Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field
Hydroxymethanesulfonate (HMS) is produced in the aqueous-phase reaction of formaldehyde (HCHO) and sulfur dioxide (SOâ‚‚) and has been proposed as a significant contributor to midlatitude wintertime pollution events. Here we report HMS detection within submicrometer atmospheric aerosols during frequ...
Published in: | Environmental Science & Technology Letters |
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ftcaltechauth:oai:authors.library.caltech.edu:fdnnk-fc960 2024-09-15T17:58:49+00:00 Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field Liu, Jun Gunsch, Matthew J. Moffett, Claire E. Xu, Lu El Asmar, Rime Zhang, Qi Watson, Thomas B. Allen, Hannah M. Crounse, John D. St. Clair, Jason Kim, Michelle Wennberg, Paul O. Weber, Rodney J. Sheesley, Rebecca J. Pratt, Kerri A. 2021-07-13 https://doi.org/10.1021/acs.estlett.1c00357 unknown American Chemical Society https://www.arm.gov/research/campaigns/amf2015saansa https://doi.org/10.1021/acs.estlett.1c00357 oai:authors.library.caltech.edu:fdnnk-fc960 eprintid:109703 resolverid:CaltechAUTHORS:20210701-170842679 info:eu-repo/semantics/openAccess Other Environmental Science and Technology Letters, 8(7), 511-518, (2021-07-13) Lipids Anions Liquids Aerosols Particulate matter info:eu-repo/semantics/article 2021 ftcaltechauth https://doi.org/10.1021/acs.estlett.1c00357 2024-08-06T15:35:05Z Hydroxymethanesulfonate (HMS) is produced in the aqueous-phase reaction of formaldehyde (HCHO) and sulfur dioxide (SO₂) and has been proposed as a significant contributor to midlatitude wintertime pollution events. Here we report HMS detection within submicrometer atmospheric aerosols during frequent late summer, regional fog events in an Arctic oil field. The number fraction of individual particles containing HMS increased during fog periods, consistent with aqueous-phase formation. The single-particle mass spectra showed the primary particle signature (oil field emissions), plus secondary oxidized organics and sulfate, consistent with aqueous-phase processing. HMS mass concentrations ranged from below the ion chromatography limit of detection (0.3 ng/m³) to 1.6 ng/m³, with sulfate concentrations of 37–222 ng/m³. HCHO and SO₂ measurements suggest that the fog HMS production rate is ∼10 times higher in the oil fields than in the upwind Beaufort Sea. Aqueous-phase reactions of local oil field emissions during frequent summertime regional fog events likely have downwind impacts on Arctic aerosol composition. The potential for fog-based HMS production was estimated to be an order of magnitude higher in Fairbanks and Anchorage, AK, than in the oil fields and may explain the missing organosulfate source contributing to Fairbanks air quality. © 2021 American Chemical Society. Received: May 9, 2021; Revised: June 16, 2021; Accepted: June 18, 2021. This study was supported by the NOAA Climate Program Office and Atmospheric Chemistry, Carbon Cycle, and Climate Program through NA14OAR4310149 (University of Michigan) and NA14OAR4310150 (Baylor University) and a Department of Energy (DOE) Early Career Award (DE-SC0019172). The field work was also supported in part by the DOE Office of Biological and Environmental Research (BER) ARM Climate Research Facility (field campaign 2013-6660). This research was also supported by a National Academies of Sciences, Engineering, and Medicine Gulf Research Program ... Article in Journal/Newspaper Beaufort Sea Caltech Authors (California Institute of Technology) Environmental Science & Technology Letters 8 7 511 518 |
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Caltech Authors (California Institute of Technology) |
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ftcaltechauth |
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unknown |
topic |
Lipids Anions Liquids Aerosols Particulate matter |
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Lipids Anions Liquids Aerosols Particulate matter Liu, Jun Gunsch, Matthew J. Moffett, Claire E. Xu, Lu El Asmar, Rime Zhang, Qi Watson, Thomas B. Allen, Hannah M. Crounse, John D. St. Clair, Jason Kim, Michelle Wennberg, Paul O. Weber, Rodney J. Sheesley, Rebecca J. Pratt, Kerri A. Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field |
