Dissolved thorium isotopes in seawater samples collected during the IN2017-V01 voyage of the RV Investigator

• Other Authors: AADC (owner), AADC, DATA OFFICER (distributor), AADC, DATA OFFICER (custodian), AU/AADC > Australian Antarctic Data Centre, Australia (hasAssociationWith), Australian Antarctic Data Centre (publisher), Australian Antarctic Division (sponsor), CREAC'H, LAYLA (collaborator), CREAC'H, LAYLA (hasPrincipalInvestigator), CREAC'H, LAYLA (author), Creac'h, L., Noble, T.L., Townsend, A. and Perez Tribouillier, H. (originator), NOBLE, TARYN L (hasPrincipalInvestigator), PEREZ TRIBOUILLIER, HABACUC (collaborator), TOWNSEND, ASHLEY (collaborator)
• Format: Dataset
• Language: unknown
• Published: Australian Ocean Data Network
• Subjects: oceans; EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > TRACE ELEMENTS; OCEAN TRACERS; OCEAN CHEMISTRY; MARINE GEOCHEMISTRY; RADIONUCLIDES; RV INVESTIGATOR; THORIUM; ISOTOPES; NISKIN BOTTLES; ICP-MS > Inductively Coupled Plasma Mass Spectrometer; SHIPS; LABORATORY; AMD/AU; AMD; CEOS; GEOGRAPHIC REGION > POLAR; OCEAN > SOUTHERN OCEAN; CONTINENT > ANTARCTICA > WILKES LAND; Antarc*; Antarctic; Antarctica; Institute for Marine and Antarctic Studies; Southern Ocean; Totten Glacier; Wilkes Land
• Online Access: https://researchdata.edu.au/dissolved-thorium-isotopes-rv-investigator/2819604

Progress Code: completed Statement: A milli-Q blank was processed and analysed every batch of 10 samples. Accuracy and precision of the analysis were assessed using the GEOTRACES inter-calibration solution SW STD 2010-1. The measured 232Th concentrations at CTD-9, 16 and 19 are excessively high, despite very low procedural blanks. We suspect issues with sample filtration at these CTD stations of the voyage, with the measurements representing a ‘total’ rather than dissolved fraction. Purpose These data were collected to determine the concentration of dissolved thorium isotopes in seawater, in order to trace particles distributions in the water column. Samples were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator from January 14th to March 5th 2017 (IN2017_V01; Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. Ten litres seawater samples were collected using a CTD rosette equipped with Niskin® bottle and filtered through a 0.45µm Millipore GWSC04510: Ground Water sampling capsule, directly into acid-cleaned 10 L polyethylene jerrycans. Samples were then acidified to pH 2 with 2 mL/L of distilled 6M HCl in a laminar flow hood. These samples were analysed for thorium isotopes (230Th and 232Th), a tracer of particle dynamics. The sample preparation was carried out in the clean lab of the Institute for Marine and Antarctic Studies (UTAS, Hobart). Seawater samples were acidified with HF (final concentration 0.6 mM, Middag et al., 2015), spiked with 10 pg of 229Th (NIST 4328C, National Institute of Standards and Technology, USA) and left to equilibrate for at least 48h. Samples were preconcentrated using Nobias® PA1L (Hitachi Technologies, Japan) cartridges, following the procedure of Pérez-Tribouillier et al., (2019). The separation and purification of thorium isotopes were performed by ...