Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols
Abstract Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium has been prepared and its structure confirmed by X‐ray analysis. This complex shows excellent catalytic activity and modest stability against air in racemization reactions of secondary alcohols. In Candida antarctica lipase B (CAL‐B) ca...
Published in: | European Journal of Organic Chemistry |
---|---|
Main Authors: | , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Wiley
2009
|
Subjects: | |
Online Access: | http://dx.doi.org/10.1002/ejoc.200801248 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.200801248 https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.200801248 |
id |
crwiley:10.1002/ejoc.200801248 |
---|---|
record_format |
openpolar |
spelling |
crwiley:10.1002/ejoc.200801248 2024-06-02T07:56:23+00:00 Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols Mavrynsky, Denys Päiviö, Mari Lundell, Katri Sillanpää, Reijo Kanerva, Liisa T. Leino, Reko 2009 http://dx.doi.org/10.1002/ejoc.200801248 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.200801248 https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.200801248 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor European Journal of Organic Chemistry volume 2009, issue 9, page 1317-1320 ISSN 1434-193X 1099-0690 journal-article 2009 crwiley https://doi.org/10.1002/ejoc.200801248 2024-05-03T10:46:21Z Abstract Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium has been prepared and its structure confirmed by X‐ray analysis. This complex shows excellent catalytic activity and modest stability against air in racemization reactions of secondary alcohols. In Candida antarctica lipase B (CAL‐B) catalyzed dynamic kinetic resolution (DKR) of 1‐phenyl‐ and 1‐(furan‐2‐yl)ethanol compounds, the new complex shows improved performance as an alcohol racemization catalyst in comparison with its well‐known pentaphenylcyclopentadienyl analogue, hitherto considered as the leading catalyst candidate. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) Article in Journal/Newspaper Antarc* Antarctica Wiley Online Library European Journal of Organic Chemistry 2009 9 1317 1320 |
institution |
Open Polar |
collection |
Wiley Online Library |
op_collection_id |
crwiley |
language |
English |
description |
Abstract Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium has been prepared and its structure confirmed by X‐ray analysis. This complex shows excellent catalytic activity and modest stability against air in racemization reactions of secondary alcohols. In Candida antarctica lipase B (CAL‐B) catalyzed dynamic kinetic resolution (DKR) of 1‐phenyl‐ and 1‐(furan‐2‐yl)ethanol compounds, the new complex shows improved performance as an alcohol racemization catalyst in comparison with its well‐known pentaphenylcyclopentadienyl analogue, hitherto considered as the leading catalyst candidate. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) |
format |
Article in Journal/Newspaper |
author |
Mavrynsky, Denys Päiviö, Mari Lundell, Katri Sillanpää, Reijo Kanerva, Liisa T. Leino, Reko |
spellingShingle |
Mavrynsky, Denys Päiviö, Mari Lundell, Katri Sillanpää, Reijo Kanerva, Liisa T. Leino, Reko Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols |
author_facet |
Mavrynsky, Denys Päiviö, Mari Lundell, Katri Sillanpää, Reijo Kanerva, Liisa T. Leino, Reko |
author_sort |
Mavrynsky, Denys |
title |
Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols |
title_short |
Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols |
title_full |
Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols |
title_fullStr |
Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols |
title_full_unstemmed |
Dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols |
title_sort |
dicarbonylchloro(pentabenzylcyclopentadienyl)ruthenium as racemization catalyst in the dynamic kinetic resolution of secondary alcohols |
publisher |
Wiley |
publishDate |
2009 |
url |
http://dx.doi.org/10.1002/ejoc.200801248 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.200801248 https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.200801248 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
European Journal of Organic Chemistry volume 2009, issue 9, page 1317-1320 ISSN 1434-193X 1099-0690 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/ejoc.200801248 |
container_title |
European Journal of Organic Chemistry |
container_volume |
2009 |
container_issue |
9 |
container_start_page |
1317 |
op_container_end_page |
1320 |
_version_ |
1800755679449841664 |