A new micro sublimation technique for high-precision d13CO2 analysis of ice cores: instrumental set-up and first results

• Main Authors: Schmitt, Jochen, Fischer, Hubertus
• Format: Conference Object
• Language: unknown
• Published: 2005
• Subjects: EPICA; ice core
• Online Access: https://epic.awi.de/id/eprint/11862/; https://hdl.handle.net/10013/epic.22306

The challenge to quantitatively explain the observed glacial/interglacial variations in atmospheric pCO2 of about 100 ppmv is a task of outstanding importance for the paleo climate community. Although pCO2 data will be shortly available over the last 650,000 years from the new EPICA Dome C ice core, isotopic information, which strongly constrains potential fluxes between carbon reservoirs and the atmosphere, is still sparse and restricted to the last approximate 40 ka due to methodological constraints.Up to now the quantitative extraction of CO2 from ice cores to measure its isotopic composition was restricted to the uppermost part where air still occurs in bubbles. Below the clathrate formation depth at about 700 m extraction efficiencies gradually decrease with unknown effects on gas- and isotopic composition. With our new method we are able to extract the air constituents quantitatively for both bubble and clathrate ice.Since gas extraction from the ice is by far more time consuming than the actual measurement in the IRMS, the system was split up into a sample preparation and the measurement device. This allows us to measure several gas samples within a short time span and, thus, to take benefit of identical measurement conditions at the IRMS for a set of samples. This is crucial as changes in the performance of the IRMS are a well known problem. The sample preparation is based on a sublimation technique which is currently designed for ice samples from 5 to 30 g. Within a glass vacuum chamber the ice is sublimated by illuminating it with infrared light and the released air dried and CO2 separated from N2, O2 and Ar. The pure CO2 and N2O gas is frozen in a small glass capillary, which is flame sealed. In this capillary the gas sample can be stored for measurement in the IRMS line. To calibrate and determine the performance of the system a continuous reference inlet with viscous flow conditions was designed. It allows us to mimic the continuous gas release of a sample during sublimation as good as possible. The ...