Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts
Abstract As a new energy source that could replace petroleum, the global reserves of methane hydrate (combustible ice) are estimated to be approximately 20 000 trillion cubic meters. A large amount of methane hydrate has been found under the seabed, but the transportation and storage of methane gas...
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crwiley:10.1002/anie.201906350 2024-04-14T08:14:50+00:00 Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts Chen, Qi Dong, Anwang Wang, Dongxu Qiu, Lu Ma, Chunxin Yuan, Yihui Zhao, Yunpeng Jia, Na Guo, Zhanhu Wang, Ning National Natural Science Foundation of China 2019 http://dx.doi.org/10.1002/anie.201906350 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201906350 https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201906350 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201906350 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Angewandte Chemie International Edition volume 58, issue 31, page 10671-10676 ISSN 1433-7851 1521-3773 General Chemistry Catalysis journal-article 2019 crwiley https://doi.org/10.1002/anie.201906350 2024-03-19T11:01:39Z Abstract As a new energy source that could replace petroleum, the global reserves of methane hydrate (combustible ice) are estimated to be approximately 20 000 trillion cubic meters. A large amount of methane hydrate has been found under the seabed, but the transportation and storage of methane gas far from coastlines are technically unfeasible and expensive. The direct conversion of methane into value‐added chemicals and liquid fuels is highly desirable but remains challenging. Herein, we prepare a series of iridium complexes based on porous polycarbazoles with high specific areas and good thermochemical stabilities. Through structure tuning we optimized their catalytic activities for the selective monoborylation of methane. One of these catalysts (CAL‐3‐Ir) can produce methyl boronic acid pinacol ester (CH 3 Bpin) in 29 % yield in 9 h with a turnover frequency (TOF) of approximately 14 h −1 . Because its pore sizes favor monoborylated products, it has a high chemoselectivity for monoborylation (CH 3 Bpin:CH 2 (Bpin) 2 =16:1). Article in Journal/Newspaper Methane hydrate Wiley Online Library Angewandte Chemie International Edition 58 31 10671 10676 |
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English |
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General Chemistry Catalysis |
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General Chemistry Catalysis Chen, Qi Dong, Anwang Wang, Dongxu Qiu, Lu Ma, Chunxin Yuan, Yihui Zhao, Yunpeng Jia, Na Guo, Zhanhu Wang, Ning Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts |
topic_facet |
General Chemistry Catalysis |
description |
Abstract As a new energy source that could replace petroleum, the global reserves of methane hydrate (combustible ice) are estimated to be approximately 20 000 trillion cubic meters. A large amount of methane hydrate has been found under the seabed, but the transportation and storage of methane gas far from coastlines are technically unfeasible and expensive. The direct conversion of methane into value‐added chemicals and liquid fuels is highly desirable but remains challenging. Herein, we prepare a series of iridium complexes based on porous polycarbazoles with high specific areas and good thermochemical stabilities. Through structure tuning we optimized their catalytic activities for the selective monoborylation of methane. One of these catalysts (CAL‐3‐Ir) can produce methyl boronic acid pinacol ester (CH 3 Bpin) in 29 % yield in 9 h with a turnover frequency (TOF) of approximately 14 h −1 . Because its pore sizes favor monoborylated products, it has a high chemoselectivity for monoborylation (CH 3 Bpin:CH 2 (Bpin) 2 =16:1). |
author2 |
National Natural Science Foundation of China |
format |
Article in Journal/Newspaper |
author |
Chen, Qi Dong, Anwang Wang, Dongxu Qiu, Lu Ma, Chunxin Yuan, Yihui Zhao, Yunpeng Jia, Na Guo, Zhanhu Wang, Ning |
author_facet |
Chen, Qi Dong, Anwang Wang, Dongxu Qiu, Lu Ma, Chunxin Yuan, Yihui Zhao, Yunpeng Jia, Na Guo, Zhanhu Wang, Ning |
author_sort |
Chen, Qi |
title |
Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts |
title_short |
Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts |
title_full |
Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts |
title_fullStr |
Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts |
title_full_unstemmed |
Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts |
title_sort |
efficient and selective methane borylation through pore size tuning of hybrid porous organic‐polymer‐based iridium catalysts |
publisher |
Wiley |
publishDate |
2019 |
url |
http://dx.doi.org/10.1002/anie.201906350 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201906350 https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201906350 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201906350 |
genre |
Methane hydrate |
genre_facet |
Methane hydrate |
op_source |
Angewandte Chemie International Edition volume 58, issue 31, page 10671-10676 ISSN 1433-7851 1521-3773 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/anie.201906350 |
container_title |
Angewandte Chemie International Edition |
container_volume |
58 |
container_issue |
31 |
container_start_page |
10671 |
op_container_end_page |
10676 |
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1796313083806744576 |