Cyclisierungsreaktionen β,γ‐ungesättigter Kohlensäurederivate. X. Reaktionen von N‐Cinnamylcarbamidsäureestern mit Sulfenylchloriden‐Synthese von 3, 5‐disubstituierten Oxazolidin‐2‐onen

Cyclization Reactions of β,γ‐Unsaturated Derivatives of Carbonic Acid. X. Reaction of N‐Cinnamyl Carbamic Acid Esters with Sulfenyl Chlorides—Synthesis of 3,5‐Disubstituted Oxazolidine‐2‐ones N‐Cinnamyl urethanes 1 have been cyclized to 3,5‐disubstituted oxazolidine‐2‐ones 3 by aromatic sulfenyl chl...

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Bibliographic Details
Published in:Journal für Praktische Chemie
Main Authors: Mühlstädt, M., Olk, B., Widera, R.
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 1986
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Online Access:http://dx.doi.org/10.1002/prac.19863280205
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Summary:Cyclization Reactions of β,γ‐Unsaturated Derivatives of Carbonic Acid. X. Reaction of N‐Cinnamyl Carbamic Acid Esters with Sulfenyl Chlorides—Synthesis of 3,5‐Disubstituted Oxazolidine‐2‐ones N‐Cinnamyl urethanes 1 have been cyclized to 3,5‐disubstituted oxazolidine‐2‐ones 3 by aromatic sulfenyl chlorides in methylene chloride. The tetrahydro‐2H‐1,3‐oxazine‐2‐ones 6 were obtained by reaction of 5‐bromotetrahydro‐2H‐1,3‐oxazine‐2‐ones 8 with thiophenols.