topic_facet |
Lipids Anions Liquids Aerosols Particulate matter |
description |
Hydroxymethanesulfonate (HMS) is produced in the aqueous-phase reaction of formaldehyde (HCHO) and sulfur dioxide (SO₂) and has been proposed as a significant contributor to midlatitude wintertime pollution events. Here we report HMS detection within submicrometer atmospheric aerosols during frequent late summer, regional fog events in an Arctic oil field. The number fraction of individual particles containing HMS increased during fog periods, consistent with aqueous-phase formation. The single-particle mass spectra showed the primary particle signature (oil field emissions), plus secondary oxidized organics and sulfate, consistent with aqueous-phase processing. HMS mass concentrations ranged from below the ion chromatography limit of detection (0.3 ng/m³) to 1.6 ng/m³, with sulfate concentrations of 37–222 ng/m³. HCHO and SO₂ measurements suggest that the fog HMS production rate is ∼10 times higher in the oil fields than in the upwind Beaufort Sea. Aqueous-phase reactions of local oil field emissions during frequent summertime regional fog events likely have downwind impacts on Arctic aerosol composition. The potential for fog-based HMS production was estimated to be an order of magnitude higher in Fairbanks and Anchorage, AK, than in the oil fields and may explain the missing organosulfate source contributing to Fairbanks air quality. © 2021 American Chemical Society. Received: May 9, 2021; Revised: June 16, 2021; Accepted: June 18, 2021. This study was supported by the NOAA Climate Program Office and Atmospheric Chemistry, Carbon Cycle, and Climate Program through NA14OAR4310149 (University of Michigan) and NA14OAR4310150 (Baylor University) and a Department of Energy (DOE) Early Career Award (DE-SC0019172). The field work was also supported in part by the DOE Office of Biological and Environmental Research (BER) ARM Climate Research Facility (field campaign 2013-6660). This research was also supported by a National Academies of Sciences, Engineering, and Medicine Gulf Research Program ... |
format |
Article in Journal/Newspaper |
author |
Liu, Jun Gunsch, Matthew J. Moffett, Claire E. Xu, Lu El Asmar, Rime Zhang, Qi Watson, Thomas B. Allen, Hannah M. Crounse, John D. St. Clair, Jason Kim, Michelle Wennberg, Paul O. Weber, Rodney J. Sheesley, Rebecca J. Pratt, Kerri A. |
author_facet |
Liu, Jun Gunsch, Matthew J. Moffett, Claire E. Xu, Lu El Asmar, Rime Zhang, Qi Watson, Thomas B. Allen, Hannah M. Crounse, John D. St. Clair, Jason Kim, Michelle Wennberg, Paul O. Weber, Rodney J. Sheesley, Rebecca J. Pratt, Kerri A. |
author_sort |
Liu, Jun |
title |
Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field |
title_short |
Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field |
title_full |
Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field |
title_fullStr |
Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field |
title_full_unstemmed |
Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field |
title_sort |
hydroxymethanesulfonate (hms) formation during summertime fog in an arctic oil field |
publisher |
American Chemical Society |
publishDate |
2021 |
url |
https://doi.org/10.1021/acs.estlett.1c00357 |
genre |
Beaufort Sea |
genre_facet |
Beaufort Sea |
op_source |
Environmental Science and Technology Letters, 8(7), 511-518, (2021-07-13) |
op_relation |
https://www.arm.gov/research/campaigns/amf2015saansa https://doi.org/10.1021/acs.estlett.1c00357 oai:authors.library.caltech.edu:fdnnk-fc960 eprintid:109703 resolverid:CaltechAUTHORS:20210701-170842679 |
op_rights |
info:eu-repo/semantics/openAccess Other |
op_doi |
https://doi.org/10.1021/acs.estlett.1c00357 |
container_title |
Environmental Science & Technology Letters |
container_volume |
8 |
container_issue |
7 |
container_start_page |
511 |
op_container_end_page |
518 |
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1810435797717876736 |