Development and application of DGT devices for passive sampling of contaminated waters in the Antarctic environment

• Format: Dataset
• Language: unknown
• Published: Australian Ocean Data Network
• Subjects: environment; oceans; EARTH SCIENCE > HUMAN DIMENSIONS > ENVIRONMENTAL IMPACTS > HEAVY METALS CONCENTRATION; OCEANS > WATER QUALITY > OCEAN CONTAMINANTS; ANTARCTICA; DGT; DIFFUSIVE GRADIENTS IN THIN FILMS; AMD/AU; CEOS; AMD; CONTINENT > ANTARCTICA > Casey; GEOGRAPHIC REGION > POLAR; Antarctic; The Antarctic; Casey Station; O'Brien Bay; Brown Bay; Antarc*; Antarctica
• Online Access: https://researchdata.edu.au/development-application-dgt-antarctic-environment/2821929

Progress Code: completed Metadata record for data from ASAC Project 2385 See the link below for public details on this project. --- Public Summary from Project --- Facilities for chemical analysis of environmental samples in Antarctica are limited, with samples frequently shipped at great expense to Australia for analysis. Development of a technique to concentrate metals from environmental samples into a thin film which can be easily transported to a laboratory for analysis is currently underway. DGT stands for Diffusive gradients in thin films, they are a passive sampling technique for trace metals based on Fick's First Law of diffusion. Basically the theory being the method: Zhang, H. and Davison, W., Anal Chem, 1995, 67, 3391-400 and Davison, W. and Zhang, H., Nature (London), 1994, 367, 546-8. Description of spreadsheets: All data were collected using DGT sediment probes or water samplers prepared from polyacrylamide diffusion layer (0.8 mm thickness, covered with a 0.13 mm thick membrane filter) and Chelex 100 binding layer (0.4 mm thick). Metadata 0304 sediment - DGT sediment probes were deployed during the 0304 summer. Samples were deployed in a 3 x 2 back-to-back array at the inner and outer sites in Brown and O'Brien Bay. ie 1.1 and 1.2 are back to back pair. All samplers were deployed for 34 days. More accurate date are on the attached s'sheet. Results shown are nanograms of metals per square centimetre accumulated in the samplers at a resolution of 2 cm. The detection limits of the metals for the samplers are based on 3 x stdev of the field blank probes. Where value = &nd& the value was less than the method detection limit. Metadata 0304 sediment Characterisation - Cores were sampled in Dec 2003 - Jan 2004 from Casey Station region. All characterisation was performed on the same 1 cm slices of core. Cores were sampled and analysed in anoxic conditions. Latitudes and Longitudess Brown Bay inner66.2803 S, 110.5414 E Brown Bay outer66.2802 S, 110.5451 E O'Brien Bay inner66.3122 S, 110.5147 E ...