Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis
Abstract Due to the need for environmental protection and sustainability, there has been a rising need to replace the traditionally harsh oxidative functionalization process, which is essential for syntheses of various organic compounds, by biocatalysis. However, the investigated alternative process...
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Online Access: | http://dx.doi.org/10.1002/cite.202400005 https://onlinelibrary.wiley.com/doi/pdf/10.1002/cite.202400005 |
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crwiley:10.1002/cite.202400005 2024-06-02T07:57:31+00:00 Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis Adomi, Lemuel Drews, Anja Deutsche Forschungsgemeinschaft 2024 http://dx.doi.org/10.1002/cite.202400005 https://onlinelibrary.wiley.com/doi/pdf/10.1002/cite.202400005 de ger Wiley http://creativecommons.org/licenses/by-nc/4.0/ Chemie Ingenieur Technik volume 96, issue 4, page 535-544 ISSN 0009-286X 1522-2640 journal-article 2024 crwiley https://doi.org/10.1002/cite.202400005 2024-05-03T11:40:54Z Abstract Due to the need for environmental protection and sustainability, there has been a rising need to replace the traditionally harsh oxidative functionalization process, which is essential for syntheses of various organic compounds, by biocatalysis. However, the investigated alternative processes are still challenged with enzyme instability and/or low specific reaction rate. Due to these still existing challenges and the recognition of Pickering emulsions as an efficient platform for continuous biphasic biocatalysis, the first, enzymatic step of the lipase catalyzed oxidative functionalization was investigated in bioactive Pickering emulsions. The study focused on the impact of Pickering emulsion composition such as the volume phase fraction, type and concentration of the nanoparticles and enzymes on continuous peroxyacetic acids synthesis. The type of nanoparticles used and Candida antarctica lipase B concentration significantly impacted the process while the other named parameters only had a marginal influence. Article in Journal/Newspaper Antarc* Antarctica Wiley Online Library Chemie Ingenieur Technik 96 4 535 544 |
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Abstract Due to the need for environmental protection and sustainability, there has been a rising need to replace the traditionally harsh oxidative functionalization process, which is essential for syntheses of various organic compounds, by biocatalysis. However, the investigated alternative processes are still challenged with enzyme instability and/or low specific reaction rate. Due to these still existing challenges and the recognition of Pickering emulsions as an efficient platform for continuous biphasic biocatalysis, the first, enzymatic step of the lipase catalyzed oxidative functionalization was investigated in bioactive Pickering emulsions. The study focused on the impact of Pickering emulsion composition such as the volume phase fraction, type and concentration of the nanoparticles and enzymes on continuous peroxyacetic acids synthesis. The type of nanoparticles used and Candida antarctica lipase B concentration significantly impacted the process while the other named parameters only had a marginal influence. |
author2 |
Deutsche Forschungsgemeinschaft |
format |
Article in Journal/Newspaper |
author |
Adomi, Lemuel Drews, Anja |
spellingShingle |
Adomi, Lemuel Drews, Anja Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis |
author_facet |
Adomi, Lemuel Drews, Anja |
author_sort |
Adomi, Lemuel |
title |
Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis |
title_short |
Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis |
title_full |
Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis |
title_fullStr |
Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis |
title_full_unstemmed |
Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis |
title_sort |
impact of pickering emulsions composition on lipase catalyzed peroxyacetic acid synthesis |
publisher |
Wiley |
publishDate |
2024 |
url |
http://dx.doi.org/10.1002/cite.202400005 https://onlinelibrary.wiley.com/doi/pdf/10.1002/cite.202400005 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
Chemie Ingenieur Technik volume 96, issue 4, page 535-544 ISSN 0009-286X 1522-2640 |
op_rights |
http://creativecommons.org/licenses/by-nc/4.0/ |
op_doi |
https://doi.org/10.1002/cite.202400005 |
container_title |
Chemie Ingenieur Technik |
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96 |
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4 |
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535 |
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544 |
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1800740685306920960 |