Gas-Chromatographic analysis of Mars soil samples with the SAM instrument onboard Curiosity - the 359 first sols
International audience Amongst the SAM suite of instruments, SAM-GC (Gas Chromatograph) is devoted to identify and quantify volatiles evolved from the thermal/chemical treatment of any soil sample collected by the Curiosity rover. The first soil samples analyzed with SAM were composed of windblown d...
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Language: | English |
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HAL CCSD
2014
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Online Access: | https://hal.archives-ouvertes.fr/hal-01111898 |
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ftccsdartic:oai:HAL:hal-01111898v1 |
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Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
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English |
topic |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] |
spellingShingle |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] Szopa, Cyril Navarro-Gonzalez, Rafael Mahaffy, Paul Buch, Arnaud Goutail, Jean-Pierre Cabane, Michel Glavin, Daniel Correia, Jean-Jacques Coll, Patrice Freissinet, Caroline Meftah, Mustapha Coscia, David Teinturier, Samuel Brunner, Anna Bonnet, Jean-Yves Millan, Maeva Gas-Chromatographic analysis of Mars soil samples with the SAM instrument onboard Curiosity - the 359 first sols |
topic_facet |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] |
description |
International audience Amongst the SAM suite of instruments, SAM-GC (Gas Chromatograph) is devoted to identify and quantify volatiles evolved from the thermal/chemical treatment of any soil sample collected by the Curiosity rover. The first soil samples analyzed with SAM were composed of windblown dust and sand collected at the Rocknest site, while the second site analyzed was a basin called “Yellowknife Bay” where two holes were drilled (John Klein & Cumberland) and analysis showed these sites to be a fluvio-lacustrine sediment. For their analysis, these samples were subjected to a pyrolysis at temperatures reaching about 850°C. For SAM-GC and GCMS analyses, different fractions of pyrolysates were collected at different temperature in the ambient-900°C range in order to discriminate potential different volatile fractions present in the solid sample. With the aim to search for potential organic molecules outgassed from the samples, a SAM-GC analytical channel composed of a thermal-desorption injector and a MXT-CLP chromatographic column was used as it was designed for the separation of a wide range of volatile organic molecules. This channel is also equipped with a thermal conductivity detector (TCD) capable to detect the most abundant species (with abundances down to approximately 10-10mol). His channel is thus complementary to the mass spectrometer detection for quantification of such species, as this last instrument does not have linear response in this domain of high abundance, whereas it is significantly more sensitive than the TCD. The results obtained with this instrument first show that the performances of SAM-GC is representative of those obtained during calibrations of the instrument in laboratory, and also that results are repeatable. Hence, the instrument performs nominally, making it the first GCMS running successfully on Mars since the Viking missions (middle of the 70’s). Moreover, the complementarity of GC towards MS is also shown, both by allowing the quantification of the major species ... |
author2 |
PLANETO - LATMOS Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) Laboratorio de Química de Plasmas y Estudios Planetarios Mexico Instituto de Ciencias Nucleares Mexico Universidad Nacional Autónoma de México (UNAM)-Universidad Nacional Autónoma de México (UNAM) NASA Goddard Space Flight Center (GSFC) Laboratoire de Génie des Procédés et Matériaux - EA 4038 (LGPM) CentraleSupélec Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA (UMR_7583)) Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS) |
format |
Conference Object |
author |
Szopa, Cyril Navarro-Gonzalez, Rafael Mahaffy, Paul Buch, Arnaud Goutail, Jean-Pierre Cabane, Michel Glavin, Daniel Correia, Jean-Jacques Coll, Patrice Freissinet, Caroline Meftah, Mustapha Coscia, David Teinturier, Samuel Brunner, Anna Bonnet, Jean-Yves Millan, Maeva |
author_facet |
Szopa, Cyril Navarro-Gonzalez, Rafael Mahaffy, Paul Buch, Arnaud Goutail, Jean-Pierre Cabane, Michel Glavin, Daniel Correia, Jean-Jacques Coll, Patrice Freissinet, Caroline Meftah, Mustapha Coscia, David Teinturier, Samuel Brunner, Anna Bonnet, Jean-Yves Millan, Maeva |
author_sort |
Szopa, Cyril |
title |
Gas-Chromatographic analysis of Mars soil samples with the SAM instrument onboard Curiosity - the 359 first sols |
title_short |
