Hemispheric asymmetry in stratospheric NO2 trends
Over 20 years of stratospheric NO2 vertical column density (VCD) data from ground-based zenith DOAS spectrometers were used for trend analysis, specifically, via multiple linear regression. Spectrometers from the Network for the Detection of Atmospheric Composition Change (NDACC) cover the subtropic...
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Language: | English |
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European Geosciences Union
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ftaemet:oai:repositorio.aemet.es:20.500.11765/7043 2024-06-23T07:46:40+00:00 Hemispheric asymmetry in stratospheric NO2 trends Yela González, Margarita Gil-Ojeda, Manuel Navarro Comas, Mónica González-Bartolome, David Puentedura, Olga Funke, Bernd Iglesias, Javier Rodríguez, Santiago García Rodríguez, Omaira Elena Ochoa, Hector Deferrari, Guillermo 2017 https://hdl.handle.net/20.500.11765/7043 eng eng European Geosciences Union https://dx.doi.org/10.5194/acp-17-13373-2017 info:eu-repo/grantAgreement/EC/FP7/284421 Atmospheric Chemistry and Physics. 2017, 17(21), p. 13373–13389 1680-7316 1680-7324 http://hdl.handle.net/20.500.11765/7043 Licencia CC: Reconocimiento CC BY info:eu-repo/semantics/openAccess Nitrogen dioxide Stratospheric trends Ozone Differential optical absorption spectroscopy (DOAS) Dióxido de nitrógeno Ozono Espectroscopía Óptica de Absorción Diferencial info:eu-repo/semantics/article 2017 ftaemet https://doi.org/20.500.11765/704310.5194/acp-17-13373-2017 2024-06-03T14:17:56Z Over 20 years of stratospheric NO2 vertical column density (VCD) data from ground-based zenith DOAS spectrometers were used for trend analysis, specifically, via multiple linear regression. Spectrometers from the Network for the Detection of Atmospheric Composition Change (NDACC) cover the subtropical latitudes in the Northern Hemisphere (Izaña, 28° N), the southern Subantarctic (Ushuaia, 55° S) and Antarctica (Marambio, 64° S, and Belgrano, 78° S). The results show that for the period 1993–2014, a mean positive decadal trend of +8.7 % was found in the subtropical Northern Hemisphere stations, and negative decadal trends of −8.7 and −13.8 % were found in the Southern Hemisphere at Ushuaia and Marambio, respectively; all trends are statistically significant at 95 %. Belgrano only shows a significant decadal trend of −11.3 % in the summer/autumn period. Most of the trends result from variations after 2005. The trend in the diurnal build-up per hour (DBU) was used to estimate the change in the rate of N2O5 conversion to NO2 during the day. With minor differences, the results reproduce those obtained for NO2. The trends computed for individual months show large month-to-month variability. At Izaña, the maximum occurs in December (+13.1 %), dropping abruptly to lower values in the first part of the year. In the Southern Hemisphere, the polar vortex dominates the monthly distributions of the trends. At Marambio, the maximum occurs in mid-winter (−21 %), whereas at the same time, the Ushuaia trend is close to its annual minimum (−7 %). The large difference in the trends at these two relatively close stations suggests a vortex shift towards the Atlantic/South American area over the past few years. Finally, the hemispheric asymmetry obtained in this work is discussed in the framework of the results obtained by previous works that considered tracer analysis and Brewer–Dobson circulation. The results obtained here provide evidence that the NO2 produced by N2O decomposition is not the only cause of the observed trend in the ... Article in Journal/Newspaper Antarc* Antarctica ARCIMÍS (Archivo Climatológico y Meteorológico Institucional - AEMET, Agencia Estatal de Meteorología) Marambio ENVELOPE(-56.750,-56.750,-64.283,-64.283) Ushuaia ENVELOPE(-40.000,-40.000,-82.167,-82.167) Belgrano ENVELOPE(-64.967,-64.967,-65.150,-65.150) Atmospheric Chemistry and Physics 17 21 13373 13389 |
institution |
Open Polar |
collection |
ARCIMÍS (Archivo Climatológico y Meteorológico Institucional - AEMET, Agencia Estatal de Meteorología) |
op_collection_id |
ftaemet |
language |
English |
topic |
Nitrogen dioxide Stratospheric trends Ozone Differential optical absorption spectroscopy (DOAS) Dióxido de nitrógeno Ozono Espectroscopía Óptica de Absorción Diferencial |
spellingShingle |
