Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway
The weathering rate of carbonate minerals is several orders of magnitude higher than for silicate minerals. Therefore, small amounts of carbonate minerals have the potential to control the dissolved weathering loads in silicate-dominated catchments. Both weathering processes produce alkalinity under...
Published in: | Biogeosciences |
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Copernicus Publications
2023
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Online Access: | https://epic.awi.de/id/eprint/58256/ https://epic.awi.de/id/eprint/58256/1/bg-20-3459-2023.pdf https://doi.org/10.5194/bg-20-3459-2023 https://hdl.handle.net/10013/epic.e267b942-cf9f-4512-9afa-708372326475 |
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ftawi:oai:epic.awi.de:58256 2024-06-02T08:05:14+00:00 Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway Lehmann, Nele Lantuit, Hugues Böttcher, Michael Ernst Hartmann, Jens Eulenburg, Antje Thomas, Helmuth 2023-08-18 application/pdf https://epic.awi.de/id/eprint/58256/ https://epic.awi.de/id/eprint/58256/1/bg-20-3459-2023.pdf https://doi.org/10.5194/bg-20-3459-2023 https://hdl.handle.net/10013/epic.e267b942-cf9f-4512-9afa-708372326475 unknown Copernicus Publications https://epic.awi.de/id/eprint/58256/1/bg-20-3459-2023.pdf Lehmann, N. , Lantuit, H. orcid:0000-0003-1497-6760 , Böttcher, M. E. , Hartmann, J. , Eulenburg, A. and Thomas, H. (2023) Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway , Biogeosciences, 20 (16), pp. 3459-3479 . doi:10.5194/bg-20-3459-2023 <https://doi.org/10.5194/bg-20-3459-2023> , hdl:10013/epic.e267b942-cf9f-4512-9afa-708372326475 EPIC3Biogeosciences, Copernicus Publications, 20(16), pp. 3459-3479, ISSN: 1726-4170 Article isiRev 2023 ftawi https://doi.org/10.5194/bg-20-3459-2023 2024-05-07T23:37:52Z The weathering rate of carbonate minerals is several orders of magnitude higher than for silicate minerals. Therefore, small amounts of carbonate minerals have the potential to control the dissolved weathering loads in silicate-dominated catchments. Both weathering processes produce alkalinity under the consumption of CO2. Given that only alkalinity generation from silicate weathering is thought to be a long-term sink for CO2, a misattributed weathering source could lead to incorrect conclusions about long- and short-term CO2 fixation. In this study, we aimed to identify the weathering sources responsible for alkalinity generation and CO2 fixation across watershed scales in a degrading permafrost landscape in northern Norway, 68.7–70.5∘ N, and on a temporal scale, in a subarctic headwater catchment on the mountainside of Iskorasfjellet, characterized by sporadic permafrost and underlain mainly by silicates as the alkalinity-bearing lithology. By analyzing total alkalinity (AT) and dissolved inorganic carbon (DIC) concentrations, as well as the stable isotope signature of the latter (δ13C-DIC), in conjunction with dissolved cation and anion loads, we found that AT was almost entirely derived from weathering of the sparse carbonate minerals. We propose that in the headwater catchment the riparian zone is a hotspot area of AT generation and release due to its enhanced hydrological connectivity and that the weathering load contribution from the uphill catchment is limited by insufficient contact time of weathering agents and weatherable materials. By using stable water isotopes, it was possible to explain temporal variations in AT concentrations following a precipitation event due to surface runoff. In addition to carbonic acid, sulfuric acid, probably originating from oxidation of pyrite or reduced sulfur in wetlands or from acid deposition, is shown to be a potential corrosive reactant. An increased proportion of sulfuric acid as a potential weathering agent may have resulted in a decrease in AT. Therefore, ... Article in Journal/Newspaper Carbonic acid Northern Norway permafrost Subarctic Alfred Wegener Institute for Polar- and Marine Research (AWI): ePIC (electronic Publication Information Center) Norway Biogeosciences 20 16 3459 3479 |
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Alfred Wegener Institute for Polar- and Marine Research (AWI): ePIC (electronic Publication Information Center) |
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ftawi |
language |
unknown |
description |
