Water soluble dicarboxylic acids and related compounds in Antarctic aerosols
International audience Antarctic aerosols collected at Syowa Station were studied for water soluble organic compounds by employing a water extraction and dibutyl ester derivatization and using a capillary gas chromatography (GC) and GC/mass spectrometry (GC/MS). Total carbon and nitrogen were also d...
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ftccsdartic:oai:HAL:hal-02053057v1 2023-05-15T13:45:04+02:00 Water soluble dicarboxylic acids and related compounds in Antarctic aerosols Kawamura, Kimitaka SEMPERE, Richard Imai, Yoshie Fujii, Yoshiyuki Hayashi, Masahiko Institute of Low-Temperature Science Hokkaido University Sapporo, Japan Institut méditerranéen d'océanologie (MIO) Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Toulon (UTLN) National Institute of Polar Research Tokyo (NiPR) Department of Earth System Science and Technology Fukuoka (ESST) Kyushu University Fukuoka 1996-08-20 https://hal-amu.archives-ouvertes.fr/hal-02053057 https://hal-amu.archives-ouvertes.fr/hal-02053057/document https://hal-amu.archives-ouvertes.fr/hal-02053057/file/ark%20_67375_WNG-65FT96KD-C.pdf https://doi.org/10.1029/96JD01541 en eng HAL CCSD American Geophysical Union info:eu-repo/semantics/altIdentifier/doi/10.1029/96JD01541 hal-02053057 https://hal-amu.archives-ouvertes.fr/hal-02053057 https://hal-amu.archives-ouvertes.fr/hal-02053057/document https://hal-amu.archives-ouvertes.fr/hal-02053057/file/ark%20_67375_WNG-65FT96KD-C.pdf doi:10.1029/96JD01541 info:eu-repo/semantics/OpenAccess ISSN: 2169-897X EISSN: 2169-8996 Journal of Geophysical Research: Atmospheres https://hal-amu.archives-ouvertes.fr/hal-02053057 Journal of Geophysical Research: Atmospheres, American Geophysical Union, 1996, 101 (D13), pp.18721-18728. ⟨10.1029/96JD01541⟩ [SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere info:eu-repo/semantics/article Journal articles 1996 ftccsdartic https://doi.org/10.1029/96JD01541 2021-10-24T00:01:35Z International audience Antarctic aerosols collected at Syowa Station were studied for water soluble organic compounds by employing a water extraction and dibutyl ester derivatization and using a capillary gas chromatography (GC) and GC/mass spectrometry (GC/MS). Total carbon and nitrogen were also determined. A homologous series of c•,o•-dicarboxylic acids (C2-Cll), 0./-oxoc&rboxylic &cids (C2-C9), and c•dicarbonyls (C2-C3) were detected, as well as pyruvic acid and aromatic (phthalic) diecid. Succinic (C4) or oxalic (C2) acid was found to be the dominant diecid species, followed by azelaic (C9), adipic (C6), or malonic (C3) acid. Concentration range of the total diacids was 5.9-88 ng m-3, with an average of 29 ng m-3. Highest concentrations were observed in the summer sample with a predominance of succinic acid (61.5 ng m-3), which comprised approximately 70% of the total diacids and accounted for 3.5% of total aerosol carbon (1020 ng m-3). The succinic acid (C4) is likely produced by photooxidation of 4-oxocarboxylic acids, which are present in the atmosphere as intermediates of the photooxidation of unsaturated fatty acids. These results indicate that the Antarctic organic aerosols originate from marine-derived lipids and are transformed largely by photochemical oxidations. c•-Oxocarboxylic acids (C2-C9, 0.36-3.0 ng m-3) also showed the highest concentration in the summer sample, again suggesting a secondary production in the atmosphere of the Antarctic and in the Southern Ocean. Article in Journal/Newspaper Antarc* Antarctic Southern Ocean Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Antarctic Southern Ocean Syowa Station The Antarctic Journal of Geophysical Research: Atmospheres 101 D13 18721 18728 |
institution |
Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere |
spellingShingle |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere Kawamura, Kimitaka SEMPERE, Richard Imai, Yoshie Fujii, Yoshiyuki Hayashi, Masahiko Water soluble dicarboxylic acids and related compounds in Antarctic aerosols |
topic_facet |
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere |
