WHONDRS Surface Water and Sediment Non-Purgeable Organic Carbon and FTICR-MS across Glacial Features in Svalbard 2021

• Main Authors: Sophia A. McKever, Rosalie Chu, Robert E Danczak, Brieanne Forbes, Vanessa A. Garayburu-Caruso, Amy E. Goldman, Andrew Hodson, Gabrielle Kleber, Leonard Magerl, Lupita Renteria, Jason G. Toyoda, Jacob Yde, James C. Stegen
• Format: Dataset
• Language: unknown
• Published: ESS-DIVE: Deep Insight for Earth Science Data 2022
• Subjects: River corridor; Freshwater; River; Stream; Sediment; Watershed; Biogeochemistry; Hydrobiogeochemical function; Organic matter; Hyporheic zone; Metabolite; Metabolomics; Mass spectrometry; Cryoconite; Spring; NPOC; Non-purgeable organic carbon; FTICR-MS; EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > SURFACE WATER; EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > GROUND WATER; EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > GLACIERS/ICE SHEETS; EARTH SCIENCE > CRYOSPHERE > GLACIERS/ICE SHEETS; Svalbard; Norway; Foxfonna; Majorfjellet; Scheelebreen; Vallåkrabreen; glacier; Ice; permafrost
• Online Access: https://search.dataone.org/view/ess-dive-d200b2f70eb970d-20230404T150244216

This dataset supports a broader study examining climatic forcing of terrestrial greenhouse gas emission through permafrost and glaciers in Svalbard. The dataset provides geochemistry and organic matter characterization data generated from surface water and sediment. Samples were collected from 8 spatially diverse sites across central Svalbard and also from a more comprehensive temporal and spatial study within one glacial catchment area throughout one summer melt season. Related data were collected and will be published separately in collaboration with Yde and Kleber. This dataset is comprised of one main data folder containing (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) dissolved organic carbon (DOC; measured as non-purgeable organic carbon; NPOC); (5) surface water sampling protocol; (6) sediment extraction protocol; (7) readme; (8) methods codes; (9) international geo-sample number (IGSN) mapping file; and (10) folder of high resolution characterization of organic matter via 7 and 12 Tesla (7T and 12T) Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) generated through the Environmental Molecular Sciences Laboratory (EMSL; https://www.pnnl.gov/environmental-molecular-sciences-laboratory). The FTICR folder contains two subfolders containing the 7T and 12T .xml data files and another subfolder containing instructions for using Formularity (https://omics.pnl.gov/software/formularity) and an R script to process the data based on the user's specific needs. All files are .csv, .pdf, .R, .ref, or .xml. This data package was originally published in September 2022. It was updated in March 2023. See the change history section in the data package readme for more details. Please refer to the data package readme and FTICR readme for guidance on using the FTICR data.