VII 3 . Nuclear Magnetic Resonance Studies of the Carbon Dioxide‐Water Equilibrium
Abstract The classical view of the entities existing in a solution of carbon dioxide in water is that of dissolved carbon dioxide, hydrated carbon dioxide or carbonic acid, bicarbonate ion, hydronium ion, and carbonate ion, Estimates of the concentrations of all these species are available from a va...
Published in: | Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie |
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Online Access: | http://dx.doi.org/10.1002/bbpc.19600640134 https://onlinelibrary.wiley.com/doi/pdf/10.1002/bbpc.19600640134 |
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crwiley:10.1002/bbpc.19600640134 2024-03-17T08:57:23+00:00 VII 3 . Nuclear Magnetic Resonance Studies of the Carbon Dioxide‐Water Equilibrium Patterson, Andrew Ettinger, Raymond 1960 http://dx.doi.org/10.1002/bbpc.19600640134 https://onlinelibrary.wiley.com/doi/pdf/10.1002/bbpc.19600640134 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie volume 64, issue 1, page 98-110 ISSN 0372-8382 journal-article 1960 crwiley https://doi.org/10.1002/bbpc.19600640134 2024-02-22T00:14:02Z Abstract The classical view of the entities existing in a solution of carbon dioxide in water is that of dissolved carbon dioxide, hydrated carbon dioxide or carbonic acid, bicarbonate ion, hydronium ion, and carbonate ion, Estimates of the concentrations of all these species are available from a variety of types of measurements. Nuclear magnetic resonance studies on. the C 13 isotope dissolved as carbon dioxide in water, deuterium oxide, and in sodium hydroxide solution of various concentrations have not given any results which would require the alteration of these views. Because of equipment limitations, carbonic acid has not been detected, but a maximum limit for its concentration has been set which is not inconsistent with the predictions of electrochemical data. Two most interesting questions remain unanswered by data thus far accumulated: Why is such a large proportion of the carbon dioxide in solution present in dissolved but not hydrated form; and Why is the reaction of hydration such a slow process? Article in Journal/Newspaper Carbonic acid Wiley Online Library Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie 64 1 98 110 |
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Wiley Online Library |
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crwiley |
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English |
description |
Abstract The classical view of the entities existing in a solution of carbon dioxide in water is that of dissolved carbon dioxide, hydrated carbon dioxide or carbonic acid, bicarbonate ion, hydronium ion, and carbonate ion, Estimates of the concentrations of all these species are available from a variety of types of measurements. Nuclear magnetic resonance studies on. the C 13 isotope dissolved as carbon dioxide in water, deuterium oxide, and in sodium hydroxide solution of various concentrations have not given any results which would require the alteration of these views. Because of equipment limitations, carbonic acid has not been detected, but a maximum limit for its concentration has been set which is not inconsistent with the predictions of electrochemical data. Two most interesting questions remain unanswered by data thus far accumulated: Why is such a large proportion of the carbon dioxide in solution present in dissolved but not hydrated form; and Why is the reaction of hydration such a slow process? |
format |
Article in Journal/Newspaper |
author |
Patterson, Andrew Ettinger, Raymond |
spellingShingle |
Patterson, Andrew Ettinger, Raymond VII 3 . Nuclear Magnetic Resonance Studies of the Carbon Dioxide‐Water Equilibrium |
author_facet |
Patterson, Andrew Ettinger, Raymond |
author_sort |
Patterson, Andrew |
title |
VII 3 . Nuclear Magnetic Resonance Studies of the Carbon Dioxide‐Water Equilibrium |
title_short |
VII 3 . Nuclear Magnetic Resonance Studies of the Carbon Dioxide‐Water Equilibrium |
title_full |
VII 3 . Nuclear Magnetic Resonance Studies of the Carbon Dioxide‐Water Equilibrium |
title_fullStr |
VII 3 . Nuclear Magnetic Resonance Studies of the Carbon Dioxide‐Water Equilibrium |
title_full_unstemmed |
VII 3 . Nuclear Magnetic Resonance Studies of the Carbon Dioxide‐Water Equilibrium |
title_sort |
vii 3 . nuclear magnetic resonance studies of the carbon dioxide‐water equilibrium |
publisher |
Wiley |
publishDate |
1960 |
url |
http://dx.doi.org/10.1002/bbpc.19600640134 https://onlinelibrary.wiley.com/doi/pdf/10.1002/bbpc.19600640134 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie volume 64, issue 1, page 98-110 ISSN 0372-8382 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/bbpc.19600640134 |
container_title |
Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie |
container_volume |
64 |
container_issue |
1 |
container_start_page |
98 |
op_container_end_page |
110 |
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1793766536814526464 |