The weathering rate of carbonate minerals is several orders of magnitude higher than for silicate minerals. Therefore, small amounts of carbonate minerals have the potential to control the dissolved weathering loads in silicate-dominated catchments. Both weathering processes produce alkalinity under the consumption of CO2. Given that only alkalinity generation from silicate weathering is thought to be a long-term sink for CO2, a misattributed weathering source could lead to incorrect conclusions about long- and short-term CO2 fixation. In this study, we aimed to identify the weathering sources responsible for alkalinity generation and CO2 fixation across watershed scales in a degrading permafrost landscape in northern Norway, 68.7–70.5∘ N, and on a temporal scale, in a subarctic headwater catchment on the mountainside of Iskorasfjellet, characterized by sporadic permafrost and underlain mainly by silicates as the alkalinity-bearing lithology. By analyzing total alkalinity (AT) and dissolved inorganic carbon (DIC) concentrations, as well as the stable isotope signature of the latter (δ13C-DIC), in conjunction with dissolved cation and anion loads, we found that AT was almost entirely derived from weathering of the sparse carbonate minerals. We propose that in the headwater catchment the riparian zone is a hotspot area of AT generation and release due to its enhanced hydrological connectivity and that the weathering load contribution from the uphill catchment is limited by insufficient contact time of weathering agents and weatherable materials. By using stable water isotopes, it was possible to explain temporal variations in AT concentrations following a precipitation event due to surface runoff. In addition to carbonic acid, sulfuric acid, probably originating from oxidation of pyrite or reduced sulfur in wetlands or from acid deposition, is shown to be a potential corrosive reactant. An increased proportion of sulfuric acid as a potential weathering agent may have resulted in a decrease in AT. Therefore, ... |
format |
Article in Journal/Newspaper |
author |
Lehmann, Nele Lantuit, Hugues Böttcher, Michael Ernst Hartmann, Jens Eulenburg, Antje Thomas, Helmuth |
spellingShingle |
Lehmann, Nele Lantuit, Hugues Böttcher, Michael Ernst Hartmann, Jens Eulenburg, Antje Thomas, Helmuth Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway |
author_facet |
Lehmann, Nele Lantuit, Hugues Böttcher, Michael Ernst Hartmann, Jens Eulenburg, Antje Thomas, Helmuth |
author_sort |
Lehmann, Nele |
title |
Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway |
title_short |
Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway |
title_full |
Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway |
title_fullStr |
Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway |
title_full_unstemmed |
Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway |
title_sort |
alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at iskorasfjellet, northern norway |
publisher |
Copernicus Publications |
publishDate |
2023 |
url |
https://epic.awi.de/id/eprint/58256/ https://epic.awi.de/id/eprint/58256/1/bg-20-3459-2023.pdf https://doi.org/10.5194/bg-20-3459-2023 https://hdl.handle.net/10013/epic.e267b942-cf9f-4512-9afa-708372326475 |
geographic |
Norway |
geographic_facet |
Norway |
genre |
Carbonic acid Northern Norway permafrost Subarctic |
genre_facet |
Carbonic acid Northern Norway permafrost Subarctic |
op_source |
EPIC3Biogeosciences, Copernicus Publications, 20(16), pp. 3459-3479, ISSN: 1726-4170 |
op_relation |
https://epic.awi.de/id/eprint/58256/1/bg-20-3459-2023.pdf Lehmann, N. , Lantuit, H. orcid:0000-0003-1497-6760 , Böttcher, M. E. , Hartmann, J. , Eulenburg, A. and Thomas, H. (2023) Alkalinity generation from carbonate weathering in a silicate-dominated headwater catchment at Iskorasfjellet, northern Norway , Biogeosciences, 20 (16), pp. 3459-3479 . doi:10.5194/bg-20-3459-2023 <https://doi.org/10.5194/bg-20-3459-2023> , hdl:10013/epic.e267b942-cf9f-4512-9afa-708372326475 |
op_doi |
https://doi.org/10.5194/bg-20-3459-2023 |
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Biogeosciences |
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20 |
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16 |
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3479 |
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