A convenient route to PHB macromonomers via anionically controlled moderate‐temperature degradation of PHB
Abstract The degradation of poly(3‐hydroxybutyrate)s in homo‐ and heterogeneous mixtures with selected salts of organic and mineral acids was investigated. Nonvolatile degradation products, of processes conducted at moderate temperatures (150–170 °C), were analyzed using 1 H NMR. Analysis of results...
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crwiley:10.1002/pola.24357 2024-09-15T18:01:36+00:00 A convenient route to PHB macromonomers via anionically controlled moderate‐temperature degradation of PHB kawalec, Michał Sobota, Michał Scandola, Mariastella Kowalczuk, Marek Kurcok, Piotr 2010 http://dx.doi.org/10.1002/pola.24357 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpola.24357 https://onlinelibrary.wiley.com/doi/pdf/10.1002/pola.24357 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Journal of Polymer Science Part A: Polymer Chemistry volume 48, issue 23, page 5490-5497 ISSN 0887-624X 1099-0518 journal-article 2010 crwiley https://doi.org/10.1002/pola.24357 2024-08-13T04:15:35Z Abstract The degradation of poly(3‐hydroxybutyrate)s in homo‐ and heterogeneous mixtures with selected salts of organic and mineral acids was investigated. Nonvolatile degradation products, of processes conducted at moderate temperatures (150–170 °C), were analyzed using 1 H NMR. Analysis of results revealed a significant decrease in poly([ R ]‐3‐hydroxybutyrate) (PHB) thermal stability in the presence of acetic acid and carbonic acid salts of alkali metals (Cs, K, Li) as well as a less substantial effect with respect to bivalent metal (Ca, Mg, Zn) salts. This significant decrease in PHB thermal stability in the presence of salts of weak Bronsted‐Lowry acids can be explained in terms of an anionic degradation reaction proceeding via an E1cB mechanism. Furthermore, continuous poly(3‐hydroxybutyrate) controlled degradation was developed by a moderate‐temperature process using carbonic acid salts as “initiators” of anionic degradation. Foamed PHB macromonomers, bearing one crotonate terminal group, were obtainable via a reactive extrusion process. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 Article in Journal/Newspaper Carbonic acid Wiley Online Library Journal of Polymer Science Part A: Polymer Chemistry 48 23 5490 5497 |
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English |
description |
Abstract The degradation of poly(3‐hydroxybutyrate)s in homo‐ and heterogeneous mixtures with selected salts of organic and mineral acids was investigated. Nonvolatile degradation products, of processes conducted at moderate temperatures (150–170 °C), were analyzed using 1 H NMR. Analysis of results revealed a significant decrease in poly([ R ]‐3‐hydroxybutyrate) (PHB) thermal stability in the presence of acetic acid and carbonic acid salts of alkali metals (Cs, K, Li) as well as a less substantial effect with respect to bivalent metal (Ca, Mg, Zn) salts. This significant decrease in PHB thermal stability in the presence of salts of weak Bronsted‐Lowry acids can be explained in terms of an anionic degradation reaction proceeding via an E1cB mechanism. Furthermore, continuous poly(3‐hydroxybutyrate) controlled degradation was developed by a moderate‐temperature process using carbonic acid salts as “initiators” of anionic degradation. Foamed PHB macromonomers, bearing one crotonate terminal group, were obtainable via a reactive extrusion process. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 |
format |
Article in Journal/Newspaper |
author |
kawalec, Michał Sobota, Michał Scandola, Mariastella Kowalczuk, Marek Kurcok, Piotr |
spellingShingle |
kawalec, Michał Sobota, Michał Scandola, Mariastella Kowalczuk, Marek Kurcok, Piotr A convenient route to PHB macromonomers via anionically controlled moderate‐temperature degradation of PHB |
author_facet |
kawalec, Michał Sobota, Michał Scandola, Mariastella Kowalczuk, Marek Kurcok, Piotr |
author_sort |
kawalec, Michał |
title |
A convenient route to PHB macromonomers via anionically controlled moderate‐temperature degradation of PHB |
title_short |
A convenient route to PHB macromonomers via anionically controlled moderate‐temperature degradation of PHB |
title_full |
A convenient route to PHB macromonomers via anionically controlled moderate‐temperature degradation of PHB |
title_fullStr |
A convenient route to PHB macromonomers via anionically controlled moderate‐temperature degradation of PHB |
title_full_unstemmed |
A convenient route to PHB macromonomers via anionically controlled moderate‐temperature degradation of PHB |
title_sort |
convenient route to phb macromonomers via anionically controlled moderate‐temperature degradation of phb |
publisher |
Wiley |
publishDate |
2010 |
url |
http://dx.doi.org/10.1002/pola.24357 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpola.24357 https://onlinelibrary.wiley.com/doi/pdf/10.1002/pola.24357 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Journal of Polymer Science Part A: Polymer Chemistry volume 48, issue 23, page 5490-5497 ISSN 0887-624X 1099-0518 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/pola.24357 |
container_title |
Journal of Polymer Science Part A: Polymer Chemistry |
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48 |
container_issue |
23 |
container_start_page |
5490 |
op_container_end_page |
5497 |
_version_ |
1810438721879670784 |