Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase

The ethyl hemiester of carbonic acid is prepared as a pure solid and sublimed to the gas phase, in spite of claims of its instability. FT-IR spectroscopy combined with ab initio calculations reveals a 5 : 1 ratio of the two most stable conformers.

Bibliographic Details
Published in:RSC Advances
Main Authors: Bernard, Jürgen, Köck, Eva-Maria, Huber, Roland G., Liedl, Klaus R., Call, Ludwig, Schlögl, Robert, Grothe, Hinrich, Loerting, Thomas
Other Authors: Austrian Science Fund
Format: Article in Journal/Newspaper
Language:English
Published: Royal Society of Chemistry (RSC) 2017
Subjects:
Carbonic acid
Online Access:http://dx.doi.org/10.1039/c7ra02792c
http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA02792C
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spelling crroyalschem:10.1039/c7ra02792c 2024-06-23T07:52:02+00:00 Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase Bernard, Jürgen Köck, Eva-Maria Huber, Roland G. Liedl, Klaus R. Call, Ludwig Schlögl, Robert Grothe, Hinrich Loerting, Thomas Austrian Science Fund 2017 http://dx.doi.org/10.1039/c7ra02792c http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA02792C en eng Royal Society of Chemistry (RSC) RSC Advances volume 7, issue 36, page 22222-22233 ISSN 2046-2069 journal-article 2017 crroyalschem https://doi.org/10.1039/c7ra02792c 2024-06-10T04:16:19Z The ethyl hemiester of carbonic acid is prepared as a pure solid and sublimed to the gas phase, in spite of claims of its instability. FT-IR spectroscopy combined with ab initio calculations reveals a 5 : 1 ratio of the two most stable conformers. Article in Journal/Newspaper Carbonic acid Royal Society of Chemistry RSC Advances 7 36 22222 22233
institution Open Polar
collection Royal Society of Chemistry
op_collection_id crroyalschem
language English
description The ethyl hemiester of carbonic acid is prepared as a pure solid and sublimed to the gas phase, in spite of claims of its instability. FT-IR spectroscopy combined with ab initio calculations reveals a 5 : 1 ratio of the two most stable conformers.
author2 Austrian Science Fund
format Article in Journal/Newspaper
author Bernard, Jürgen
Köck, Eva-Maria
Huber, Roland G.
Liedl, Klaus R.
Call, Ludwig
Schlögl, Robert
Grothe, Hinrich
Loerting, Thomas
spellingShingle Bernard, Jürgen
Köck, Eva-Maria
Huber, Roland G.
Liedl, Klaus R.
Call, Ludwig
Schlögl, Robert
Grothe, Hinrich
Loerting, Thomas
Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase
author_facet Bernard, Jürgen
Köck, Eva-Maria
Huber, Roland G.
Liedl, Klaus R.
Call, Ludwig
Schlögl, Robert
Grothe, Hinrich
Loerting, Thomas
author_sort Bernard, Jürgen
title Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase
title_short Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase
title_full Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase
title_fullStr Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase
title_full_unstemmed Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase
title_sort carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase
publisher Royal Society of Chemistry (RSC)
publishDate 2017
url http://dx.doi.org/10.1039/c7ra02792c
http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA02792C
genre Carbonic acid
genre_facet Carbonic acid
op_source RSC Advances
volume 7, issue 36, page 22222-22233
ISSN 2046-2069
op_doi https://doi.org/10.1039/c7ra02792c
container_title RSC Advances
container_volume 7
container_issue 36
container_start_page 22222
op_container_end_page 22233
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