Geochemical investigation of perennial spring activity and associated mineral precipitates at Expedition Fiord, Axel Heiberg Island, Canadian high arctic

Two groups of perennial springs are observed in the Canadian High Arctic at Expedition Fiord on Axel Heiberg Island. Saline discharge (~1.3-2.5 molal) produces a variety of calcite (travertine) and gypsum-rich precipitates. Field observations, laboratory experiments, and geochemical modeling of the...

Full description

Bibliographic Details
Main Author: Omelon, Christopher R.
Format: Thesis
Language:English
Published: McGill University 1999
Subjects:
Online Access:http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=18255
id ftcanadathes:oai:collectionscanada.gc.ca:QMM.18255
record_format openpolar
spelling ftcanadathes:oai:collectionscanada.gc.ca:QMM.18255 2023-05-15T15:03:36+02:00 Geochemical investigation of perennial spring activity and associated mineral precipitates at Expedition Fiord, Axel Heiberg Island, Canadian high arctic Omelon, Christopher R. Master of Science (Department of Geography) 1999 application/pdf http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=18255 en eng McGill University http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=18255 All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated. Earth Sciences -- Geochemistry Electronic Thesis or Dissertation 1999 ftcanadathes 2014-02-16T01:02:49Z Two groups of perennial springs are observed in the Canadian High Arctic at Expedition Fiord on Axel Heiberg Island. Saline discharge (~1.3-2.5 molal) produces a variety of calcite (travertine) and gypsum-rich precipitates. Field observations, laboratory experiments, and geochemical modeling of the waters reveal that calcite precipitation is controlled primarily by CO2 degassing, but alternating light (sparite calcite crystals) and dark (amorphous micritic calcite spheres coated by organic material and trace metals) laminae are present. Evaluation of the geochemical environment in conjunction with field observations suggest that micrite layer formation may be influenced by microbial activity, although their presence has yet to be confirmed. In addition, discharge from two springs at Colour Peak leads to the precipitation of metastable calcium carbonate crystals (0.25-0.5 cm long) on terraced and steep mound slopes that form during winter months. Background literature and field observations suggest that this mineral may be ikaite (CaCO3•6H2O). The precipitation of this mineral may provide information regarding its environmental growth constraints and opportunities. Deux groupes des sources pérennes sont observés dans le Haut-Arctique au fjord Expedition sur l'île Axel Heiberg. Les eaux minéralisées (~1.3-2.5 molal) qui sortent des sources produisent une précipitation de dépôts variés et riches en calcite (travertine) et gypse. Les observations de terrain, les expériences en laboratoire et les modèles geochimiques des eaux montrent que la précipitation de calcite est contrôlée principalmente par la perte de gaz CO2 mais il y a des couches pâles (crystaux calcite sparite) et foncées (sphères de calcite micritique amorphe emrobées par materiaux organique et metaux trace). L'évaluation de l'environnement geochimique et les observations de terrain suggèrent que la production de la couche micritique pourrait être influencée par l'activité microbienne, mais la présence de microbes reste à confirmer. Les sources pérennes à Colour Peak produisent également des cristaux calcium carbonate "métastable" (0.25-0.5 cm) sur les pentes raides et en terrasses pendant l'hiver. La litérature et les observations de terrain suggèrent que ce minéral peut fournir de l'information sur les conditions environnementales de la croissance. fr Thesis Arctic Arctique* Axel Heiberg Island Theses Canada/Thèses Canada (Library and Archives Canada) Arctic Axel Heiberg Island ENVELOPE(-91.001,-91.001,79.752,79.752) Colour Peak ENVELOPE(-91.284,-91.284,79.469,79.469) Expedition Fiord ENVELOPE(-92.001,-92.001,79.335,79.335) Heiberg ENVELOPE(13.964,13.964,66.424,66.424)
institution Open Polar
collection Theses Canada/Thèses Canada (Library and Archives Canada)
op_collection_id ftcanadathes
language English
topic Earth Sciences -- Geochemistry
spellingShingle Earth Sciences -- Geochemistry
Omelon, Christopher R.
