Preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil
Abstract To prepare polymers based on the vegetable oils, an acrylic monomer with long alkyl chain, (2‐(acryloyloxy) ethyl oleate) (AEO)), was prepared by the reaction of hydroxyl ethyl acrylate (HEA) with methyl oleate (MO), in which the MO, having very similar structure to the bio‐diesel, was the...
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crwiley:10.1002/app.31467 2024-06-23T07:47:03+00:00 Preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil Cho, Hang‐Goo Park, Seong‐Yung Jegal, Jonggeon Song, Bong‐Keun Kim, Hyung‐Joong 2009 http://dx.doi.org/10.1002/app.31467 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fapp.31467 https://onlinelibrary.wiley.com/doi/pdf/10.1002/app.31467 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Journal of Applied Polymer Science volume 116, issue 2, page 736-742 ISSN 0021-8995 1097-4628 journal-article 2009 crwiley https://doi.org/10.1002/app.31467 2024-05-31T08:15:12Z Abstract To prepare polymers based on the vegetable oils, an acrylic monomer with long alkyl chain, (2‐(acryloyloxy) ethyl oleate) (AEO)), was prepared by the reaction of hydroxyl ethyl acrylate (HEA) with methyl oleate (MO), in which the MO, having very similar structure to the bio‐diesel, was the one derived from Linseed oil. For the formation of the AEO, Novozyme‐435, the Candida antarctica lipase B loaded on the acrylic resin, was used as a catalyst. To optimize its reaction condition, effects of experimental factors, such as, different enzymes, reaction temperature, water activity of enzyme, concentration of enzyme used, and molar ratio of HEA and MO, were studied. The AEO was then, after characterization using several analytical methods, polymerized by the radical polymerization, using benzoyl peroxide (BPO) as a catalyst. The M n of the polymers prepared under different experimental conditions was in the range from 20,000 to 30,000 g/mol. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 Article in Journal/Newspaper Antarc* Antarctica Wiley Online Library Journal of Applied Polymer Science 116 2 736 742 |
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English |
description |
Abstract To prepare polymers based on the vegetable oils, an acrylic monomer with long alkyl chain, (2‐(acryloyloxy) ethyl oleate) (AEO)), was prepared by the reaction of hydroxyl ethyl acrylate (HEA) with methyl oleate (MO), in which the MO, having very similar structure to the bio‐diesel, was the one derived from Linseed oil. For the formation of the AEO, Novozyme‐435, the Candida antarctica lipase B loaded on the acrylic resin, was used as a catalyst. To optimize its reaction condition, effects of experimental factors, such as, different enzymes, reaction temperature, water activity of enzyme, concentration of enzyme used, and molar ratio of HEA and MO, were studied. The AEO was then, after characterization using several analytical methods, polymerized by the radical polymerization, using benzoyl peroxide (BPO) as a catalyst. The M n of the polymers prepared under different experimental conditions was in the range from 20,000 to 30,000 g/mol. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 |
format |
Article in Journal/Newspaper |
author |
Cho, Hang‐Goo Park, Seong‐Yung Jegal, Jonggeon Song, Bong‐Keun Kim, Hyung‐Joong |
spellingShingle |
Cho, Hang‐Goo Park, Seong‐Yung Jegal, Jonggeon Song, Bong‐Keun Kim, Hyung‐Joong Preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil |
author_facet |
Cho, Hang‐Goo Park, Seong‐Yung Jegal, Jonggeon Song, Bong‐Keun Kim, Hyung‐Joong |
author_sort |
Cho, Hang‐Goo |
title |
Preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil |
title_short |
Preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil |
title_full |
Preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil |
title_fullStr |
Preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil |
title_full_unstemmed |
Preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil |
title_sort |
preparation and characterization of acrylic polymers based on a novel acrylic monomer produced from vegetable oil |
publisher |
Wiley |
publishDate |
2009 |
url |
http://dx.doi.org/10.1002/app.31467 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fapp.31467 https://onlinelibrary.wiley.com/doi/pdf/10.1002/app.31467 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
Journal of Applied Polymer Science volume 116, issue 2, page 736-742 ISSN 0021-8995 1097-4628 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/app.31467 |
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Journal of Applied Polymer Science |
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116 |
container_issue |
2 |
container_start_page |
736 |
op_container_end_page |
742 |
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1802650437637111808 |