Nucleophile Substitutionen an Kohlensäurederivaten. XIX. Alkoholyse und Hydrolyse des Bis(trichlormethyl)carbonates
Nucleophilic Substitutions at Carbonic Acid Derivatives. XIX. Alcoholysis and Hydrolysis of Bis(trichloromethyl)carbonate The rate constants of hydrolysis and alcoholysis of bis(trichlormethyl)carbonate in xan have been determinated conductometrically. The effects of the water and alcohol concentrat...
Published in: | Journal für Praktische Chemie |
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Main Authors: | , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Wiley
1985
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Subjects: | |
Online Access: | http://dx.doi.org/10.1002/prac.19853270602 http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fprac.19853270602 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fprac.19853270602 https://onlinelibrary.wiley.com/doi/pdf/10.1002/prac.19853270602 |
Summary: | Nucleophilic Substitutions at Carbonic Acid Derivatives. XIX. Alcoholysis and Hydrolysis of Bis(trichloromethyl)carbonate The rate constants of hydrolysis and alcoholysis of bis(trichlormethyl)carbonate in xan have been determinated conductometrically. The effects of the water and alcohol concentrations, the temperature and deuterium have been studied. By the hydrolysis and alcoholysis of bis(trichlormethyl)carbonate the nucleophilic attack of water and alcohol is the rate‐determining step, followed by a fast elimination of unstable trichloro‐methanol. |
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