Fractionation of 226Ra and Ba in the Upper North Pacific Ocean
Investigations conducted during the GEOSECS program concluded that radium-226 (T 1/2 = 1602 y) and barium are tightly correlated in waters above 2500 m in the Atlantic, Pacific and Antarctic Oceans, with a fairly uniform 226 Ra/Ba ratio of 2.3 ± 0.2 dpm µmol -1 (4.6 nmol 226 Ra/mol Ba). Here, we rep...
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Online Access: | http://dx.doi.org/10.3389/fmars.2022.859117 https://www.frontiersin.org/articles/10.3389/fmars.2022.859117/full |
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crfrontiers:10.3389/fmars.2022.859117 2024-02-11T09:58:17+01:00 Fractionation of 226Ra and Ba in the Upper North Pacific Ocean van Beek, Pieter François, Roger Honda, Makio Charette, Matthew A. Reyss, Jean-Louis Ganeshram, Raja Monnin, Christophe Honjo, Susumu 2022 http://dx.doi.org/10.3389/fmars.2022.859117 https://www.frontiersin.org/articles/10.3389/fmars.2022.859117/full unknown Frontiers Media SA https://creativecommons.org/licenses/by/4.0/ Frontiers in Marine Science volume 9 ISSN 2296-7745 Ocean Engineering Water Science and Technology Aquatic Science Global and Planetary Change Oceanography journal-article 2022 crfrontiers https://doi.org/10.3389/fmars.2022.859117 2024-01-26T10:04:13Z Investigations conducted during the GEOSECS program concluded that radium-226 (T 1/2 = 1602 y) and barium are tightly correlated in waters above 2500 m in the Atlantic, Pacific and Antarctic Oceans, with a fairly uniform 226 Ra/Ba ratio of 2.3 ± 0.2 dpm µmol -1 (4.6 nmol 226 Ra/mol Ba). Here, we report new 226 Ra and Ba data obtained at three different stations in the Pacific Ocean: stations K1 and K3 in the North-West Pacific and station old Hale Aloha, off Hawaii Island. The relationship between 226 Ra and Ba found at these stations is broadly consistent with that reported during the GEOSECS program. At the three investigated stations, however, we find that the 226 Ra/Ba ratios are significantly lower in the upper 500 m of the water column than at greater depths, a pattern that was overlooked during the GEOSECS program, either because of the precision of the measurements or because of the relatively low sampling resolution in the upper 500 m. Although not always apparent in individual GEOSECS profiles, this trend was noted before from the non-zero intercept of the linear regression when plotting the global data set of Ba versus 226 Ra seawater concentration and was attributed, at least in part, to the predominance of surface input from rivers for Ba versus bottom input from sediments for 226 Ra. Similarly, low 226 Ra/Ba ratios in the upper 500 m have been reported in other oceanic basins (e.g. Atlantic Ocean). Parallel to the low 226 Ra/Ba ratios in seawater, higher 226 Ra/Ba ratios were found in suspended particles collected in the upper 500 m. This suggests that fractionation between the two elements may contribute to the lower 226 Ra/Ba ratios found in the upper 500 m, with 226 Ra being preferentially removed from surface water, possibly as a result of mass fractionation during celestite formation by acantharians and/or barite precipitation, since both chemical elements have similar ionic radius and the same configuration of valence electrons. This finding has implications for dating of marine carbonates by ... Article in Journal/Newspaper Antarc* Antarctic Frontiers (Publisher) Antarctic Pacific Hale ENVELOPE(-86.317,-86.317,-78.067,-78.067) Frontiers in Marine Science 9 |
institution |
Open Polar |
collection |
Frontiers (Publisher) |
op_collection_id |
crfrontiers |
language |
unknown |
topic |
Ocean Engineering Water Science and Technology Aquatic Science Global and Planetary Change Oceanography |
spellingShingle |