Nitrogen dioxide Stratospheric trends Ozone Differential optical absorption spectroscopy (DOAS) Dióxido de nitrógeno Ozono Espectroscopía Óptica de Absorción Diferencial Yela González, Margarita Gil-Ojeda, Manuel Navarro Comas, Mónica González-Bartolome, David Puentedura, Olga Funke, Bernd Iglesias, Javier Rodríguez, Santiago García Rodríguez, Omaira Elena Ochoa, Hector Deferrari, Guillermo Hemispheric asymmetry in stratospheric NO2 trends |
topic_facet |
Nitrogen dioxide Stratospheric trends Ozone Differential optical absorption spectroscopy (DOAS) Dióxido de nitrógeno Ozono Espectroscopía Óptica de Absorción Diferencial |
description |
Over 20 years of stratospheric NO2 vertical column density (VCD) data from ground-based zenith DOAS spectrometers were used for trend analysis, specifically, via multiple linear regression. Spectrometers from the Network for the Detection of Atmospheric Composition Change (NDACC) cover the subtropical latitudes in the Northern Hemisphere (Izaña, 28° N), the southern Subantarctic (Ushuaia, 55° S) and Antarctica (Marambio, 64° S, and Belgrano, 78° S). The results show that for the period 1993–2014, a mean positive decadal trend of +8.7 % was found in the subtropical Northern Hemisphere stations, and negative decadal trends of −8.7 and −13.8 % were found in the Southern Hemisphere at Ushuaia and Marambio, respectively; all trends are statistically significant at 95 %. Belgrano only shows a significant decadal trend of −11.3 % in the summer/autumn period. Most of the trends result from variations after 2005. The trend in the diurnal build-up per hour (DBU) was used to estimate the change in the rate of N2O5 conversion to NO2 during the day. With minor differences, the results reproduce those obtained for NO2. The trends computed for individual months show large month-to-month variability. At Izaña, the maximum occurs in December (+13.1 %), dropping abruptly to lower values in the first part of the year. In the Southern Hemisphere, the polar vortex dominates the monthly distributions of the trends. At Marambio, the maximum occurs in mid-winter (−21 %), whereas at the same time, the Ushuaia trend is close to its annual minimum (−7 %). The large difference in the trends at these two relatively close stations suggests a vortex shift towards the Atlantic/South American area over the past few years. Finally, the hemispheric asymmetry obtained in this work is discussed in the framework of the results obtained by previous works that considered tracer analysis and Brewer–Dobson circulation. The results obtained here provide evidence that the NO2 produced by N2O decomposition is not the only cause of the observed trend in the ... |
format |
Article in Journal/Newspaper |
author |
Yela González, Margarita Gil-Ojeda, Manuel Navarro Comas, Mónica González-Bartolome, David Puentedura, Olga Funke, Bernd Iglesias, Javier Rodríguez, Santiago García Rodríguez, Omaira Elena Ochoa, Hector Deferrari, Guillermo |
author_facet |
Yela González, Margarita Gil-Ojeda, Manuel Navarro Comas, Mónica González-Bartolome, David Puentedura, Olga Funke, Bernd Iglesias, Javier Rodríguez, Santiago García Rodríguez, Omaira Elena Ochoa, Hector Deferrari, Guillermo |
author_sort |
Yela González, Margarita |
title |
Hemispheric asymmetry in stratospheric NO2 trends |
title_short |
Hemispheric asymmetry in stratospheric NO2 trends |
title_full |
Hemispheric asymmetry in stratospheric NO2 trends |
title_fullStr |
Hemispheric asymmetry in stratospheric NO2 trends |
title_full_unstemmed |
Hemispheric asymmetry in stratospheric NO2 trends |
title_sort |
hemispheric asymmetry in stratospheric no2 trends |
publisher |
European Geosciences Union |
publishDate |
2017 |
url |
https://hdl.handle.net/20.500.11765/7043 |
long_lat |
ENVELOPE(-56.750,-56.750,-64.283,-64.283) ENVELOPE(-40.000,-40.000,-82.167,-82.167) ENVELOPE(-64.967,-64.967,-65.150,-65.150) |
geographic |
Marambio Ushuaia Belgrano |
geographic_facet |
Marambio Ushuaia Belgrano |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
https://dx.doi.org/10.5194/acp-17-13373-2017 info:eu-repo/grantAgreement/EC/FP7/284421 Atmospheric Chemistry and Physics. 2017, 17(21), p. 13373–13389 1680-7316 1680-7324 http://hdl.handle.net/20.500.11765/7043 |
op_rights |
Licencia CC: Reconocimiento CC BY info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/20.500.11765/704310.5194/acp-17-13373-2017 |
container_title |
Atmospheric Chemistry and Physics |
container_volume |
17 |
container_issue |
21 |
container_start_page |
13373 |
op_container_end_page |
13389 |
_version_ |
1802647457781252096 |