Assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in Antarctic marine waters

This study assessed the performance of diffusive gradients in thin-films (DGT) with a binding resin that used Chelex-100 (iminodiacetic acid functional groups) to measure cadmium, copper, nickel, lead, and zinc contaminants in Antarctic marine conditions. To do this, three sets of experiments were d...

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Bibliographic Details
Other Authors: AADC (originator), AU/AADC > Australian Antarctic Data Centre, Australia (resourceProvider)
Format: Dataset
Language:unknown
Published: Australian Ocean Data Network
Subjects:
AMD
Online Access:https://researchdata.ands.org.au/assessment-performance-diffusive-marine-waters/1358662
https://data.aad.gov.au/metadata/records/AAS_4326_DGTvalidation
https://data.aad.gov.au/aadc/metadata/citation.cfm?entry_id=AAS_4326_DGTvalidation
https://data.aad.gov.au/eds/4811/download
https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=AAS_4326
https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=4326
id ftands:oai:ands.org.au::1358662
record_format openpolar
institution Open Polar
collection Research Data Australia (Australian National Data Service - ANDS)
op_collection_id ftands
language unknown
topic environment
oceans
TRACE METALS
EARTH SCIENCE
TERRESTRIAL HYDROSPHERE
WATER QUALITY/WATER CHEMISTRY
MARINE ENVIRONMENT MONITORING
CONTAMINANT LEVELS/SPILLS
HUMAN DIMENSIONS
ENVIRONMENTAL IMPACTS
TOXICITY LEVELS
BIOSPHERE
ECOLOGICAL DYNAMICS
ECOTOXICOLOGY
ENVIRONMENTAL MONITORING
DIFFUSIVE GRADIENTS IN THIN-FILMS
ICP-AES &gt
Inductively Coupled Plasma Atomic Emission Spectrometer
ICP-MS &gt
Inductively Coupled Plasma Mass Spectrometer
LABORATORY
AMD/AU
AMD
CEOS
CONTINENT &gt
AUSTRALIA/NEW ZEALAND &gt
AUSTRALIA
GEOGRAPHIC REGION &gt
POLAR
ANTARCTICA
OCEAN &gt
SOUTHERN OCEAN
spellingShingle environment
oceans
TRACE METALS
EARTH SCIENCE
TERRESTRIAL HYDROSPHERE
WATER QUALITY/WATER CHEMISTRY
MARINE ENVIRONMENT MONITORING
CONTAMINANT LEVELS/SPILLS
HUMAN DIMENSIONS
ENVIRONMENTAL IMPACTS
TOXICITY LEVELS
BIOSPHERE
ECOLOGICAL DYNAMICS
ECOTOXICOLOGY
ENVIRONMENTAL MONITORING
DIFFUSIVE GRADIENTS IN THIN-FILMS
ICP-AES &gt
Inductively Coupled Plasma Atomic Emission Spectrometer
ICP-MS &gt
Inductively Coupled Plasma Mass Spectrometer
LABORATORY
AMD/AU
AMD
CEOS
CONTINENT &gt
AUSTRALIA/NEW ZEALAND &gt
AUSTRALIA
GEOGRAPHIC REGION &gt
POLAR
ANTARCTICA
OCEAN &gt
SOUTHERN OCEAN
Assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in Antarctic marine waters
topic_facet environment
oceans
TRACE METALS
EARTH SCIENCE
TERRESTRIAL HYDROSPHERE
WATER QUALITY/WATER CHEMISTRY
MARINE ENVIRONMENT MONITORING
CONTAMINANT LEVELS/SPILLS
HUMAN DIMENSIONS
ENVIRONMENTAL IMPACTS
TOXICITY LEVELS
BIOSPHERE
ECOLOGICAL DYNAMICS
ECOTOXICOLOGY
ENVIRONMENTAL MONITORING
DIFFUSIVE GRADIENTS IN THIN-FILMS
ICP-AES &gt
Inductively Coupled Plasma Atomic Emission Spectrometer
ICP-MS &gt
Inductively Coupled Plasma Mass Spectrometer
LABORATORY
AMD/AU
AMD
CEOS
CONTINENT &gt
AUSTRALIA/NEW ZEALAND &gt
AUSTRALIA
GEOGRAPHIC REGION &gt
POLAR
ANTARCTICA
OCEAN &gt
SOUTHERN OCEAN
description This study assessed the performance of diffusive gradients in thin-films (DGT) with a binding resin that used Chelex-100 (iminodiacetic acid functional groups) to measure cadmium, copper, nickel, lead, and zinc contaminants in Antarctic marine conditions. To do this, three sets of experiments were done: (I) the uptake of metals to DGT samplers was assessed over time when deployed to three metal mixtures of known concentrations (DGT performance page). This allowed for the determination of metal diffusion coefficients in Antarctic marine conditions and demonstrated when