Effects of seafloor and laboratory dissolution on the Mg/Ca composition of Globigerinoides sacculifer and Orbulina universa tests - A laser ablation ICPMS microanalysis perspective

• Published in: Earth and Planetary Science Letters
• Main Authors: Sadekov, Aleksey, Eggins, Stephen, Klinkhammer, G, Rosenthal, Y
• Format: Article in Journal/Newspaper
• Language: unknown
• Published: Elsevier
• Subjects: Keywords: Calcite crusts; Calcite dissolution; Chamber walls; Core-top samples; Diagenetics; Indian ocean; Laser-ablation-ICP-MS; Mean values; Outer surface; Paleoceanography; Planktonic foraminifera; Sea floor; Sea surface temperatures; Selective dissolution; Sele Calcite dissolution; Calcite lysocline; Laser ablation ICPMS; Mg/Ca thermometry; Indian
• Online Access: http://hdl.handle.net/1885/32722; https://doi.org/10.1016/j.epsl.2010.01.039; https://openresearch-repository.anu.edu.au/bitstream/1885/32722/5/SadekovEggins_Effects_2010.pdf.jpg; https://openresearch-repository.anu.edu.au/bitstream/1885/32722/7/01_Sadekov_Effects_of_seafloor_and_2010.pdf.jpg

Partial or selective dissolution of planktonic foraminiferal tests on the seafloor has been shown to alter original test Mg/Ca compositions and thus may limit the accuracy of Mg/Ca-based thermometry for reconstructions of past sea surface temperatures. We have employed laser ablation ICPMS to determine the extent of dissolution-caused changes in Mg/Ca distribution across individual chamber walls of the planktonic foraminifera Globigerinoides sacculifer and Orbulina universa. G. sacculifer samples collected from a core-top depth transect in the NE Indian Ocean and laboratory dissolution experiments show little if any evidence of preferential removal of Mg-rich calcite layers by progressive dissolution of the tests. We attribute the absence of selective dissolution to the banded distribution of Mg across the chamber walls of these foraminiferal species and to the minimal presence of calcite crusts with relatively low-Mg composition on the outer surfaces of tests. Mg/Ca microanalyses of G. sacculifer from core-top samples further indicate that for samples collected above the calcite lysocline the effect of postdepositional dissolution on Mg/Ca sample mean values is minimal and within the uncertainty of Mg/Ca thermometry (i.e. ±0.4mmol/mol; ±0.8°C at ~28°C). Comparison with previously published results for G. sacculifer supports these observations. Simple modelling of G. sacculifer test dissolution indicates that selective removal of calcite with high-Mg/Ca values from within the final chamber of G. sacculifer test appears insufficient to cause the ~10% decrease in Mg/Ca values observed above calcite lysocline. These changes in test composition might be related to development/removal as a function of Δ[CO32-] of a thin diagenetic surface coating which has a relatively high-Mg/Ca composition (i.e. 20-25mmol/mol).