Lipase‐Catalyzed Synthesis of d‐Psicose Fatty Acid Diesters and their Emulsification Activities
Abstract The diesterification of d ‐psicose (the C‐3 epimer of d ‐fructose) with fatty acid vinyl esters of selected acyl chain lengths (C 8 , C 10 , and C 12 ) was successfully carried out using Candida antarctica lipase (Novozym 435) at 45 °C for 24 h to give the 1,6‐diacyl‐ d ‐psicofuranoses with...
Published in: | Journal of the American Oil Chemists' Society |
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crwiley:10.1007/s11746-008-1242-x 2024-06-02T07:56:27+00:00 Lipase‐Catalyzed Synthesis of d‐Psicose Fatty Acid Diesters and their Emulsification Activities Afach, Ghanwa Kawanami, Yasuhiro Cheetangdee, Nopparat Fukada, Kazuhiro Izumori, Ken 2008 http://dx.doi.org/10.1007/s11746-008-1242-x https://onlinelibrary.wiley.com/doi/full/10.1007/s11746-008-1242-x en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Journal of the American Oil Chemists' Society volume 85, issue 8, page 755-760 ISSN 0003-021X 1558-9331 journal-article 2008 crwiley https://doi.org/10.1007/s11746-008-1242-x 2024-05-03T10:59:35Z Abstract The diesterification of d ‐psicose (the C‐3 epimer of d ‐fructose) with fatty acid vinyl esters of selected acyl chain lengths (C 8 , C 10 , and C 12 ) was successfully carried out using Candida antarctica lipase (Novozym 435) at 45 °C for 24 h to give the 1,6‐diacyl‐ d ‐psicofuranoses with a high regioselectivity in good yields (83–90%). These diesters of d ‐psicose have hydrophilic‐lipophilic balance (HLB) values (6.5–8.2) similar to HLB values of monoglyceride compounds which constitute the largest single type of emulsifiers employed by the food industry. Ability of the d ‐psicose diesters to stabilize oil‐in‐water emulsions and the weight‐averaged oil‐droplet diameter in the emulsions was evaluated in this study. Emulsion stability of oil droplets stabilized by d ‐psicose dicaprylate (0.3%, w/v in oil phase) was comparable to d ‐fructose dicaprylate (0.2%, w/v). It was further confirmed that the d ‐psicose diesters exhibited an emulsification activity depending on the chain length of fatty acid; d ‐psicose dicaprate showed better emulsion stability than the other diesters. Article in Journal/Newspaper Antarc* Antarctica Wiley Online Library Journal of the American Oil Chemists' Society 85 8 755 760 |
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Wiley Online Library |
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language |
English |
description |
Abstract The diesterification of d ‐psicose (the C‐3 epimer of d ‐fructose) with fatty acid vinyl esters of selected acyl chain lengths (C 8 , C 10 , and C 12 ) was successfully carried out using Candida antarctica lipase (Novozym 435) at 45 °C for 24 h to give the 1,6‐diacyl‐ d ‐psicofuranoses with a high regioselectivity in good yields (83–90%). These diesters of d ‐psicose have hydrophilic‐lipophilic balance (HLB) values (6.5–8.2) similar to HLB values of monoglyceride compounds which constitute the largest single type of emulsifiers employed by the food industry. Ability of the d ‐psicose diesters to stabilize oil‐in‐water emulsions and the weight‐averaged oil‐droplet diameter in the emulsions was evaluated in this study. Emulsion stability of oil droplets stabilized by d ‐psicose dicaprylate (0.3%, w/v in oil phase) was comparable to d ‐fructose dicaprylate (0.2%, w/v). It was further confirmed that the d ‐psicose diesters exhibited an emulsification activity depending on the chain length of fatty acid; d ‐psicose dicaprate showed better emulsion stability than the other diesters. |
format |
Article in Journal/Newspaper |
author |
Afach, Ghanwa Kawanami, Yasuhiro Cheetangdee, Nopparat Fukada, Kazuhiro Izumori, Ken |
spellingShingle |
Afach, Ghanwa Kawanami, Yasuhiro Cheetangdee, Nopparat Fukada, Kazuhiro Izumori, Ken Lipase‐Catalyzed Synthesis of d‐Psicose Fatty Acid Diesters and their Emulsification Activities |
author_facet |
Afach, Ghanwa Kawanami, Yasuhiro Cheetangdee, Nopparat Fukada, Kazuhiro Izumori, Ken |
author_sort |
Afach, Ghanwa |
title |
Lipase‐Catalyzed Synthesis of d‐Psicose Fatty Acid Diesters and their Emulsification Activities |
title_short |
Lipase‐Catalyzed Synthesis of d‐Psicose Fatty Acid Diesters and their Emulsification Activities |
title_full |
Lipase‐Catalyzed Synthesis of d‐Psicose Fatty Acid Diesters and their Emulsification Activities |
title_fullStr |
Lipase‐Catalyzed Synthesis of d‐Psicose Fatty Acid Diesters and their Emulsification Activities |
title_full_unstemmed |
Lipase‐Catalyzed Synthesis of d‐Psicose Fatty Acid Diesters and their Emulsification Activities |
title_sort |
lipase‐catalyzed synthesis of d‐psicose fatty acid diesters and their emulsification activities |
publisher |
Wiley |
publishDate |
2008 |
url |
http://dx.doi.org/10.1007/s11746-008-1242-x https://onlinelibrary.wiley.com/doi/full/10.1007/s11746-008-1242-x |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
Journal of the American Oil Chemists' Society volume 85, issue 8, page 755-760 ISSN 0003-021X 1558-9331 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1007/s11746-008-1242-x |
container_title |
Journal of the American Oil Chemists' Society |
container_volume |
85 |
container_issue |
8 |
container_start_page |
755 |
op_container_end_page |
760 |
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1800756141159874560 |