Ocean Engineering Water Science and Technology Aquatic Science Global and Planetary Change Oceanography van Beek, Pieter François, Roger Honda, Makio Charette, Matthew A. Reyss, Jean-Louis Ganeshram, Raja Monnin, Christophe Honjo, Susumu Fractionation of 226Ra and Ba in the Upper North Pacific Ocean |
topic_facet |
Ocean Engineering Water Science and Technology Aquatic Science Global and Planetary Change Oceanography |
description |
Investigations conducted during the GEOSECS program concluded that radium-226 (T 1/2 = 1602 y) and barium are tightly correlated in waters above 2500 m in the Atlantic, Pacific and Antarctic Oceans, with a fairly uniform 226 Ra/Ba ratio of 2.3 ± 0.2 dpm µmol -1 (4.6 nmol 226 Ra/mol Ba). Here, we report new 226 Ra and Ba data obtained at three different stations in the Pacific Ocean: stations K1 and K3 in the North-West Pacific and station old Hale Aloha, off Hawaii Island. The relationship between 226 Ra and Ba found at these stations is broadly consistent with that reported during the GEOSECS program. At the three investigated stations, however, we find that the 226 Ra/Ba ratios are significantly lower in the upper 500 m of the water column than at greater depths, a pattern that was overlooked during the GEOSECS program, either because of the precision of the measurements or because of the relatively low sampling resolution in the upper 500 m. Although not always apparent in individual GEOSECS profiles, this trend was noted before from the non-zero intercept of the linear regression when plotting the global data set of Ba versus 226 Ra seawater concentration and was attributed, at least in part, to the predominance of surface input from rivers for Ba versus bottom input from sediments for 226 Ra. Similarly, low 226 Ra/Ba ratios in the upper 500 m have been reported in other oceanic basins (e.g. Atlantic Ocean). Parallel to the low 226 Ra/Ba ratios in seawater, higher 226 Ra/Ba ratios were found in suspended particles collected in the upper 500 m. This suggests that fractionation between the two elements may contribute to the lower 226 Ra/Ba ratios found in the upper 500 m, with 226 Ra being preferentially removed from surface water, possibly as a result of mass fractionation during celestite formation by acantharians and/or barite precipitation, since both chemical elements have similar ionic radius and the same configuration of valence electrons. This finding has implications for dating of marine carbonates by ... |
format |
Article in Journal/Newspaper |
author |
van Beek, Pieter François, Roger Honda, Makio Charette, Matthew A. Reyss, Jean-Louis Ganeshram, Raja Monnin, Christophe Honjo, Susumu |
author_facet |
van Beek, Pieter François, Roger Honda, Makio Charette, Matthew A. Reyss, Jean-Louis Ganeshram, Raja Monnin, Christophe Honjo, Susumu |
author_sort |
van Beek, Pieter |
title |
Fractionation of 226Ra and Ba in the Upper North Pacific Ocean |
title_short |
Fractionation of 226Ra and Ba in the Upper North Pacific Ocean |
title_full |
Fractionation of 226Ra and Ba in the Upper North Pacific Ocean |
title_fullStr |
Fractionation of 226Ra and Ba in the Upper North Pacific Ocean |
title_full_unstemmed |
Fractionation of 226Ra and Ba in the Upper North Pacific Ocean |
title_sort |
fractionation of 226ra and ba in the upper north pacific ocean |
publisher |
Frontiers Media SA |
publishDate |
2022 |
url |
http://dx.doi.org/10.3389/fmars.2022.859117 https://www.frontiersin.org/articles/10.3389/fmars.2022.859117/full |
long_lat |
ENVELOPE(-86.317,-86.317,-78.067,-78.067) |
geographic |
Antarctic Pacific Hale |
geographic_facet |
Antarctic Pacific Hale |
genre |
Antarc* Antarctic |
genre_facet |
Antarc* Antarctic |
op_source |
Frontiers in Marine Science volume 9 ISSN 2296-7745 |
op_rights |
https://creativecommons.org/licenses/by/4.0/ |
op_doi |
https://doi.org/10.3389/fmars.2022.859117 |
container_title |
Frontiers in Marine Science |
container_volume |
9 |
_version_ |
1790593906478415872 |