description |
International audience Antarctic aerosols collected at Syowa Station were studied for water soluble organic compounds by employing a water extraction and dibutyl ester derivatization and using a capillary gas chromatography (GC) and GC/mass spectrometry (GC/MS). Total carbon and nitrogen were also determined. A homologous series of c•,o•-dicarboxylic acids (C2-Cll), 0./-oxoc&rboxylic &cids (C2-C9), and c•dicarbonyls (C2-C3) were detected, as well as pyruvic acid and aromatic (phthalic) diecid. Succinic (C4) or oxalic (C2) acid was found to be the dominant diecid species, followed by azelaic (C9), adipic (C6), or malonic (C3) acid. Concentration range of the total diacids was 5.9-88 ng m-3, with an average of 29 ng m-3. Highest concentrations were observed in the summer sample with a predominance of succinic acid (61.5 ng m-3), which comprised approximately 70% of the total diacids and accounted for 3.5% of total aerosol carbon (1020 ng m-3). The succinic acid (C4) is likely produced by photooxidation of 4-oxocarboxylic acids, which are present in the atmosphere as intermediates of the photooxidation of unsaturated fatty acids. These results indicate that the Antarctic organic aerosols originate from marine-derived lipids and are transformed largely by photochemical oxidations. c•-Oxocarboxylic acids (C2-C9, 0.36-3.0 ng m-3) also showed the highest concentration in the summer sample, again suggesting a secondary production in the atmosphere of the Antarctic and in the Southern Ocean. |
author2 |
Institute of Low-Temperature Science Hokkaido University Sapporo, Japan Institut méditerranéen d'océanologie (MIO) Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Toulon (UTLN) National Institute of Polar Research Tokyo (NiPR) Department of Earth System Science and Technology Fukuoka (ESST) Kyushu University Fukuoka |
format |
Article in Journal/Newspaper |
author |
Kawamura, Kimitaka SEMPERE, Richard Imai, Yoshie Fujii, Yoshiyuki Hayashi, Masahiko |
author_facet |
Kawamura, Kimitaka SEMPERE, Richard Imai, Yoshie Fujii, Yoshiyuki Hayashi, Masahiko |
author_sort |
Kawamura, Kimitaka |
title |
Water soluble dicarboxylic acids and related compounds in Antarctic aerosols |
title_short |
Water soluble dicarboxylic acids and related compounds in Antarctic aerosols |
title_full |
Water soluble dicarboxylic acids and related compounds in Antarctic aerosols |
title_fullStr |
Water soluble dicarboxylic acids and related compounds in Antarctic aerosols |
title_full_unstemmed |
Water soluble dicarboxylic acids and related compounds in Antarctic aerosols |
title_sort |
water soluble dicarboxylic acids and related compounds in antarctic aerosols |
publisher |
HAL CCSD |
publishDate |
1996 |
url |
https://hal-amu.archives-ouvertes.fr/hal-02053057 https://hal-amu.archives-ouvertes.fr/hal-02053057/document https://hal-amu.archives-ouvertes.fr/hal-02053057/file/ark%20_67375_WNG-65FT96KD-C.pdf https://doi.org/10.1029/96JD01541 |
geographic |
Antarctic Southern Ocean Syowa Station The Antarctic |
geographic_facet |
Antarctic Southern Ocean Syowa Station The Antarctic |
genre |
Antarc* Antarctic Southern Ocean |
genre_facet |
Antarc* Antarctic Southern Ocean |
op_source |
ISSN: 2169-897X EISSN: 2169-8996 Journal of Geophysical Research: Atmospheres https://hal-amu.archives-ouvertes.fr/hal-02053057 Journal of Geophysical Research: Atmospheres, American Geophysical Union, 1996, 101 (D13), pp.18721-18728. ⟨10.1029/96JD01541⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1029/96JD01541 hal-02053057 https://hal-amu.archives-ouvertes.fr/hal-02053057 https://hal-amu.archives-ouvertes.fr/hal-02053057/document https://hal-amu.archives-ouvertes.fr/hal-02053057/file/ark%20_67375_WNG-65FT96KD-C.pdf doi:10.1029/96JD01541 |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1029/96JD01541 |
container_title |
Journal of Geophysical Research: Atmospheres |
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101 |
container_issue |
D13 |
container_start_page |
18721 |
op_container_end_page |
18728 |
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1766212457492119552 |