Neodymium isotopes in seawater samples collected during the IN2017-V01 voyage of the RV Investigator

• Other Authors: AADC (owner), AADC, DATA OFFICER (distributor), AADC, DATA OFFICER (custodian), AU/AADC > Australian Antarctic Data Centre, Australia (hasAssociationWith), Australian Antarctic Data Centre (publisher), Australian Antarctic Division (sponsor), CHARLIER, BRUCE L. A. (collaborator), CREAC'H, LAYLA (collaborator), CREAC'H, LAYLA (hasPrincipalInvestigator), CREAC'H, LAYLA (author), Creac'h, L., Noble, T. and Charlier, B.L. (originator), NOBLE, TARYN (hasPrincipalInvestigator)
• Format: Dataset
• Language: unknown
• Published: Australian Ocean Data Network
• Subjects: oceans; geoscientificInformation; EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > OCEAN TRACERS; TRACE ELEMENTS; MARINE GEOCHEMISTRY; ISOTOPES; RV INVESTIGATOR; TIMS - THERMAL IONISATION MASS SPECTROMETER; NEODYMIUM; NISKIN BOTTLES; ICP-MS > Inductively Coupled Plasma Mass Spectrometer; SHIPS; LABORATORY; CEOS; GEOGRAPHIC REGION > POLAR; OCEAN > SOUTHERN OCEAN; CONTINENT > ANTARCTICA > WILKES LAND; Antarc*; Antarctic; Antarctica; Southern Ocean; Totten Glacier; Wilkes Land
• Online Access: https://researchdata.edu.au/neodymium-isotopes-seawater-rv-investigator/2819970

Progress Code: completed Statement: Multiple procedural blanks and certified standards were processed and analysed in the same manner as samples. Accuracy and precision of the seawater - Nd analysis were assessed using JNdi-1 isotopic reference material (Geological Survey of Japan, Tanaka et al., 2000). We suspect issues with sample filtration at the CTD stations 9, 16 and 19 of the voyage, with the measurements representing a ‘total’ (and less radiogenic eNd) rather than dissolved fraction. Purpose These data were collected in order to determine the Nd isotopic composition of water masses and for paleo-proxies calibration. Samples were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator from January 14th to March 5th 2017 (IN2017_V01; Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. Ten litres seawater samples were collected using a CTD rosette equipped with Niskin® bottle and filtered through a 0.45µm Acropak® capsule filter directly into acid-cleaned 10 L polyethylene jerrycans. Samples were then acidified to pH 2 with 2 mL/L of distilled 6M HCl in a laminar flow hood. These samples were analysed for neodymium (Nd) isotopes, a tracer of ocean circulation. In the home laboratory (IMAS Trace-Metal Lab, UTAS, Hobart, Australia), seawater samples were pre-concentrated using pre-packed Nobias® PA1L (Hitachi Technologies, Japan) chelating resin cartridges following the method of Pérez-Tribouillier et al., (2019). Rare Earth Elements were separated using anion-exchange chromatography (Anderson et al., 2012) and cation-exchange chromatography (Struve et al., 2016). Finally, Nd isotopes were isolated using LN-Spec column chemistry (Pin and Zalduegui, 1997). Purified seawater sample Nd concentrations were checked prior to isotopic analysis using Sector Field Inductively Coupled Mass ...