Unsaturated carbonic acid derivatives III. Copolymerization behavior of S‐, O‐ and N‐vinyl derivatives of carbonic acid

• Published in: Die Makromolekulare Chemie
• Main Authors: Ringsdorf, H., Weinshenker, N., Overberger, C. G.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Wiley 1963
• Subjects: Carbonic acid
• Online Access: http://dx.doi.org/10.1002/macp.1963.020640110; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmacp.1963.020640110; https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.1963.020640110

Abstract S‐Vinyl‐N‐diethyl monothiolcarbamate, O‐Vinyl‐N‐diethyl carbamate, and N‐Vinyl‐N‐methyl‐S‐ethyl monothiocarbamate were copolymerized with styrene and vinyl acetate. The A LFREY ‐P RICE Q‐ and e‐values were calculated and compared with those of other S, O, and N‐vinyl monomers. The S‐vinyl thiolcarbamate was found to be more reactive as a comonomer than the N‐ or O‐vinyl compounds.