Unsaturated carbonic acid derivatives III. Copolymerization behavior of S‐, O‐ and N‐vinyl derivatives of carbonic acid

Abstract S‐Vinyl‐N‐diethyl monothiolcarbamate, O‐Vinyl‐N‐diethyl carbamate, and N‐Vinyl‐N‐methyl‐S‐ethyl monothiocarbamate were copolymerized with styrene and vinyl acetate. The A LFREY ‐P RICE Q‐ and e‐values were calculated and compared with those of other S, O, and N‐vinyl monomers. The S‐vinyl...

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Bibliographic Details
Published in:Die Makromolekulare Chemie
Main Authors: Ringsdorf, H., Weinshenker, N., Overberger, C. G.
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 1963
Subjects:
Online Access:http://dx.doi.org/10.1002/macp.1963.020640110
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmacp.1963.020640110
https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.1963.020640110
Description
Summary:Abstract S‐Vinyl‐N‐diethyl monothiolcarbamate, O‐Vinyl‐N‐diethyl carbamate, and N‐Vinyl‐N‐methyl‐S‐ethyl monothiocarbamate were copolymerized with styrene and vinyl acetate. The A LFREY ‐P RICE Q‐ and e‐values were calculated and compared with those of other S, O, and N‐vinyl monomers. The S‐vinyl thiolcarbamate was found to be more reactive as a comonomer than the N‐ or O‐vinyl compounds.