Nucleophile Substitutionen an funktionellen Kohlensäurederivaten. XVI. Kinetik und Mechanismus der Hydrolyse von Kohlensäure‐ N,N,N′‐triphenylchloramidin
Nucleophilic Substitution to Carbonic Acid Derivatives. XVI. Kinetics and Mechanism of N,N,N′‐Triphenylchloroformamidin Hydrolysis First order rate constants of N,N,N′‐triphenylchloroformic amidine hydrolysis in dioxane‐water have been determined by u.v.‐spectroscopy. The effects of water concentrat...
Published in: | Journal für Praktische Chemie |
---|---|
Main Authors: | , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Wiley
1982
|
Subjects: | |
Online Access: | http://dx.doi.org/10.1002/prac.19823240504 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fprac.19823240504 https://onlinelibrary.wiley.com/doi/pdf/10.1002/prac.19823240504 |
id |
crwiley:10.1002/prac.19823240504 |
---|---|
record_format |
openpolar |
spelling |
crwiley:10.1002/prac.19823240504 2024-06-02T08:05:11+00:00 Nucleophile Substitutionen an funktionellen Kohlensäurederivaten. XVI. Kinetik und Mechanismus der Hydrolyse von Kohlensäure‐ N,N,N′‐triphenylchloramidin Bacaloglu, R. Bacaloglu, I. Chicu, A. 1982 http://dx.doi.org/10.1002/prac.19823240504 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fprac.19823240504 https://onlinelibrary.wiley.com/doi/pdf/10.1002/prac.19823240504 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Journal für Praktische Chemie volume 324, issue 5, page 717-724 ISSN 0021-8383 journal-article 1982 crwiley https://doi.org/10.1002/prac.19823240504 2024-05-03T10:48:59Z Nucleophilic Substitution to Carbonic Acid Derivatives. XVI. Kinetics and Mechanism of N,N,N′‐Triphenylchloroformamidin Hydrolysis First order rate constants of N,N,N′‐triphenylchloroformic amidine hydrolysis in dioxane‐water have been determined by u.v.‐spectroscopy. The effects of water concentration, addition of KClO 4 , LiCl, HgCl 2 , and AgNO 3 or nucleophilic agents (piperidine) as well as isotopic effects have been investigated. Activation entropy and enthalpy have been determined. According to the data obtained the reaction takes place in two steps – chlorionization and reaction of the formed cation with the nucleophilic agent. Both steps have rates of the same order of magnitude, but can become slow steps in specific conditions. Article in Journal/Newspaper Carbonic acid Wiley Online Library Journal für Praktische Chemie 324 5 717 724 |
institution |
Open Polar |
collection |
Wiley Online Library |
op_collection_id |
crwiley |
language |
English |
description |
Nucleophilic Substitution to Carbonic Acid Derivatives. XVI. Kinetics and Mechanism of N,N,N′‐Triphenylchloroformamidin Hydrolysis First order rate constants of N,N,N′‐triphenylchloroformic amidine hydrolysis in dioxane‐water have been determined by u.v.‐spectroscopy. The effects of water concentration, addition of KClO 4 , LiCl, HgCl 2 , and AgNO 3 or nucleophilic agents (piperidine) as well as isotopic effects have been investigated. Activation entropy and enthalpy have been determined. According to the data obtained the reaction takes place in two steps – chlorionization and reaction of the formed cation with the nucleophilic agent. Both steps have rates of the same order of magnitude, but can become slow steps in specific conditions. |
format |
Article in Journal/Newspaper |
author |
Bacaloglu, R. Bacaloglu, I. Chicu, A. |
spellingShingle |
Bacaloglu, R. Bacaloglu, I. Chicu, A. Nucleophile Substitutionen an funktionellen Kohlensäurederivaten. XVI. Kinetik und Mechanismus der Hydrolyse von Kohlensäure‐ N,N,N′‐triphenylchloramidin |
author_facet |
Bacaloglu, R. Bacaloglu, I. Chicu, A. |
author_sort |
Bacaloglu, R. |
title |
Nucleophile Substitutionen an funktionellen Kohlensäurederivaten. XVI. Kinetik und Mechanismus der Hydrolyse von Kohlensäure‐ N,N,N′‐triphenylchloramidin |
title_short |
Nucleophile Substitutionen an funktionellen Kohlensäurederivaten. XVI. Kinetik und Mechanismus der Hydrolyse von Kohlensäure‐ N,N,N′‐triphenylchloramidin |
title_full |
Nucleophile Substitutionen an funktionellen Kohlensäurederivaten. XVI. Kinetik und Mechanismus der Hydrolyse von Kohlensäure‐ N,N,N′‐triphenylchloramidin |
title_fullStr |
Nucleophile Substitutionen an funktionellen Kohlensäurederivaten. XVI. Kinetik und Mechanismus der Hydrolyse von Kohlensäure‐ N,N,N′‐triphenylchloramidin |
title_full_unstemmed |
Nucleophile Substitutionen an funktionellen Kohlensäurederivaten. XVI. Kinetik und Mechanismus der Hydrolyse von Kohlensäure‐ N,N,N′‐triphenylchloramidin |
title_sort |
nucleophile substitutionen an funktionellen kohlensäurederivaten. xvi. kinetik und mechanismus der hydrolyse von kohlensäure‐ n,n,n′‐triphenylchloramidin |
publisher |
Wiley |
publishDate |
1982 |
url |
http://dx.doi.org/10.1002/prac.19823240504 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fprac.19823240504 https://onlinelibrary.wiley.com/doi/pdf/10.1002/prac.19823240504 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Journal für Praktische Chemie volume 324, issue 5, page 717-724 ISSN 0021-8383 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/prac.19823240504 |
container_title |
Journal für Praktische Chemie |
container_volume |
324 |
container_issue |
5 |
container_start_page |
717 |
op_container_end_page |
724 |
_version_ |
1800749968613441536 |