A New Route to Cyclohexanone using H 2 CO 3 as a Molecular Catalytic Ligand to Boost the Thorough Hydrogenation of Nitroarenes over Pd Nanocatalysts
Abstract Carbon dioxide has been important in green chemistry, especially in catalytic and chemical engineering applications. While exploring CO 2 to produce cyclohexanone for nylon or nylon 66 that is currently produced with low yields using harsh catalytic methods, we made the exciting discovery t...
Published in: | ChemCatChem |
---|---|
Main Authors: | , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Wiley
2019
|
Subjects: | |
Online Access: | http://dx.doi.org/10.1002/cctc.201900389 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcctc.201900389 https://onlinelibrary.wiley.com/doi/pdf/10.1002/cctc.201900389 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/cctc.201900389 |
id |
crwiley:10.1002/cctc.201900389 |
---|---|
record_format |
openpolar |
spelling |
crwiley:10.1002/cctc.201900389 2024-09-15T18:01:38+00:00 A New Route to Cyclohexanone using H 2 CO 3 as a Molecular Catalytic Ligand to Boost the Thorough Hydrogenation of Nitroarenes over Pd Nanocatalysts Zhao, Tian‐Jian Zhang, Jun‐Jun Zhang, Bing Liu, Yong‐Xing Lin, Yun‐Xiao Wang, Hong‐Hui Su, Hui Li, Xin‐Hao Chen, Jie‐Sheng 2019 http://dx.doi.org/10.1002/cctc.201900389 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcctc.201900389 https://onlinelibrary.wiley.com/doi/pdf/10.1002/cctc.201900389 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/cctc.201900389 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor ChemCatChem volume 11, issue 12, page 2837-2842 ISSN 1867-3880 1867-3899 journal-article 2019 crwiley https://doi.org/10.1002/cctc.201900389 2024-08-30T04:12:46Z Abstract Carbon dioxide has been important in green chemistry, especially in catalytic and chemical engineering applications. While exploring CO 2 to produce cyclohexanone for nylon or nylon 66 that is currently produced with low yields using harsh catalytic methods, we made the exciting discovery that carbonic acid, generated from dissolved CO 2 in water, was utilized as molecular catalytic ligand to produce cyclohexanone via the hydrogenation of nitrobenzene in aqueous solution that uses Pd catalysts with a total yield higher than 90 %. Importantly, the gaseous nature of catalytic ligand H 2 CO 3 profoundly simplifies post‐catalysis cleanup unlike liquid or solid catalysts. This new green catalysis strategy demonstrated the universality for hydrogenation of aromatic compounds like aniline and N‐methylaniline and could be broadly applicable in other catalytic field like artificial photosynthesis and electrocatalytic organic synthesis. Article in Journal/Newspaper Carbonic acid Wiley Online Library ChemCatChem 11 12 2837 2842 |
institution |
Open Polar |
collection |
Wiley Online Library |
op_collection_id |
crwiley |
language |
English |
description |
Abstract Carbon dioxide has been important in green chemistry, especially in catalytic and chemical engineering applications. While exploring CO 2 to produce cyclohexanone for nylon or nylon 66 that is currently produced with low yields using harsh catalytic methods, we made the exciting discovery that carbonic acid, generated from dissolved CO 2 in water, was utilized as molecular catalytic ligand to produce cyclohexanone via the hydrogenation of nitrobenzene in aqueous solution that uses Pd catalysts with a total yield higher than 90 %. Importantly, the gaseous nature of catalytic ligand H 2 CO 3 profoundly simplifies post‐catalysis cleanup unlike liquid or solid catalysts. This new green catalysis strategy demonstrated the universality for hydrogenation of aromatic compounds like aniline and N‐methylaniline and could be broadly applicable in other catalytic field like artificial photosynthesis and electrocatalytic organic synthesis. |
format |
Article in Journal/Newspaper |
author |
Zhao, Tian‐Jian Zhang, Jun‐Jun Zhang, Bing Liu, Yong‐Xing Lin, Yun‐Xiao Wang, Hong‐Hui Su, Hui Li, Xin‐Hao Chen, Jie‐Sheng |
spellingShingle |
Zhao, Tian‐Jian Zhang, Jun‐Jun Zhang, Bing Liu, Yong‐Xing Lin, Yun‐Xiao Wang, Hong‐Hui Su, Hui Li, Xin‐Hao Chen, Jie‐Sheng A New Route to Cyclohexanone using H 2 CO 3 as a Molecular Catalytic Ligand to Boost the Thorough Hydrogenation of Nitroarenes over Pd Nanocatalysts |
author_facet |
Zhao, Tian‐Jian Zhang, Jun‐Jun Zhang, Bing Liu, Yong‐Xing Lin, Yun‐Xiao Wang, Hong‐Hui Su, Hui Li, Xin‐Hao Chen, Jie‐Sheng |
author_sort |
Zhao, Tian‐Jian |
title |
A New Route to Cyclohexanone using H 2 CO 3 as a Molecular Catalytic Ligand to Boost the Thorough Hydrogenation of Nitroarenes over Pd Nanocatalysts |
title_short |
A New Route to Cyclohexanone using H 2 CO 3 as a Molecular Catalytic Ligand to Boost the Thorough Hydrogenation of Nitroarenes over Pd Nanocatalysts |
title_full |
A New Route to Cyclohexanone using H 2 CO 3 as a Molecular Catalytic Ligand to Boost the Thorough Hydrogenation of Nitroarenes over Pd Nanocatalysts |
title_fullStr |
A New Route to Cyclohexanone using H 2 CO 3 as a Molecular Catalytic Ligand to Boost the Thorough Hydrogenation of Nitroarenes over Pd Nanocatalysts |
title_full_unstemmed |
A New Route to Cyclohexanone using H 2 CO 3 as a Molecular Catalytic Ligand to Boost the Thorough Hydrogenation of Nitroarenes over Pd Nanocatalysts |
title_sort |
new route to cyclohexanone using h 2 co 3 as a molecular catalytic ligand to boost the thorough hydrogenation of nitroarenes over pd nanocatalysts |
publisher |
Wiley |
publishDate |
2019 |
url |
http://dx.doi.org/10.1002/cctc.201900389 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcctc.201900389 https://onlinelibrary.wiley.com/doi/pdf/10.1002/cctc.201900389 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/cctc.201900389 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
ChemCatChem volume 11, issue 12, page 2837-2842 ISSN 1867-3880 1867-3899 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/cctc.201900389 |
container_title |
ChemCatChem |
container_volume |
11 |
container_issue |
12 |
container_start_page |
2837 |
op_container_end_page |
2842 |
_version_ |
1810438737447878656 |