Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer
International audience The design of omega-amino-alpha-alkoxy-acetate as monomer enables to dramatically speed up the formation of polyamides catalyzed by the supported lipase B of Candida antarctica. Only 30 min are needed to reach 93% conversion whereas 240 h are necessary to observe the same leve...
Published in: | Polymer |
---|---|
Main Authors: | , , , , |
Other Authors: | , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
HAL CCSD
2013
|
Subjects: | |
Online Access: | https://hal-amu.archives-ouvertes.fr/hal-01460472 https://doi.org/10.1016/j.polymer.2013.05.011 |
id |
ftccsdartic:oai:HAL:hal-01460472v1 |
---|---|
record_format |
openpolar |
spelling |
ftccsdartic:oai:HAL:hal-01460472v1 2023-05-15T14:04:23+02:00 Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer Poulhès, Florent Mouysset, Dominique Gil, Gérard Bertrand, Michèle P. Gastaldi, Stéphane Institut de Chimie Radicalaire (ICR) Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) Institut des Sciences Moléculaires de Marseille (ISM2) Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Institut de Chimie du CNRS (INC) 2013-06 https://hal-amu.archives-ouvertes.fr/hal-01460472 https://doi.org/10.1016/j.polymer.2013.05.011 en eng HAL CCSD Elsevier info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2013.05.011 hal-01460472 https://hal-amu.archives-ouvertes.fr/hal-01460472 doi:10.1016/j.polymer.2013.05.011 ISSN: 0032-3861 Polymer https://hal-amu.archives-ouvertes.fr/hal-01460472 Polymer, Elsevier, 2013, 54 (14), pp.3467--3471. ⟨10.1016/j.polymer.2013.05.011⟩ [CHIM]Chemical Sciences info:eu-repo/semantics/article Journal articles 2013 ftccsdartic https://doi.org/10.1016/j.polymer.2013.05.011 2021-12-19T02:38:37Z International audience The design of omega-amino-alpha-alkoxy-acetate as monomer enables to dramatically speed up the formation of polyamides catalyzed by the supported lipase B of Candida antarctica. Only 30 min are needed to reach 93% conversion whereas 240 h are necessary to observe the same level of conversion with a monomer devoided of an oxygen atom in position beta relative to the electrophilic carbonyl group. Yields, Mn, Mw, DPn and PDI reach very good values for an enzymatic synthesis of polyamides. (C) 2013 Elsevier Ltd. All rights reserved. Article in Journal/Newspaper Antarc* Antarctica Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Polymer 54 14 3467 3471 |
institution |
Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
[CHIM]Chemical Sciences |
spellingShingle |
[CHIM]Chemical Sciences Poulhès, Florent Mouysset, Dominique Gil, Gérard Bertrand, Michèle P. Gastaldi, Stéphane Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer |
topic_facet |
[CHIM]Chemical Sciences |
description |
International audience The design of omega-amino-alpha-alkoxy-acetate as monomer enables to dramatically speed up the formation of polyamides catalyzed by the supported lipase B of Candida antarctica. Only 30 min are needed to reach 93% conversion whereas 240 h are necessary to observe the same level of conversion with a monomer devoided of an oxygen atom in position beta relative to the electrophilic carbonyl group. Yields, Mn, Mw, DPn and PDI reach very good values for an enzymatic synthesis of polyamides. (C) 2013 Elsevier Ltd. All rights reserved. |
author2 |
Institut de Chimie Radicalaire (ICR) Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) Institut des Sciences Moléculaires de Marseille (ISM2) Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS)-École Centrale de Marseille (ECM)-Institut de Chimie du CNRS (INC) |
format |
Article in Journal/Newspaper |
author |
Poulhès, Florent Mouysset, Dominique Gil, Gérard Bertrand, Michèle P. Gastaldi, Stéphane |
author_facet |
Poulhès, Florent Mouysset, Dominique Gil, Gérard Bertrand, Michèle P. Gastaldi, Stéphane |
author_sort |
Poulhès, Florent |
title |
Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer |
title_short |
Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer |
title_full |
Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer |
title_fullStr |
Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer |
title_full_unstemmed |
Speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer |
title_sort |
speeding-up enzyme-catalyzed synthesis of polyamides using omega-amino-alpha-alkoxy-acetate as monomer |
publisher |
HAL CCSD |
publishDate |
2013 |
url |
https://hal-amu.archives-ouvertes.fr/hal-01460472 https://doi.org/10.1016/j.polymer.2013.05.011 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
ISSN: 0032-3861 Polymer https://hal-amu.archives-ouvertes.fr/hal-01460472 Polymer, Elsevier, 2013, 54 (14), pp.3467--3471. ⟨10.1016/j.polymer.2013.05.011⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2013.05.011 hal-01460472 https://hal-amu.archives-ouvertes.fr/hal-01460472 doi:10.1016/j.polymer.2013.05.011 |
op_doi |
https://doi.org/10.1016/j.polymer.2013.05.011 |
container_title |
Polymer |
container_volume |
54 |
container_issue |
14 |
container_start_page |
3467 |
op_container_end_page |
3471 |
_version_ |
1766275431027179520 |