Tracing Volatiles, Halogens, and Chalcophile Metals during Melt Evolution at the Tolbachik Monogenetic Field, Kamchatka

• Published in: Journal of Petrology
• Main Authors: Iveson, Alexander A, Humphreys, Madeleine C S, Jenner, Frances E, Kunz, Barbara E, Savov, Ivan P, De Hoog, Jan C M, Churikova, Tatiana G, Gordeychik, Boris N, Hammond, Samantha J, Plechov, Pavel Yu, Blundy, Jon, Agostini, Samuele
• Other Authors: Leverhulme Trust, St Mary’s College scholarship at Durham University, RFBR, NERC From Arc Magmas to Ore Systems, NERC, NERC Mantle Volatiles
• Format: Article in Journal/Newspaper
• Language: English
• Published: Oxford University Press (OUP) 2022
• Subjects: Tolbachik; Kamchatka
• Online Access: http://dx.doi.org/10.1093/petrology/egac087; https://academic.oup.com/petrology/advance-article-pdf/doi/10.1093/petrology/egac087/45556035/egac087.pdf; https://academic.oup.com/petrology/article-pdf/63/9/egac087/47828954/egac087.pdf

Abstract Melt storage and supply beneath arc volcanoes may be distributed between a central stratovolcano and wider fields of monogenetic cones, indicating complex shallow plumbing systems. However, the impact of such spatially variable magma storage conditions on volatile degassing and trace element geochemistry is unclear. This study explores magma generation and storage processes beneath the Tolbachik volcanic field, Kamchatka, Russia, in order to investigate the evolution of the magmatic volatile phase and, specifically, the strong enrichment of chalcophile metals (in particular, Cu) in this system. We present new geochemical data for a large suite of olivine- and clinopyroxene-hosted melt inclusions (and host phenocrysts) from five separate monogenetic cones within the Tolbachik volcanic field. These high-Al composition magmas likely reflect the homogenised fractionation products of primitive intermediate-Mg melt compositions, stored at shallow depths after significant fractional crystallisation. Boron isotope compositions and incompatible trace element ratios of the melt inclusions suggest a deeper plumbing system that is dominated by extensive fractional crystallisation and fed by melts derived from an isotopically homogeneous parental magma composition. Volatile components (H2O, CO2, S, Cl, F) show that magmas feeding different monogenetic cones had variable initial volatile contents and subsequently experienced different fluid-saturated storage conditions and degassing histories. We also show that melts supplying the Tolbachik volcanic field are strongly enriched in Cu compared with almost all other Kamchatka rocks, including samples from the Tolbachik central stratocones, and other volcanoes situated in close proximity in the Central Kamchatka Depression. The melt inclusions record Cu concentrations ≥450 μg/g at ca. 4–5 wt.% MgO, which can only be explained by bulk incompatible partitioning behaviour of Cu, i.e. evolution under sulphide-undersaturated conditions. We suggest that initial mantle melting ...