II. On a new series of sulphuretted acids
Adopting the idea that the series of organic compounds of which sulphuretted hydrogen is the type, corresponds in every respect with the series of which water is the type, I concluded that not only mercaptans and neutral sulphides which correspond to the alcohols and ethers, but also compounds corre...
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1856
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Online Access: | http://dx.doi.org/10.1098/rspl.1854.0012 https://royalsocietypublishing.org/doi/pdf/10.1098/rspl.1854.0012 |
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crroyalsociety:10.1098/rspl.1854.0012 2024-06-02T08:05:11+00:00 II. On a new series of sulphuretted acids 1856 http://dx.doi.org/10.1098/rspl.1854.0012 https://royalsocietypublishing.org/doi/pdf/10.1098/rspl.1854.0012 en eng The Royal Society https://royalsociety.org/journals/ethics-policies/data-sharing-mining/ Proceedings of the Royal Society of London volume 7, page 37-40 ISSN 0370-1662 2053-9126 journal-article 1856 crroyalsociety https://doi.org/10.1098/rspl.1854.0012 2024-05-07T14:16:24Z Adopting the idea that the series of organic compounds of which sulphuretted hydrogen is the type, corresponds in every respect with the series of which water is the type, I concluded that not only mercaptans and neutral sulphides which correspond to the alcohols and ethers, but also compounds corresponding to the acids, anhydrous acids and ethers of acids might be produced; I therefore endeavoured to obtain reactions which would enable me to replace oxygen in the compounds of the latter series by sulphur. Such reactions are produced by the compounds of sulphur with phosphorus—the tersulphide (P 2 S 3 ) and the pentasulphide (P 2 S 5 )—which are easily obtained by fusing together amorphous phosphorus and sulphur in an atmosphere of carbonic acid; no explosion takes place, although the combination is attended with a very violent action. Article in Journal/Newspaper Carbonic acid The Royal Society Proceedings of the Royal Society of London 7 37 40 |
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The Royal Society |
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crroyalsociety |
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English |
description |
Adopting the idea that the series of organic compounds of which sulphuretted hydrogen is the type, corresponds in every respect with the series of which water is the type, I concluded that not only mercaptans and neutral sulphides which correspond to the alcohols and ethers, but also compounds corresponding to the acids, anhydrous acids and ethers of acids might be produced; I therefore endeavoured to obtain reactions which would enable me to replace oxygen in the compounds of the latter series by sulphur. Such reactions are produced by the compounds of sulphur with phosphorus—the tersulphide (P 2 S 3 ) and the pentasulphide (P 2 S 5 )—which are easily obtained by fusing together amorphous phosphorus and sulphur in an atmosphere of carbonic acid; no explosion takes place, although the combination is attended with a very violent action. |
format |
Article in Journal/Newspaper |
title |
II. On a new series of sulphuretted acids |
spellingShingle |
II. On a new series of sulphuretted acids |
title_short |
II. On a new series of sulphuretted acids |
title_full |
II. On a new series of sulphuretted acids |
title_fullStr |
II. On a new series of sulphuretted acids |
title_full_unstemmed |
II. On a new series of sulphuretted acids |
title_sort |
ii. on a new series of sulphuretted acids |
publisher |
The Royal Society |
publishDate |
1856 |
url |
http://dx.doi.org/10.1098/rspl.1854.0012 https://royalsocietypublishing.org/doi/pdf/10.1098/rspl.1854.0012 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Proceedings of the Royal Society of London volume 7, page 37-40 ISSN 0370-1662 2053-9126 |
op_rights |
https://royalsociety.org/journals/ethics-policies/data-sharing-mining/ |
op_doi |
https://doi.org/10.1098/rspl.1854.0012 |
container_title |
Proceedings of the Royal Society of London |
container_volume |
7 |
container_start_page |
37 |
op_container_end_page |
40 |
_version_ |
1800749972556087296 |