metal competition for binding sites were likely to occur. (II) the DGT were deployed in the presence of the microalga Phaeocystis antarctica at a concentration of 1000-3000 cells/mL to investigate how environmentally realistic concentrations of an Antarctic marine microalgae affect the uptake of metals (DGT uptake with algae page). Finally, the DGT-labile concentrations from part (II) were used in reference toxicity mixture models to predict toxicity to the microalgae so they could be compared to a previous study that investigated the toxicity of metal mixtures to Phaeocystis antarctica and Cryothecomonas armigera (DGT toxicity modelling page). These laboratory experiments investigate the applicability of DGT to measure the common metal contaminants cadmium, copper, nickel, lead, and zinc in conditions reflective of the Antarctic marine environment. These experiments determine the diffusion coefficients necessary to calculate DGT-labile concentrations in field deployments, identifies the influence of microalgae to the accumulation of metals, determines the concentration at which metal-metal competition is likely on the binding resin, and demonstrates the use of DGT-labile concentrations in contaminant mixture reference models to predict toxicities to two Antarctic marine microalgae.
author2 AADC (originator)
AU/AADC > Australian Antarctic Data Centre, Australia (resourceProvider)
format Dataset
title Assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in Antarctic marine waters
title_short Assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in Antarctic marine waters
title_full Assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in Antarctic marine waters
title_fullStr Assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in Antarctic marine waters
title_full_unstemmed Assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in Antarctic marine waters
title_sort assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in antarctic marine waters
publisher Australian Ocean Data Network
url https://researchdata.ands.org.au/assessment-performance-diffusive-marine-waters/1358662
https://data.aad.gov.au/metadata/records/AAS_4326_DGTvalidation
https://data.aad.gov.au/aadc/metadata/citation.cfm?entry_id=AAS_4326_DGTvalidation
https://data.aad.gov.au/eds/4811/download
https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=AAS_4326
https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=4326
op_coverage Spatial: northlimit=-48.16243; southlimit=-66.79191; westlimit=14.0625; eastLimit=166.64063
Temporal: From 2017-06-15 to 2017-06-22
long_lat ENVELOPE(14.0625,166.64063,-48.16243,-66.79191)
geographic Antarctic
Southern Ocean
The Antarctic
New Zealand
geographic_facet Antarctic
Southern Ocean
The Antarctic
New Zealand
genre Antarc*
Antarctic
Antarctica
Southern Ocean
genre_facet Antarc*
Antarctic
Antarctica
Southern Ocean
op_source https://data.aad.gov.au
op_relation https://researchdata.ands.org.au/assessment-performance-diffusive-marine-waters/1358662
b6ad6c3c-c4ba-4f6e-9ff7-15eeec85717d
https://data.aad.gov.au/metadata/records/AAS_4326_DGTvalidation
https://data.aad.gov.au/aadc/metadata/citation.cfm?entry_id=AAS_4326_DGTvalidation
https://data.aad.gov.au/eds/4811/download
https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=AAS_4326
https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=4326
_version_ 1766247711998214144
