Ba distribution in surface Southern Ocean sediments and export production estimates
International audience We present excess Ba (Baxs) data (i.e., total Ba corrected for lithogenic Ba) for surface sediments from a north-south transect between the Polar Front Zone and the northern Weddell Gyre in the Atlantic sector and between the Polar Front Zone and the Antarctic continent in the...
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Online Access: | https://hal.archives-ouvertes.fr/hal-00291395 https://doi.org/10.1029/2000PA000552 |
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ftccsdartic:oai:HAL:hal-00291395v1 2023-05-15T13:36:53+02:00 Ba distribution in surface Southern Ocean sediments and export production estimates Fagel, N. Dehairs, F. Andre, L. Bareille, Gilles Monnin, C. Laboratoire de Chimie Analytique Bio-Inorganique et Environnement (LCABIE) Université de Pau et des Pays de l'Adour (UPPA)-Centre National de la Recherche Scientifique (CNRS) Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux (IPREM) Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) 2002 https://hal.archives-ouvertes.fr/hal-00291395 https://doi.org/10.1029/2000PA000552 en eng HAL CCSD American Geophysical Union info:eu-repo/semantics/altIdentifier/doi/10.1029/2000PA000552 hal-00291395 https://hal.archives-ouvertes.fr/hal-00291395 doi:10.1029/2000PA000552 ISSN: 0883-8305 Paleoceanography https://hal.archives-ouvertes.fr/hal-00291395 Paleoceanography, American Geophysical Union, 2002, 17 (2), pp.1-1-1-20 ⟨10.1029/2000PA000552⟩ Southern Ocean Export production Sediment Excess Ba [CHIM.ANAL]Chemical Sciences/Analytical chemistry info:eu-repo/semantics/article Journal articles 2002 ftccsdartic https://doi.org/10.1029/2000PA000552 2021-12-12T06:19:55Z International audience We present excess Ba (Baxs) data (i.e., total Ba corrected for lithogenic Ba) for surface sediments from a north-south transect between the Polar Front Zone and the northern Weddell Gyre in the Atlantic sector and between the Polar Front Zone and the Antarctic continent in the Indian sector. Focus is on two different processes that affect excess Ba accumulation in the sediments: sediment redistribution and excess Ba dissolution. The effect of these processes needs to be corrected for in order to convert accumulation rate into vertical rain rate, the flux component that can be linked to export production. In the Southern Ocean a major process affecting Ba accumulation rate is sediment focusing, which is corrected for using excess 230Th. This correction, however, may not always be straightforward because of boundary scavenging effects. A further major process affecting excess Ba accumulation is barite dissolution during exposure at the sediment-water column interface. Export production estimates derived from excess 230Th and barite dissolution corrected Baxs accumulation rates (i.e., excess Ba vertical rain rates) are of the same magnitude but generally larger than export production estimates based on water column proxies (234Th-deficit in the upper water column; particulate excess Ba enrichment in the mesopelagic water column). We believe export production values based on excess Ba vertical rain rate might be overestimated due to inaccurate assessment of the Baxs preservation rate. Barite dissolution has, in general, been taken into account by relating it to exposure time before burial depending on the rate of sediment accumulation. However, the observed decrease of excess Ba content with increasing water column depth (or increasing hydrostatic pressure) illustrates the dependence of barite preservation on degree of saturation in the deep water column in accordance with available thermodynamic data. Therefore correction for barite dissolution would not be appropriate by considering only ... Article in Journal/Newspaper Antarc* Antarctic Southern Ocean Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Antarctic Southern Ocean The Antarctic Indian Weddell Paleoceanography 17 2 1-1 1-20 |
institution |
Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
Southern Ocean Export production Sediment Excess Ba [CHIM.ANAL]Chemical Sciences/Analytical chemistry |
spellingShingle |
Southern Ocean Export production Sediment Excess Ba [CHIM.ANAL]Chemical Sciences/Analytical chemistry Fagel, N. Dehairs, F. Andre, L. Bareille, Gilles Monnin, C. Ba distribution in surface Southern Ocean sediments and export production estimates |
