Speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by XANES spectroscopy
Sulfur speciation in a comprehensive set of insoluble organic matter (IOM) samples extracted from 3 CI (Orgueil, Alais, Ivuna), 5 CM (QUE97990, Murchison, Murray, QUE99355, Cold Bokkeveld), 1 CR (Renazzo) and ungrouped C2 Tagish Lake chondrites has been studied by K-edge XANES micro-spectroscopy. Fi...
Published in: | Earth and Planetary Science Letters |
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Main Authors: | , , , , , , |
Other Authors: | , , , , , , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
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HAL CCSD
2010
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Online Access: | https://hal-bioemco.ccsd.cnrs.fr/bioemco-00575865 https://doi.org/10.1016/j.epsl.2010.10.012 |
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ftccsdartic:oai:HAL:bioemco-00575865v1 |
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Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
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ftccsdartic |
language |
English |
topic |
[SDE]Environmental Sciences |
spellingShingle |
[SDE]Environmental Sciences Orthous-Daunay, François-Regis Quirico, Eric Lemelle, Laurence Beck, P. De Andrade, Vanessa Simionovici, Alexandre Derenne, Sylvie Speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by XANES spectroscopy |
topic_facet |
[SDE]Environmental Sciences |
description |
Sulfur speciation in a comprehensive set of insoluble organic matter (IOM) samples extracted from 3 CI (Orgueil, Alais, Ivuna), 5 CM (QUE97990, Murchison, Murray, QUE99355, Cold Bokkeveld), 1 CR (Renazzo) and ungrouped C2 Tagish Lake chondrites has been studied by K-edge XANES micro-spectroscopy. Five main sulfur groups were identified: (1) sulfides, (2) aliphatic sulfur, (3) heterocyclic organic sulfur, (4) oxidized organic sulfur and (5) sulfates. The IOM of the 3 CIs and the extensively altered Cold Bokkeveld CM exhibit a higher abundance of heterocyclic versus aliphatic organic sulfur compared to the other CMs and compared to the Renazzo and Tagish Lake chondrites. This suggests greater thermal heating on the parent body of CIs, consistent with the higher temperatures experienced by these chondrites (~ 70 °C for the most altered clasts of Cold Bokkeveld; 100-150 °C for CIs). Alais may have experienced more heating than Ivuna and Orgueil. The IOM of CIs contains oxidized organic sulfur, suggesting the presence of a mild-temperature oxidation process on the parent body. Among type 2 chondrites other than Cold Bokkeveld, no significant variation of the sulfur speciation was detected. This suggests tenuous oxidation processes and a low-temperature aqueous alteration (< ~ 35 °C) on the parent body. The global chemical variations between the CR and CM groups (e.g. H/C elemental ratio, alkyl groups concentration) reported in earlier studies appear to be more the result of chemical variations among the accreted precursors than of post-accretional processes. |
author2 |
Laboratoire de Planétologie de Grenoble (LPG) Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) LABORATOIRE DE SCIENCE DE LA TERRE ENS Laboratoire de Sciences de la Terre (LST) École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL) Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) European Synchrotron Radiation Facility (ESRF) Laboratoire de Géodynamique des Chaines Alpines (LGCA) Observatoire des Sciences de l'Univers de Grenoble (OSUG) Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) Biogéochimie et écologie des milieux continentaux (Bioemco) Centre National de la Recherche Scientifique (CNRS)-AgroParisTech-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut National de la Recherche Agronomique (INRA)-École normale supérieure - Paris (ENS Paris) Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL) |
format |
Article in Journal/Newspaper |
author |
Orthous-Daunay, François-Regis Quirico, Eric Lemelle, Laurence Beck, P. De Andrade, Vanessa Simionovici, Alexandre Derenne, Sylvie |
author_facet |
Orthous-Daunay, François-Regis Quirico, Eric Lemelle, Laurence Beck, P. De Andrade, Vanessa Simionovici, Alexandre Derenne, Sylvie |
author_sort |
Orthous-Daunay, François-Regis |
title |
Speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by XANES spectroscopy |
title_short |
Speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by XANES spectroscopy |
title_full |
Speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by XANES spectroscopy |
title_fullStr |
Speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by XANES spectroscopy |
title_full_unstemmed |
Speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by XANES spectroscopy |
title_sort |
speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by xanes spectroscopy |
