New insight into the pectolite – serandite series: a single crystal diffraction study of Na(Ca 1.73 Mn 0.27 )[HSi 3 O 9 ] at 293 and 100 K
Using synchrotron radiation, a single crystal investigation has been performed at 293 and 100 K for the structural characterization of the manganoan pectolite, Na(Ca 1.73 Mn 0.27 )[Si 3 O 8 (OH)] (from the pegmatite at Mt. Koashva, Khibiny alkaline massif, Kola peninsula, Russia). The data obtained...
Published in: | Zeitschrift für Kristallographie - Crystalline Materials |
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Walter de Gruyter GmbH
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crdegruyter:10.1524/zkri.2007.222.12.696 2023-05-15T17:05:01+02:00 New insight into the pectolite – serandite series: a single crystal diffraction study of Na(Ca 1.73 Mn 0.27 )[HSi 3 O 9 ] at 293 and 100 K Arakcheeva, Alla Pattison, Philip Meisser, Nicolas Chapuis, Gervais Pekov, Igor V. Thélin, Philippe 2007 http://dx.doi.org/10.1524/zkri.2007.222.12.696 https://www.degruyter.com/document/doi/10.1524/zkri.2007.222.12.696/xml https://www.degruyter.com/document/doi/10.1524/zkri.2007.222.12.696/pdf en eng Walter de Gruyter GmbH Zeitschrift für Kristallographie - Crystalline Materials volume 222, issue 12, page 696-704 ISSN 2196-7105 2194-4946 Inorganic Chemistry Condensed Matter Physics General Materials Science journal-article 2007 crdegruyter https://doi.org/10.1524/zkri.2007.222.12.696 2022-06-16T13:42:05Z Using synchrotron radiation, a single crystal investigation has been performed at 293 and 100 K for the structural characterization of the manganoan pectolite, Na(Ca 1.73 Mn 0.27 )[Si 3 O 8 (OH)] (from the pegmatite at Mt. Koashva, Khibiny alkaline massif, Kola peninsula, Russia). The data obtained are compared with other members of the pectolite – serandite, Na(Ca 2–x Mn x )[Si 3 O 8 (OH)], series. The strong asymmetric hydrogen bond observed in the other members of the series has been confirmed at 293 K (O3–O4 = 2.473(3) Å; H–O3 = 0.97(4) Å, H … O4 = 1.50(4) Å O3–H … O4 = 178(4)°). This bond exhibits strengthening (O3–O4 = 2.458(2) Å) and becomes more symmetric at 100 K (H–O3 = 1.06(4) Å, H … O4 = 1.40(4) Å, O3–H … O4 177(4)°). The data obtained for 293 K confirm the previously hinted tendency: the higher the content of Mn, the more asymmetric the H-bond. The influence of the asymmetric position of the H-bond on the environment close to the bonded O3 and O4 atoms and the H–Na interaction are discussed. The alternative topological role of the hydrogen bond is considered in comparison to a similar structure Li 2 Mg 2 [Si 4 O 11 ]. Article in Journal/Newspaper kola peninsula De Gruyter (via Crossref) Kola Peninsula Khibiny ENVELOPE(33.210,33.210,67.679,67.679) Koashva ENVELOPE(34.082,34.082,67.656,67.656) Zeitschrift für Kristallographie - Crystalline Materials 222 12 696 704 |
institution |
Open Polar |
collection |
De Gruyter (via Crossref) |
op_collection_id |
crdegruyter |
language |
English |
topic |
Inorganic Chemistry Condensed Matter Physics General Materials Science |
spellingShingle |
Inorganic Chemistry Condensed Matter Physics General Materials Science Arakcheeva, Alla Pattison, Philip Meisser, Nicolas Chapuis, Gervais Pekov, Igor V. Thélin, Philippe New insight into the pectolite – serandite series: a single crystal diffraction study of Na(Ca 1.73 Mn 0.27 )[HSi 3 O 9 ] at 293 and 100 K |
topic_facet |
