Testing our understanding of Arctic denitrification using MIPAS-E satellite measurements in winter 2002/2003

• Main Authors: Davies, S., Mann, G. W., Carslaw, K. S., Chipperfield, M. P., Remedios, J. J., Allen, G., Waterfall, A. M., Spang, R., Toon, G. C.
• Other Authors: Institute for Atmospheric Science Leeds, School of Earth and Environment Leeds (SEE), University of Leeds-University of Leeds, Earth Observation Science Group Leicester (EOS), Space Research Centre Leicester, University of Leicester-University of Leicester, School of Earth, Atmospheric and Environmental Sciences Manchester (SEAES), University of Manchester Manchester, STFC Rutherford Appleton Laboratory (RAL), Science and Technology Facilities Council (STFC), Institut für Energie- und Klimaforschung - Stratosphäre (IEK-7), Forschungszentrum Jülich GmbH, Helmholtz-Gemeinschaft = Helmholtz Association-Helmholtz-Gemeinschaft = Helmholtz Association, Jet Propulsion Laboratory (JPL), NASA-California Institute of Technology (CALTECH)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2006
• Subjects: [SDU.OCEAN]Sciences of the Universe [physics]/Ocean; Atmosphere; Arctic
• Online Access: https://hal.science/hal-00295994; https://hal.science/hal-00295994/document; https://hal.science/hal-00295994/file/acp-6-3149-2006.pdf

International audience Observations of gas-phase HNO 3 and N 2 O in the polar stratosphere from the Michelson Interferometer for Passive Atmospheric Sounding aboard the ENVISAT satellite (MIPAS-E) were made during the cold Arctic winter of 2002/2003. Vortex temperatures were unusually low in early winter and remained favourable for polar stratospheric cloud formation and denitrification until mid-January. MIPAS-E observations provide the first dataset with sufficient coverage of the polar vortex in mid-winter which enables a reasonable estimate of the timing of onset and spatial distribution of denitrification of the Arctic lower stratosphere to be performed. We use the observations from MIPAS-E to test the evolution of denitrification in the DLAPSE (Denitrification by Lagrangian Particle Sedimentation) microphysical denitrification model coupled to the SLIMCAT chemical transport model. In addition, the predicted denitrification from a simple equilibrium nitric acid trihydrate-based scheme is also compared with MIPAS-E. Modelled denitrification is compared with in-vortex NO y and N 2 O observations from the balloon-borne MarkIV interferometer in mid-December. Denitrification was clearly observed by MIPAS-E in mid-December 2002 and reached 80% in the core of the vortex by early January 2003. The DLAPSE model is broadly able to capture both the timing of onset and the spatial distribution of the observed denitrification. A simple thermodynamic equilibrium scheme is able to reproduce the observed denitrification in the core of the vortex but overestimates denitrification closer to the vortex edge. This study also suggests that the onset of denitrification in simple thermodynamic schemes may be earlier than in the MIPAS-E observations.