publisher |
HAL CCSD |
publishDate |
2010 |
url |
https://hal-bioemco.ccsd.cnrs.fr/bioemco-00575865 https://doi.org/10.1016/j.epsl.2010.10.012 |
long_lat |
ENVELOPE(144.250,144.250,-67.317,-67.317) ENVELOPE(-134.272,-134.272,60.313,60.313) ENVELOPE(-134.233,-134.233,59.717,59.717) |
geographic |
Murchison Tagish Tagish Lake |
geographic_facet |
Murchison Tagish Tagish Lake |
genre |
Tagish |
genre_facet |
Tagish |
op_source |
ISSN: 0012-821X Earth and Planetary Science Letters https://hal-bioemco.ccsd.cnrs.fr/bioemco-00575865 Earth and Planetary Science Letters, Elsevier, 2010, 2010 (300), pp.321-328. ⟨10.1016/j.epsl.2010.10.012⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.epsl.2010.10.012 bioemco-00575865 https://hal-bioemco.ccsd.cnrs.fr/bioemco-00575865 doi:10.1016/j.epsl.2010.10.012 PRODINRA: 245900 WOS: 000286284600014 |
op_doi |
https://doi.org/10.1016/j.epsl.2010.10.012 |
container_title |
Earth and Planetary Science Letters |
container_volume |
300 |
container_issue |
3-4 |
container_start_page |
321 |
op_container_end_page |
328 |
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1766213546038788096 |
spelling |
ftccsdartic:oai:HAL:bioemco-00575865v1 2023-05-15T18:30:04+02:00 Speciation of sulfur in the insoluble organic matter from carbonaceous chondrites by XANES spectroscopy Orthous-Daunay, François-Regis Quirico, Eric Lemelle, Laurence Beck, P. De Andrade, Vanessa Simionovici, Alexandre Derenne, Sylvie Laboratoire de Planétologie de Grenoble (LPG) Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) LABORATOIRE DE SCIENCE DE LA TERRE ENS Laboratoire de Sciences de la Terre (LST) École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL) Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) European Synchrotron Radiation Facility (ESRF) Laboratoire de Géodynamique des Chaines Alpines (LGCA) Observatoire des Sciences de l'Univers de Grenoble (OSUG) Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) Biogéochimie et écologie des milieux continentaux (Bioemco) Centre National de la Recherche Scientifique (CNRS)-AgroParisTech-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut National de la Recherche Agronomique (INRA)-École normale supérieure - Paris (ENS Paris) Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL) 2010-11-17 https://hal-bioemco.ccsd.cnrs.fr/bioemco-00575865 https://doi.org/10.1016/j.epsl.2010.10.012 en eng HAL CCSD Elsevier info:eu-repo/semantics/altIdentifier/doi/10.1016/j.epsl.2010.10.012 bioemco-00575865 https://hal-bioemco.ccsd.cnrs.fr/bioemco-00575865 doi:10.1016/j.epsl.2010.10.012 PRODINRA: 245900 WOS: 000286284600014 ISSN: 0012-821X Earth and Planetary Science Letters https://hal-bioemco.ccsd.cnrs.fr/bioemco-00575865 Earth and Planetary Science Letters, Elsevier, 2010, 2010 (300), pp.321-328. ⟨10.1016/j.epsl.2010.10.012⟩ [SDE]Environmental Sciences info:eu-repo/semantics/article Journal articles 2010 ftccsdartic https://doi.org/10.1016/j.epsl.2010.10.012 2021-11-21T04:29:36Z Sulfur speciation in a comprehensive set of insoluble organic matter (IOM) samples extracted from 3 CI (Orgueil, Alais, Ivuna), 5 CM (QUE97990, Murchison, Murray, QUE99355, Cold Bokkeveld), 1 CR (Renazzo) and ungrouped C2 Tagish Lake chondrites has been studied by K-edge XANES micro-spectroscopy. Five main sulfur groups were identified: (1) sulfides, (2) aliphatic sulfur, (3) heterocyclic organic sulfur, (4) oxidized organic sulfur and (5) sulfates. The IOM of the 3 CIs and the extensively altered Cold Bokkeveld CM exhibit a higher abundance of heterocyclic versus aliphatic organic sulfur compared to the other CMs and compared to the Renazzo and Tagish Lake chondrites. This suggests greater thermal heating on the parent body of CIs, consistent with the higher temperatures experienced by these chondrites (~ 70 °C for the most altered clasts of Cold Bokkeveld; 100-150 °C for CIs). Alais may have experienced more heating than Ivuna and Orgueil. The IOM of CIs contains oxidized organic sulfur, suggesting the presence of a mild-temperature oxidation process on the parent body. Among type 2 chondrites other than Cold Bokkeveld, no significant variation of the sulfur speciation was detected. This suggests tenuous oxidation processes and a low-temperature aqueous alteration (< ~ 35 °C) on the parent body. The global chemical variations between the CR and CM groups (e.g. H/C elemental ratio, alkyl groups concentration) reported in earlier studies appear to be more the result of chemical variations among the accreted precursors than of post-accretional processes. Article in Journal/Newspaper Tagish Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Murchison ENVELOPE(144.250,144.250,-67.317,-67.317) Tagish ENVELOPE(-134.272,-134.272,60.313,60.313) Tagish Lake ENVELOPE(-134.233,-134.233,59.717,59.717) Earth and Planetary Science Letters 300 3-4 321 328 |