Alkalinity and dissolved inorganic carbon exports from tropical and subtropical river catchments discharging to the Great Barrier Reef, Australia

• Published in: Hydrological Processes
• Main Authors: Rosentreter, Judith A., Eyre, Bradley D.
• Other Authors: Australian Research Council
• Format: Article in Journal/Newspaper
• Language: English
• Published: Wiley 2019
• Subjects: Fitzroy; Ocean acidification
• Online Access: http://dx.doi.org/10.1002/hyp.13679; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fhyp.13679; https://onlinelibrary.wiley.com/doi/pdf/10.1002/hyp.13679; https://onlinelibrary.wiley.com/doi/full-xml/10.1002/hyp.13679; https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/hyp.13679

Abstract Dissolved inorganic carbon (DIC) transport by rivers is an important control on the pH and carbonate chemistry of the coastal ocean. Here, we combine DIC and total alkalinity (TAlk) concentrations from four tropical rivers of the Great Barrier Reef region in Australia with daily river discharge to quantify annual river loads and export rates. DIC in the four rivers ranged from 284 to 2,639 μmol kg −1 and TAlk ranged from 220 to 2,612 μmol kg −1 . DIC:TAlk ratios were mostly greater than one suggesting elevated exports of free [CO 2 *]. This was pronounced in the Johnstone and Herbert rivers of the tropical wet north. The largest annual loads were transported in the two large river catchments of the southern Great Barrier Reef region, the Fitzroy and Burdekin rivers. The carbon stable isotopic composition of DIC suggests that carbonate weathering was the dominant source of DIC in the southern rivers, and silicate weathering was likely a source of DIC in the northern Wet Tropics rivers. Annual loads and export rates were strongly driven by precipitation and discharge patterns, the occurrence of tropical cyclones, and associated flooding events, as well as distinct seasonal dry and wet periods. As such, short‐lived hydrological events and long‐term (seasonal and inter‐annual) variation of DIC and TAlk that are pronounced in rivers of the tropical and subtropical wet and dry climate zone should be accounted for when assessing inorganic carbon loads to the coastal ocean and the potential to buffer against or accelerate ocean acidification.