DBU‐Promoted Nucleophilic Activation of Carbonic Acid Diesters
Abstract The reactivity of carbonic acid diesters in the presence of the amidine base DBU (1,8‐diazabicyclo[5.4.0]undec‐7‐ene) has been investigated for the first time. Organic carbonates can be activated by DBU through the formation of N ‐alkoxycarbonyl ketene aminal 2 as the ultimate product. The...
| Published in: | European Journal of Organic Chemistry |
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| Main Authors: | , , |
| Format: | Article in Journal/Newspaper |
| Language: | English |
| Published: |
Wiley
2011
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1002/ejoc.201001725 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201001725 http://onlinelibrary.wiley.com/wol1/doi/10.1002/ejoc.201001725/fullpdf |