Geochemical investigation of perennial spring activity and associated mineral precipitates at Expedition Fiord, Axel Heiberg Island, Canadian high arctic
topic_facet Earth Sciences -- Geochemistry
description Two groups of perennial springs are observed in the Canadian High Arctic at Expedition Fiord on Axel Heiberg Island. Saline discharge (~1.3-2.5 molal) produces a variety of calcite (travertine) and gypsum-rich precipitates. Field observations, laboratory experiments, and geochemical modeling of the waters reveal that calcite precipitation is controlled primarily by CO2 degassing, but alternating light (sparite calcite crystals) and dark (amorphous micritic calcite spheres coated by organic material and trace metals) laminae are present. Evaluation of the geochemical environment in conjunction with field observations suggest that micrite layer formation may be influenced by microbial activity, although their presence has yet to be confirmed. In addition, discharge from two springs at Colour Peak leads to the precipitation of metastable calcium carbonate crystals (0.25-0.5 cm long) on terraced and steep mound slopes that form during winter months. Background literature and field observations suggest that this mineral may be ikaite (CaCO3•6H2O). The precipitation of this mineral may provide information regarding its environmental growth constraints and opportunities. Deux groupes des sources pérennes sont observés dans le Haut-Arctique au fjord Expedition sur l'île Axel Heiberg. Les eaux minéralisées (~1.3-2.5 molal) qui sortent des sources produisent une précipitation de dépôts variés et riches en calcite (travertine) et gypse. Les observations de terrain, les expériences en laboratoire et les modèles geochimiques des eaux montrent que la précipitation de calcite est contrôlée principalmente par la perte de gaz CO2 mais il y a des couches pâles (crystaux calcite sparite) et foncées (sphères de calcite micritique amorphe emrobées par materiaux organique et metaux trace). L'évaluation de l'environnement geochimique et les observations de terrain suggèrent que la production de la couche micritique pourrait être influencée par l'activité microbienne, mais la présence de microbes reste à confirmer. Les sources pérennes à Colour Peak produisent également des cristaux calcium carbonate "métastable" (0.25-0.5 cm) sur les pentes raides et en terrasses pendant l'hiver. La litérature et les observations de terrain suggèrent que ce minéral peut fournir de l'information sur les conditions environnementales de la croissance. fr
format Thesis
author Omelon, Christopher R.
author_facet Omelon, Christopher R.
author_sort Omelon, Christopher R.
title Geochemical investigation of perennial spring activity and associated mineral precipitates at Expedition Fiord, Axel Heiberg Island, Canadian high arctic
title_short Geochemical investigation of perennial spring activity and associated mineral precipitates at Expedition Fiord, Axel Heiberg Island, Canadian high arctic
title_full Geochemical investigation of perennial spring activity and associated mineral precipitates at Expedition Fiord, Axel Heiberg Island, Canadian high arctic
title_fullStr Geochemical investigation of perennial spring activity and associated mineral precipitates at Expedition Fiord, Axel Heiberg Island, Canadian high arctic
title_full_unstemmed Geochemical investigation of perennial spring activity and associated mineral precipitates at Expedition Fiord, Axel Heiberg Island, Canadian high arctic
title_sort geochemical investigation of perennial spring activity and associated mineral precipitates at expedition fiord, axel heiberg island, canadian high arctic
publisher McGill University
publishDate 1999
url http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=18255
op_coverage Master of Science (Department of Geography)
long_lat ENVELOPE(-91.001,-91.001,79.752,79.752)
ENVELOPE(-91.284,-91.284,79.469,79.469)
ENVELOPE(-92.001,-92.001,79.335,79.335)
ENVELOPE(13.964,13.964,66.424,66.424)
geographic Arctic
Axel Heiberg Island
Colour Peak
Expedition Fiord
Heiberg
geographic_facet Arctic
Axel Heiberg Island
Colour Peak
Expedition Fiord
Heiberg
genre Arctic
Arctique*
Axel Heiberg Island
genre_facet Arctic
Arctique*
Axel Heiberg Island
op_relation http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=18255
op_rights All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.
_version_ 1766335462034636800