Gas-Chromatographic analysis of Mars soil samples with the SAM instrument onboard Curiosity - the 359 first sols |
title_full |
Gas-Chromatographic analysis of Mars soil samples with the SAM instrument onboard Curiosity - the 359 first sols |
title_fullStr |
Gas-Chromatographic analysis of Mars soil samples with the SAM instrument onboard Curiosity - the 359 first sols |
title_full_unstemmed |
Gas-Chromatographic analysis of Mars soil samples with the SAM instrument onboard Curiosity - the 359 first sols |
title_sort |
gas-chromatographic analysis of mars soil samples with the sam instrument onboard curiosity - the 359 first sols |
publisher |
HAL CCSD |
publishDate |
2014 |
url |
https://hal.archives-ouvertes.fr/hal-01111898 |
op_coverage |
Moscow, Russia |
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ENVELOPE(-114.336,-114.336,62.367,62.367) |
geographic |
Yellowknife Yellowknife Bay |
geographic_facet |
Yellowknife Yellowknife Bay |
genre |
Yellowknife |
genre_facet |
Yellowknife |
op_source |
40th COSPAR Scientific Assembly https://hal.archives-ouvertes.fr/hal-01111898 40th COSPAR Scientific Assembly, Aug 2014, Moscow, Russia. pp.Abstract B0.2-13-14 |
op_relation |
hal-01111898 https://hal.archives-ouvertes.fr/hal-01111898 BIBCODE: 2014cosp.40E3260S |
_version_ |
1766236881173872640 |
spelling |
ftccsdartic:oai:HAL:hal-01111898v1 2023-05-15T18:45:44+02:00 Gas-Chromatographic analysis of Mars soil samples with the SAM instrument onboard Curiosity - the 359 first sols Szopa, Cyril Navarro-Gonzalez, Rafael Mahaffy, Paul Buch, Arnaud Goutail, Jean-Pierre Cabane, Michel Glavin, Daniel Correia, Jean-Jacques Coll, Patrice Freissinet, Caroline Meftah, Mustapha Coscia, David Teinturier, Samuel Brunner, Anna Bonnet, Jean-Yves Millan, Maeva PLANETO - LATMOS Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) Laboratorio de Química de Plasmas y Estudios Planetarios Mexico Instituto de Ciencias Nucleares Mexico Universidad Nacional Autónoma de México (UNAM)-Universidad Nacional Autónoma de México (UNAM) NASA Goddard Space Flight Center (GSFC) Laboratoire de Génie des Procédés et Matériaux - EA 4038 (LGPM) CentraleSupélec Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA (UMR_7583)) Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS) Moscow, Russia 2014-08-02 https://hal.archives-ouvertes.fr/hal-01111898 en eng HAL CCSD hal-01111898 https://hal.archives-ouvertes.fr/hal-01111898 BIBCODE: 2014cosp.40E3260S 40th COSPAR Scientific Assembly https://hal.archives-ouvertes.fr/hal-01111898 40th COSPAR Scientific Assembly, Aug 2014, Moscow, Russia. pp.Abstract B0.2-13-14 [PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] info:eu-repo/semantics/conferenceObject Conference papers 2014 ftccsdartic 2021-11-21T03:15:30Z International audience Amongst the SAM suite of instruments, SAM-GC (Gas Chromatograph) is devoted to identify and quantify volatiles evolved from the thermal/chemical treatment of any soil sample collected by the Curiosity rover. The first soil samples analyzed with SAM were composed of windblown dust and sand collected at the Rocknest site, while the second site analyzed was a basin called “Yellowknife Bay” where two holes were drilled (John Klein & Cumberland) and analysis showed these sites to be a fluvio-lacustrine sediment. For their analysis, these samples were subjected to a pyrolysis at temperatures reaching about 850°C. For SAM-GC and GCMS analyses, different fractions of pyrolysates were collected at different temperature in the ambient-900°C range in order to discriminate potential different volatile fractions present in the solid sample. With the aim to search for potential organic molecules outgassed from the samples, a SAM-GC analytical channel composed of a thermal-desorption injector and a MXT-CLP chromatographic column was used as it was designed for the separation of a wide range of volatile organic molecules. This channel is also equipped with a thermal conductivity detector (TCD) capable to detect the most abundant species (with abundances down to approximately 10-10mol). His channel is thus complementary to the mass spectrometer detection for quantification of such species, as this last instrument does not have linear response in this domain of high abundance, whereas it is significantly more sensitive than the TCD. The results obtained with this instrument first show that the performances of SAM-GC is representative of those obtained during calibrations of the instrument in laboratory, and also that results are repeatable. Hence, the instrument performs nominally, making it the first GCMS running successfully on Mars since the Viking missions (middle of the 70’s). Moreover, the complementarity of GC towards MS is also shown, both by allowing the quantification of the major species ... Conference Object Yellowknife Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Yellowknife Yellowknife Bay ENVELOPE(-114.336,-114.336,62.367,62.367) |