Polymers of carbonic acid, 8. Linear polybiurets
Abstract Linear polybiurets can be synthesized by polycondensation of chloroformyl isocyanate and N , N ′‐bis(trimethylsilyl)‐α,ω‐diaminoalkanes or silylated aromatic diamines. The polybiurets were characterized by elemental analyses, inherent viscosity measurements, IR spectroscopy, 1 H, 13 C, 15 N...
Published in: | Die Makromolekulare Chemie |
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Main Authors: | , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Wiley
1992
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Subjects: | |
Online Access: | http://dx.doi.org/10.1002/macp.1992.021931012 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmacp.1992.021931012 https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.1992.021931012 |
Summary: | Abstract Linear polybiurets can be synthesized by polycondensation of chloroformyl isocyanate and N , N ′‐bis(trimethylsilyl)‐α,ω‐diaminoalkanes or silylated aromatic diamines. The polybiurets were characterized by elemental analyses, inherent viscosity measurements, IR spectroscopy, 1 H, 13 C, 15 N NMR spectroscopy in solution, differential scanning calorimetry (DSC) measurements, wide‐angle X‐ray scattering (WAXS) and thermogravimetric analyses. All polybiurets are semicrystalline materials with a low rate of crystallization and unexpectedly low melting points. 13 C and 15 N NMR cross‐polarization/magic angle spinning (CP/MAS) spectra of the solid polybiurets indicate different conformations for the amorphous and crystalline phase. All polybiurets gradually decompose upon heating above 200°C. Synthetic methods and properties of linear biurets were also checked by synthesis and characterization of N , N ′‐dioctylbiuret. |
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