Inorganic Chemistry Condensed Matter Physics General Materials Science |
description |
Using synchrotron radiation, a single crystal investigation has been performed at 293 and 100 K for the structural characterization of the manganoan pectolite, Na(Ca 1.73 Mn 0.27 )[Si 3 O 8 (OH)] (from the pegmatite at Mt. Koashva, Khibiny alkaline massif, Kola peninsula, Russia). The data obtained are compared with other members of the pectolite – serandite, Na(Ca 2–x Mn x )[Si 3 O 8 (OH)], series. The strong asymmetric hydrogen bond observed in the other members of the series has been confirmed at 293 K (O3–O4 = 2.473(3) Å; H–O3 = 0.97(4) Å, H … O4 = 1.50(4) Å O3–H … O4 = 178(4)°). This bond exhibits strengthening (O3–O4 = 2.458(2) Å) and becomes more symmetric at 100 K (H–O3 = 1.06(4) Å, H … O4 = 1.40(4) Å, O3–H … O4 177(4)°). The data obtained for 293 K confirm the previously hinted tendency: the higher the content of Mn, the more asymmetric the H-bond. The influence of the asymmetric position of the H-bond on the environment close to the bonded O3 and O4 atoms and the H–Na interaction are discussed. The alternative topological role of the hydrogen bond is considered in comparison to a similar structure Li 2 Mg 2 [Si 4 O 11 ]. |
format |
Article in Journal/Newspaper |
author |
Arakcheeva, Alla Pattison, Philip Meisser, Nicolas Chapuis, Gervais Pekov, Igor V. Thélin, Philippe |
author_facet |
Arakcheeva, Alla Pattison, Philip Meisser, Nicolas Chapuis, Gervais Pekov, Igor V. Thélin, Philippe |
author_sort |
Arakcheeva, Alla |
title |
New insight into the pectolite – serandite series: a single crystal diffraction study of Na(Ca 1.73 Mn 0.27 )[HSi 3 O 9 ] at 293 and 100 K |
title_short |
New insight into the pectolite – serandite series: a single crystal diffraction study of Na(Ca 1.73 Mn 0.27 )[HSi 3 O 9 ] at 293 and 100 K |
title_full |
New insight into the pectolite – serandite series: a single crystal diffraction study of Na(Ca 1.73 Mn 0.27 )[HSi 3 O 9 ] at 293 and 100 K |
title_fullStr |
New insight into the pectolite – serandite series: a single crystal diffraction study of Na(Ca 1.73 Mn 0.27 )[HSi 3 O 9 ] at 293 and 100 K |
title_full_unstemmed |
New insight into the pectolite – serandite series: a single crystal diffraction study of Na(Ca 1.73 Mn 0.27 )[HSi 3 O 9 ] at 293 and 100 K |
title_sort |
new insight into the pectolite – serandite series: a single crystal diffraction study of na(ca 1.73 mn 0.27 )[hsi 3 o 9 ] at 293 and 100 k |
publisher |
Walter de Gruyter GmbH |
publishDate |
2007 |
url |
http://dx.doi.org/10.1524/zkri.2007.222.12.696 https://www.degruyter.com/document/doi/10.1524/zkri.2007.222.12.696/xml https://www.degruyter.com/document/doi/10.1524/zkri.2007.222.12.696/pdf |
long_lat |
ENVELOPE(33.210,33.210,67.679,67.679) ENVELOPE(34.082,34.082,67.656,67.656) |
geographic |
Kola Peninsula Khibiny Koashva |
geographic_facet |
Kola Peninsula Khibiny Koashva |
genre |
kola peninsula |
genre_facet |
kola peninsula |
op_source |
Zeitschrift für Kristallographie - Crystalline Materials volume 222, issue 12, page 696-704 ISSN 2196-7105 2194-4946 |
op_doi |
https://doi.org/10.1524/zkri.2007.222.12.696 |
container_title |
Zeitschrift für Kristallographie - Crystalline Materials |
container_volume |
222 |
container_issue |
12 |
container_start_page |
696 |
op_container_end_page |
704 |
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1766059401479716864 |