Metal‐Free Carbon Materials for CO 2 Electrochemical Reduction
Abstract The rapid increase of the CO 2 concentration in the Earth's atmosphere has resulted in numerous environmental issues, such as global warming, ocean acidification, melting of the polar ice, rising sea level, and extinction of species. To search for suitable and capable catalytic systems...
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crwiley:10.1002/adma.201701784 2024-10-06T13:51:51+00:00 Metal‐Free Carbon Materials for CO 2 Electrochemical Reduction Duan, Xiaochuan Xu, Jiantie Wei, Zengxi Ma, Jianmin Guo, Shaojun Wang, Shuangyin Liu, Huakun Dou, Shixue National Natural Science Foundation of China Australian Research Council 2017 http://dx.doi.org/10.1002/adma.201701784 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadma.201701784 https://onlinelibrary.wiley.com/doi/pdf/10.1002/adma.201701784 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/adma.201701784 https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/adma.201701784 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#am http://onlinelibrary.wiley.com/termsAndConditions#vor Advanced Materials volume 29, issue 41 ISSN 0935-9648 1521-4095 journal-article 2017 crwiley https://doi.org/10.1002/adma.201701784 2024-09-23T04:37:11Z Abstract The rapid increase of the CO 2 concentration in the Earth's atmosphere has resulted in numerous environmental issues, such as global warming, ocean acidification, melting of the polar ice, rising sea level, and extinction of species. To search for suitable and capable catalytic systems for CO 2 conversion, electrochemical reduction of CO 2 (CO 2 RR) holds great promise. Emerging heterogeneous carbon materials have been considered as promising metal‐free electrocatalysts for the CO 2 RR, owing to their abundant natural resources, tailorable porous structures, resistance to acids and bases, high‐temperature stability, and environmental friendliness. They exhibit remarkable CO 2 RR properties, including catalytic activity, long durability, and high selectivity. Here, various carbon materials (e.g., carbon fibers, carbon nanotubes, graphene, diamond, nanoporous carbon, and graphene dots) with heteroatom doping (e.g., N, S, and B) that can be used as metal‐free catalysts for the CO 2 RR are highlighted. Recent advances regarding the identification of active sites for the CO 2 RR and the pathway of reduction of CO 2 to the final product are comprehensively reviewed. Additionally, the emerging challenges and some perspectives on the development of heteroatom‐doped carbon materials as metal‐free electrocatalysts for the CO 2 RR are included. Article in Journal/Newspaper Ocean acidification Wiley Online Library Advanced Materials 29 41 |
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Abstract The rapid increase of the CO 2 concentration in the Earth's atmosphere has resulted in numerous environmental issues, such as global warming, ocean acidification, melting of the polar ice, rising sea level, and extinction of species. To search for suitable and capable catalytic systems for CO 2 conversion, electrochemical reduction of CO 2 (CO 2 RR) holds great promise. Emerging heterogeneous carbon materials have been considered as promising metal‐free electrocatalysts for the CO 2 RR, owing to their abundant natural resources, tailorable porous structures, resistance to acids and bases, high‐temperature stability, and environmental friendliness. They exhibit remarkable CO 2 RR properties, including catalytic activity, long durability, and high selectivity. Here, various carbon materials (e.g., carbon fibers, carbon nanotubes, graphene, diamond, nanoporous carbon, and graphene dots) with heteroatom doping (e.g., N, S, and B) that can be used as metal‐free catalysts for the CO 2 RR are highlighted. Recent advances regarding the identification of active sites for the CO 2 RR and the pathway of reduction of CO 2 to the final product are comprehensively reviewed. Additionally, the emerging challenges and some perspectives on the development of heteroatom‐doped carbon materials as metal‐free electrocatalysts for the CO 2 RR are included. |
author2 |
National Natural Science Foundation of China Australian Research Council |
format |
Article in Journal/Newspaper |
author |
Duan, Xiaochuan Xu, Jiantie Wei, Zengxi Ma, Jianmin Guo, Shaojun Wang, Shuangyin Liu, Huakun Dou, Shixue |
spellingShingle |
Duan, Xiaochuan Xu, Jiantie Wei, Zengxi Ma, Jianmin Guo, Shaojun Wang, Shuangyin Liu, Huakun Dou, Shixue Metal‐Free Carbon Materials for CO 2 Electrochemical Reduction |
author_facet |
Duan, Xiaochuan Xu, Jiantie Wei, Zengxi Ma, Jianmin Guo, Shaojun Wang, Shuangyin Liu, Huakun Dou, Shixue |
author_sort |
Duan, Xiaochuan |
title |
Metal‐Free Carbon Materials for CO 2 Electrochemical Reduction |
title_short |
Metal‐Free Carbon Materials for CO 2 Electrochemical Reduction |
title_full |
Metal‐Free Carbon Materials for CO 2 Electrochemical Reduction |
title_fullStr |
Metal‐Free Carbon Materials for CO 2 Electrochemical Reduction |
title_full_unstemmed |
Metal‐Free Carbon Materials for CO 2 Electrochemical Reduction |
title_sort |
metal‐free carbon materials for co 2 electrochemical reduction |
publisher |
Wiley |
publishDate |
2017 |
url |
http://dx.doi.org/10.1002/adma.201701784 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadma.201701784 https://onlinelibrary.wiley.com/doi/pdf/10.1002/adma.201701784 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/adma.201701784 https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/adma.201701784 |
genre |
Ocean acidification |
genre_facet |
Ocean acidification |
op_source |
Advanced Materials volume 29, issue 41 ISSN 0935-9648 1521-4095 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#am http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/adma.201701784 |
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Advanced Materials |
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29 |
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41 |
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1812180159489376256 |