spelling ftands:oai:ands.org.au::1358662 2023-05-15T13:47:42+02:00 Assessment of the performance of diffusive gradients in thin-films for metal contaminant measurements in Antarctic marine waters AADC (originator) AU/AADC > Australian Antarctic Data Centre, Australia (resourceProvider) Spatial: northlimit=-48.16243; southlimit=-66.79191; westlimit=14.0625; eastLimit=166.64063 Temporal: From 2017-06-15 to 2017-06-22 https://researchdata.ands.org.au/assessment-performance-diffusive-marine-waters/1358662 https://data.aad.gov.au/metadata/records/AAS_4326_DGTvalidation https://data.aad.gov.au/aadc/metadata/citation.cfm?entry_id=AAS_4326_DGTvalidation https://data.aad.gov.au/eds/4811/download https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=AAS_4326 https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=4326 unknown Australian Ocean Data Network https://researchdata.ands.org.au/assessment-performance-diffusive-marine-waters/1358662 b6ad6c3c-c4ba-4f6e-9ff7-15eeec85717d https://data.aad.gov.au/metadata/records/AAS_4326_DGTvalidation https://data.aad.gov.au/aadc/metadata/citation.cfm?entry_id=AAS_4326_DGTvalidation https://data.aad.gov.au/eds/4811/download https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=AAS_4326 https://secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=4326 https://data.aad.gov.au environment oceans TRACE METALS EARTH SCIENCE TERRESTRIAL HYDROSPHERE WATER QUALITY/WATER CHEMISTRY MARINE ENVIRONMENT MONITORING CONTAMINANT LEVELS/SPILLS HUMAN DIMENSIONS ENVIRONMENTAL IMPACTS TOXICITY LEVELS BIOSPHERE ECOLOGICAL DYNAMICS ECOTOXICOLOGY ENVIRONMENTAL MONITORING DIFFUSIVE GRADIENTS IN THIN-FILMS ICP-AES &gt Inductively Coupled Plasma Atomic Emission Spectrometer ICP-MS &gt Inductively Coupled Plasma Mass Spectrometer LABORATORY AMD/AU AMD CEOS CONTINENT &gt AUSTRALIA/NEW ZEALAND &gt AUSTRALIA GEOGRAPHIC REGION &gt POLAR ANTARCTICA OCEAN &gt SOUTHERN OCEAN dataset ftands 2020-01-05T22:19:52Z This study assessed the performance of diffusive gradients in thin-films (DGT) with a binding resin that used Chelex-100 (iminodiacetic acid functional groups) to measure cadmium, copper, nickel, lead, and zinc contaminants in Antarctic marine conditions. To do this, three sets of experiments were done: (I) the uptake of metals to DGT samplers was assessed over time when deployed to three metal mixtures of known concentrations (DGT performance page). This allowed for the determination of metal diffusion coefficients in Antarctic marine conditions and demonstrated when metal competition for binding sites were likely to occur. (II) the DGT were deployed in the presence of the microalga Phaeocystis antarctica at a concentration of 1000-3000 cells/mL to investigate how environmentally realistic concentrations of an Antarctic marine microalgae affect the uptake of metals (DGT uptake with algae page). Finally, the DGT-labile concentrations from part (II) were used in reference toxicity mixture models to predict toxicity to the microalgae so they could be compared to a previous study that investigated the toxicity of metal mixtures to Phaeocystis antarctica and Cryothecomonas armigera (DGT toxicity modelling page). These laboratory experiments investigate the applicability of DGT to measure the common metal contaminants cadmium, copper, nickel, lead, and zinc in conditions reflective of the Antarctic marine environment. These experiments determine the diffusion coefficients necessary to calculate DGT-labile concentrations in field deployments, identifies the influence of microalgae to the accumulation of metals, determines the concentration at which metal-metal competition is likely on the binding resin, and demonstrates the use of DGT-labile concentrations in contaminant mixture reference models to predict toxicities to two Antarctic marine microalgae. Dataset Antarc* Antarctic Antarctica Southern Ocean Research Data Australia (Australian National Data Service - ANDS) Antarctic Southern Ocean The Antarctic New Zealand ENVELOPE(14.0625,166.64063,-48.16243,-66.79191)