Polymers of carbonic acid, 12. Spontaneous and hematin‐initiated polymerizations of trimethylene carbonate and neopentylene carbonate
Abstract The purity and reactivity of trimethylene carbonate (TMC, 1,3‐dioxan‐2‐one) depends largely on the purification procedure. Vacuum distillation and recrystallization from CCl 4 are less efficient than recrystallization from tetrahydrofuran (THF) or ethyl acetate (EtAc). TMC recrystallized fr...
Published in: | Macromolecular Chemistry and Physics |
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Main Authors: | , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Wiley
1996
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Subjects: | |
Online Access: | http://dx.doi.org/10.1002/macp.1996.021970323 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmacp.1996.021970323 https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.1996.021970323 |
Summary: | Abstract The purity and reactivity of trimethylene carbonate (TMC, 1,3‐dioxan‐2‐one) depends largely on the purification procedure. Vacuum distillation and recrystallization from CCl 4 are less efficient than recrystallization from tetrahydrofuran (THF) or ethyl acetate (EtAc). TMC recrystallized from CCl 4 contains between 5 and 8 mol‐% of CCl 4 which inhibits the spontaneous polymerization at temperatures ≥ 100°C as do other alkylating agents. The spontaneous polymerization of pure TMC may give high yields (up to 90%) and high molecular weights (weight‐average molecular weights up to 200 000). The polymerization mechanism is discussed. It seems to be anionic in nature. Neopentylene carbonate (NPC, 5,5‐dimethyl‐1,3‐dioxan‐2‐one) is rather insensitive to the purification procedure and does not undergo spontaneous polymerization at temperatures ⩽ 125°C. Hematin initiates the polymerizations of TMC and NPC in bulk, but high yields and high molecular weights were only obtained in the case of TMC. |
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