What controls the isotopic composition of Greenland surface snow?

• Published in: Climate of the Past
• Main Authors: Steen-Larsen, H.C., Masson-Delmotte, Valérie, Hirabayashi, M., Winkler, R., Satow, K., Prié, F., Bayou, N., Brun, E., Cuffey, K.M., Dahl-Jensen, D., Dumont, M., Guillevic, M., Kipfstuhl, S., Landais, A., Popp, T., Risi, C., Steffen, K., Stenni, B., Sveinbjörnsdottír, A.E.
• Other Authors: Laboratoire des Sciences du Climat et de l'Environnement Gif-sur-Yvette (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado Boulder -National Oceanic and Atmospheric Administration (NOAA), Centre for Ice and Climate Copenhagen, Niels Bohr Institute Copenhagen (NBI), Faculty of Science Copenhagen, University of Copenhagen = Københavns Universitet (KU)-University of Copenhagen = Københavns Universitet (KU)-Faculty of Science Copenhagen, University of Copenhagen = Københavns Universitet (KU)-University of Copenhagen = Københavns Universitet (KU), Glaces et Continents, Climats et Isotopes Stables (GLACCIOS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), National Institute of Polar Research Tokyo (NiPR), Groupe d'étude de l'atmosphère météorologique (CNRM-GAME), Institut national des sciences de l'Univers (INSU - CNRS)-Météo France-Centre National de la Recherche Scientifique (CNRS), Berkeley Atmospheric Sciences Center (BASC), University of California Berkeley, University of California-University of California, Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung (AWI), Laboratoire de Météorologie Dynamique (UMR 8539) (LMD), Département des Géosciences - ENS Paris, École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-École des Ponts ParisTech (ENPC)-École polytechnique (X)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC), Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology Zürich (ETH Zürich), Department of Geological, Environmental and Marine Sciences Trieste, Università degli studi di Trieste, Institute of Earth Sciences Reykjavik, University of Iceland Reykjavik
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2014
• Subjects: [SDU.STU.CL]Sciences of the Universe [physics]/Earth Sciences/Climatology; Greenland; Greenland ice core; ice core
• Online Access: https://hal.archives-ouvertes.fr/hal-01088924; https://hal.archives-ouvertes.fr/hal-01088924/document; https://hal.archives-ouvertes.fr/hal-01088924/file/cp-10-377-2014.pdf; https://doi.org/10.5194/CP-10-377-2014

International audience Water stable isotopes in Greenland ice core data provide key paleoclimatic information, and have been compared with precipitation isotopic composition simulated by isotopically enabled atmospheric models. However, post-depositional processes linked with snow metamorphism remain poorly documented. For this purpose, monitoring of the isotopic composition (d18O, dD) of near-surface water vapor, precipitation and samples of the top (0.5 cm) snow surface has been conducted during two summers (2011-2012) at NEEM, NW Greenland. The samples also include a subset of 17O-excess measurements over 4 days, and the measurements span the 2012 Greenland heat wave. Our observations are consistent with calculations assuming isotopic equilibrium between surface snow and water vapor. We observe a strong correlation between near-surface vapor d18O and air temperature (0.85 ± 0.11‰ °C-1 (R = 0.76) for 2012). The correlation with air temperature is not observed in precipitation data or surface snow data. Deuterium excess (d-excess) is strongly anti-correlated with d18O with a stronger slope for vapor than for precipitation and snow surface data. During nine 1-5-day periods between precipitation events, our data demonstrate parallel changes of d18O and d-excess in surface snow and near-surface vapor. The changes in d18O of the vapor are similar or larger than those of the snow d18O. It is estimated using the CROCUS snow model that 6 to 20% of the surface snow mass is exchanged with the atmosphere. In our data, the sign of surface snow isotopic changes is not related to the sign or magnitude of sublimation or deposition. Comparisons with atmospheric models show that day-to-day variations in near-surface vapor isotopic composition are driven by synoptic variations and changes in air mass trajectories and distillation histories. We suggest that, in between precipitation events, changes in the surface snow isotopic composition are driven by these changes in near-surface vapor isotopic composition. This is ...