an amorphous behavior for high 1,3-PDO content. On the other side, the reduction of the diethyl carboxylate chain length from diethyl adipate to diethyl succinate did not induce a clear tendency with M n varying from 22 to 12 kg/mol with the succinate content. Furthermore, T g increased with the succinate content and the good thermal stability of copolyesters were dependent on the diethyl carboxylates composition. Finally, both copolyesters exhibited an isodimorphic co-crystallization behavior. |
author2 |
Institut de chimie et procédés pour l'énergie, l'environnement et la santé (ICPEES) Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE) Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) |
format |
Article in Journal/Newspaper |
author |
Debuissy, Thibaud Pollet, Eric Avérous, Luc |
author_facet |
Debuissy, Thibaud Pollet, Eric Avérous, Luc |
author_sort |
Debuissy, Thibaud |
title |
Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length |
title_short |
Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length |
title_full |
Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length |
title_fullStr |
Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length |
title_full_unstemmed |
Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length |
title_sort |
lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. effect of the monomer length |
publisher |
HAL CCSD |
publishDate |
2017 |
url |
https://hal.archives-ouvertes.fr/hal-03114434 https://doi.org/10.1016/j.eurpolymj.2017.10.028 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
ISSN: 0014-3057 EISSN: 1873-1945 European Polymer Journal https://hal.archives-ouvertes.fr/hal-03114434 European Polymer Journal, Elsevier, 2017, 97, ⟨10.1016/j.eurpolymj.2017.10.028⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2017.10.028 hal-03114434 https://hal.archives-ouvertes.fr/hal-03114434 doi:10.1016/j.eurpolymj.2017.10.028 |
op_doi |
https://doi.org/10.1016/j.eurpolymj.2017.10.028 |
container_title |
European Polymer Journal |
container_volume |
97 |
container_start_page |
328 |
op_container_end_page |
337 |
_version_ |
1766247238826196992 |