topic_facet |
Southern Ocean Export production Sediment Excess Ba [CHIM.ANAL]Chemical Sciences/Analytical chemistry |
description |
International audience We present excess Ba (Baxs) data (i.e., total Ba corrected for lithogenic Ba) for surface sediments from a north-south transect between the Polar Front Zone and the northern Weddell Gyre in the Atlantic sector and between the Polar Front Zone and the Antarctic continent in the Indian sector. Focus is on two different processes that affect excess Ba accumulation in the sediments: sediment redistribution and excess Ba dissolution. The effect of these processes needs to be corrected for in order to convert accumulation rate into vertical rain rate, the flux component that can be linked to export production. In the Southern Ocean a major process affecting Ba accumulation rate is sediment focusing, which is corrected for using excess 230Th. This correction, however, may not always be straightforward because of boundary scavenging effects. A further major process affecting excess Ba accumulation is barite dissolution during exposure at the sediment-water column interface. Export production estimates derived from excess 230Th and barite dissolution corrected Baxs accumulation rates (i.e., excess Ba vertical rain rates) are of the same magnitude but generally larger than export production estimates based on water column proxies (234Th-deficit in the upper water column; particulate excess Ba enrichment in the mesopelagic water column). We believe export production values based on excess Ba vertical rain rate might be overestimated due to inaccurate assessment of the Baxs preservation rate. Barite dissolution has, in general, been taken into account by relating it to exposure time before burial depending on the rate of sediment accumulation. However, the observed decrease of excess Ba content with increasing water column depth (or increasing hydrostatic pressure) illustrates the dependence of barite preservation on degree of saturation in the deep water column in accordance with available thermodynamic data. Therefore correction for barite dissolution would not be appropriate by considering only ... |
author2 |
Laboratoire de Chimie Analytique Bio-Inorganique et Environnement (LCABIE) Université de Pau et des Pays de l'Adour (UPPA)-Centre National de la Recherche Scientifique (CNRS) Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux (IPREM) Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
format |
Article in Journal/Newspaper |
author |
Fagel, N. Dehairs, F. Andre, L. Bareille, Gilles Monnin, C. |
author_facet |
Fagel, N. Dehairs, F. Andre, L. Bareille, Gilles Monnin, C. |
author_sort |
Fagel, N. |
title |
Ba distribution in surface Southern Ocean sediments and export production estimates |
title_short |
Ba distribution in surface Southern Ocean sediments and export production estimates |
title_full |
Ba distribution in surface Southern Ocean sediments and export production estimates |
title_fullStr |
Ba distribution in surface Southern Ocean sediments and export production estimates |
title_full_unstemmed |
Ba distribution in surface Southern Ocean sediments and export production estimates |
title_sort |
ba distribution in surface southern ocean sediments and export production estimates |
publisher |
HAL CCSD |
publishDate |
2002 |
url |
https://hal.archives-ouvertes.fr/hal-00291395 https://doi.org/10.1029/2000PA000552 |
geographic |
Antarctic Southern Ocean The Antarctic Indian Weddell |
geographic_facet |
Antarctic Southern Ocean The Antarctic Indian Weddell |
genre |
Antarc* Antarctic Southern Ocean |
genre_facet |
Antarc* Antarctic Southern Ocean |
op_source |
ISSN: 0883-8305 Paleoceanography https://hal.archives-ouvertes.fr/hal-00291395 Paleoceanography, American Geophysical Union, 2002, 17 (2), pp.1-1-1-20 ⟨10.1029/2000PA000552⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1029/2000PA000552 hal-00291395 https://hal.archives-ouvertes.fr/hal-00291395 doi:10.1029/2000PA000552 |
op_doi |
https://doi.org/10.1029/2000PA000552 |
container_title |
Paleoceanography |
container_volume |
17 |
container_issue |
2 |
container_start_page |
1-1 |
op_container_end_page |
1-20 |
_version_ |
1766085280486391808 |