Lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one
Abstract Enzymatic ring‐opening polymerization of a 6‐membered cyclic carbonate, 1,3‐dioxan‐2‐one, was investigated by using lipase as catalyst in bulk. Supported lipase derived from Candida antarctica catalyzed the polymerization to give the corresponding aliphatic polycarbonate. Unchanged monomer...
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crwiley:10.1002/marc.1997.030180707 2024-06-02T07:57:40+00:00 Lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one Kobayashi, Shiro Kikuchi, Hirofumi Uyama, Hiroshi 1997 http://dx.doi.org/10.1002/marc.1997.030180707 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmarc.1997.030180707 https://onlinelibrary.wiley.com/doi/pdf/10.1002/marc.1997.030180707 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Macromolecular Rapid Communications volume 18, issue 7, page 575-579 ISSN 1022-1336 1521-3927 journal-article 1997 crwiley https://doi.org/10.1002/marc.1997.030180707 2024-05-03T11:58:10Z Abstract Enzymatic ring‐opening polymerization of a 6‐membered cyclic carbonate, 1,3‐dioxan‐2‐one, was investigated by using lipase as catalyst in bulk. Supported lipase derived from Candida antarctica catalyzed the polymerization to give the corresponding aliphatic polycarbonate. Unchanged monomer was recovered in the absence of the enzyme or using an inactivated enzyme, indicating that the present polymerization proceeds through enzymatic catalysis. Article in Journal/Newspaper Antarc* Antarctica Wiley Online Library Macromolecular Rapid Communications 18 7 575 579 |
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Open Polar |
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Wiley Online Library |
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crwiley |
language |
English |
description |
Abstract Enzymatic ring‐opening polymerization of a 6‐membered cyclic carbonate, 1,3‐dioxan‐2‐one, was investigated by using lipase as catalyst in bulk. Supported lipase derived from Candida antarctica catalyzed the polymerization to give the corresponding aliphatic polycarbonate. Unchanged monomer was recovered in the absence of the enzyme or using an inactivated enzyme, indicating that the present polymerization proceeds through enzymatic catalysis. |
format |
Article in Journal/Newspaper |
author |
Kobayashi, Shiro Kikuchi, Hirofumi Uyama, Hiroshi |
spellingShingle |
Kobayashi, Shiro Kikuchi, Hirofumi Uyama, Hiroshi Lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one |
author_facet |
Kobayashi, Shiro Kikuchi, Hirofumi Uyama, Hiroshi |
author_sort |
Kobayashi, Shiro |
title |
Lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one |
title_short |
Lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one |
title_full |
Lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one |
title_fullStr |
Lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one |
title_full_unstemmed |
Lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one |
title_sort |
lipase‐catalyzed ring‐opening polymerization of 1,3‐dioxan‐2‐one |
publisher |
Wiley |
publishDate |
1997 |
url |
http://dx.doi.org/10.1002/marc.1997.030180707 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmarc.1997.030180707 https://onlinelibrary.wiley.com/doi/pdf/10.1002/marc.1997.030180707 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
Macromolecular Rapid Communications volume 18, issue 7, page 575-579 ISSN 1022-1336 1521-3927 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/marc.1997.030180707 |
container_title |
Macromolecular Rapid Communications |
container_volume |
18 |
container_issue |
7 |
container_start_page |
575 |
op_container_end_page |
579 |
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1800740861708861440 |