Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents
Different (co)polyesters, poly(1,4-butylene succinate-ran-2,3-butylene succinate) (PBB'S), were enzymatically copolymerized at different 1,4-butanediol (1,4-BDO)/2,3-butanediol (2,3-BDO) molar ratios, with immobilized Candida antarctica lipase B (CALB). The synthesized macromolecular architectu...
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ftccsdartic:oai:HAL:hal-03112136v1 2023-05-15T13:47:30+02:00 Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents Debuissy, Thibaud Pollet, Eric Avérous, Luc Laboratoire des Matériaux, Surfaces et Procédés pour la Catalyse (LMSPC) Institut de chimie et procédés pour l'énergie, l'environnement et la santé (ICPEES) Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE) Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE) Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) 2017 https://hal.archives-ouvertes.fr/hal-03112136 https://doi.org/10.1016/j.eurpolymj.2017.04.045 en eng HAL CCSD Elsevier info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2017.04.045 hal-03112136 https://hal.archives-ouvertes.fr/hal-03112136 doi:10.1016/j.eurpolymj.2017.04.045 ISSN: 0014-3057 EISSN: 1873-1945 European Polymer Journal https://hal.archives-ouvertes.fr/hal-03112136 European Polymer Journal, Elsevier, 2017, ⟨10.1016/j.eurpolymj.2017.04.045⟩ ///C:/Users/averous/Documents/Mendeley Desktop//Debuissy, Pollet, Avérous - 2017 - Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters.pdf [CHIM.POLY]Chemical Sciences/Polymers info:eu-repo/semantics/article Journal articles 2017 ftccsdartic https://doi.org/10.1016/j.eurpolymj.2017.04.045 2021-12-12T00:50:56Z Different (co)polyesters, poly(1,4-butylene succinate-ran-2,3-butylene succinate) (PBB'S), were enzymatically copolymerized at different 1,4-butanediol (1,4-BDO)/2,3-butanediol (2,3-BDO) molar ratios, with immobilized Candida antarctica lipase B (CALB). The synthesized macromolecular architectures were characterized by NMR, SEC, FTIR, WAXS, MALDI-TOF MS, DSC, TGA and specific optical rotation. Based on an optimized process, PBB'S copolyesters were synthesized in high yield. A random distribution between both BDOs was obtained along the chain. Mw‾ decreased with increasing 2,3-BDO content, from 26 to 6 kg/mol. The specific optical rotation decreased linearly with decreasing 2,3-BDO content, and can be used as a characterization technique to determine PBB'S composition. DSC results showed that an increase in 2,3-BDO content raised the Tg and reduced the degree of crystallinity, leading to amorphous materials for 2,3-BDO content higher than 47 mol.%. Synthesized copolyesters exhibited a good thermal stability, higher than 250 °C, with a degradation profile depending on the 1,4-BDO/2,3-BDO ratio. Article in Journal/Newspaper Antarc* Antarctica Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) European Polymer Journal 93 103 115 |
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Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
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ftccsdartic |
language |
English |
topic |
[CHIM.POLY]Chemical Sciences/Polymers |
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[CHIM.POLY]Chemical Sciences/Polymers Debuissy, Thibaud Pollet, Eric Avérous, Luc Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents |
topic_facet |
[CHIM.POLY]Chemical Sciences/Polymers |
description |
Different (co)polyesters, poly(1,4-butylene succinate-ran-2,3-butylene succinate) (PBB'S), were enzymatically copolymerized at different 1,4-butanediol (1,4-BDO)/2,3-butanediol (2,3-BDO) molar ratios, with immobilized Candida antarctica lipase B (CALB). The synthesized macromolecular architectures were characterized by NMR, SEC, FTIR, WAXS, MALDI-TOF MS, DSC, TGA and specific optical rotation. Based on an optimized process, PBB'S copolyesters were synthesized in high yield. A random distribution between both BDOs was obtained along the chain. Mw‾ decreased with increasing 2,3-BDO content, from 26 to 6 kg/mol. The specific optical rotation decreased linearly with decreasing 2,3-BDO content, and can be used as a characterization technique to determine PBB'S composition. DSC results showed that an increase in 2,3-BDO content raised the Tg and reduced the degree of crystallinity, leading to amorphous materials for 2,3-BDO content higher than 47 mol.%. Synthesized copolyesters exhibited a good thermal stability, higher than 250 °C, with a degradation profile depending on the 1,4-BDO/2,3-BDO ratio. |
author2 |
Laboratoire des Matériaux, Surfaces et Procédés pour la Catalyse (LMSPC) Institut de chimie et procédés pour l'énergie, l'environnement et la santé (ICPEES) Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE) Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE) Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) |
format |
Article in Journal/Newspaper |
author |
Debuissy, Thibaud Pollet, Eric Avérous, Luc |
author_facet |
Debuissy, Thibaud Pollet, Eric Avérous, Luc |
author_sort |
Debuissy, Thibaud |
title |
Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents |
title_short |
Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents |
title_full |
Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents |
title_fullStr |
Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents |
title_full_unstemmed |
Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. Influence of 1,4- and 2,3-butanediol contents |
title_sort |
enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters and characterization. influence of 1,4- and 2,3-butanediol contents |
publisher |
HAL CCSD |
publishDate |
2017 |
url |
https://hal.archives-ouvertes.fr/hal-03112136 https://doi.org/10.1016/j.eurpolymj.2017.04.045 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
ISSN: 0014-3057 EISSN: 1873-1945 European Polymer Journal https://hal.archives-ouvertes.fr/hal-03112136 European Polymer Journal, Elsevier, 2017, ⟨10.1016/j.eurpolymj.2017.04.045⟩ ///C:/Users/averous/Documents/Mendeley Desktop//Debuissy, Pollet, Avérous - 2017 - Enzymatic synthesis of biobased poly(1,4-butylene succinate-ran-2,3-butylene succinate) copolyesters.pdf |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2017.04.045 hal-03112136 https://hal.archives-ouvertes.fr/hal-03112136 doi:10.1016/j.eurpolymj.2017.04.045 |
op_doi |
https://doi.org/10.1016/j.eurpolymj.2017.04.045 |
container_title |
European Polymer Journal |
container_volume |
93 |
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103 |
op_container_end_page |
115 |
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1766247239785644032 |