Three Theorems for the Spectroscopic -Kinetic Analysis of Chemical Reactions
Abstract The results obtained in the last 25-30 years for the spectroscopic-kinetic analysis of reaction systems using absorbance (A) diagrams and the method of formal integration are summarised in three theorems. Theorem 1: A reaction mechanism can be experimentally disproved but not proved. Theore...
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Walter de Gruyter GmbH
1995
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crdegruyter:10.1515/zna-1995-1109 2023-05-15T15:52:39+02:00 Three Theorems for the Spectroscopic -Kinetic Analysis of Chemical Reactions Mauser, H. Polster, J. 1995 http://dx.doi.org/10.1515/zna-1995-1109 https://www.degruyter.com/view/journals/zna/50/11/article-p1031.xml https://www.degruyter.com/document/doi/10.1515/zna-1995-1109/xml https://www.degruyter.com/document/doi/10.1515/zna-1995-1109/pdf en eng Walter de Gruyter GmbH http://creativecommons.org/licenses/by-nc-nd/3.0/ CC-BY-NC-ND Zeitschrift für Naturforschung A volume 50, issue 11, page 1031-1040 ISSN 1865-7109 0932-0784 Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics journal-article 1995 crdegruyter https://doi.org/10.1515/zna-1995-1109 2022-04-14T05:03:46Z Abstract The results obtained in the last 25-30 years for the spectroscopic-kinetic analysis of reaction systems using absorbance (A) diagrams and the method of formal integration are summarised in three theorems. Theorem 1: A reaction mechanism can be experimentally disproved but not proved. Theorem 2: Two strictly linear reaction systems having the same number of linearly independent reaction steps can not be distinguished from each other by purely spectroscopic means. Theorem 3: Thermally controlled reaction systems which consist of two linearly independent reaction steps -one step of which is at least a reaction of second order -can not be distinguished from each other by purely spectroscopic means if their eigenvalues have the same functional dependence on the initial concentrations. The advantages of the formalism presented are demonstrated using the photoreduction of anthraquinone-2-carbonic acid in alkaline methanolic solution. Article in Journal/Newspaper Carbonic acid De Gruyter (via Crossref) Zeitschrift für Naturforschung A 50 11 1031 1040 |
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Open Polar |
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De Gruyter (via Crossref) |
op_collection_id |
crdegruyter |
language |
English |
topic |
Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
spellingShingle |
Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics Mauser, H. Polster, J. Three Theorems for the Spectroscopic -Kinetic Analysis of Chemical Reactions |
topic_facet |
Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
description |
Abstract The results obtained in the last 25-30 years for the spectroscopic-kinetic analysis of reaction systems using absorbance (A) diagrams and the method of formal integration are summarised in three theorems. Theorem 1: A reaction mechanism can be experimentally disproved but not proved. Theorem 2: Two strictly linear reaction systems having the same number of linearly independent reaction steps can not be distinguished from each other by purely spectroscopic means. Theorem 3: Thermally controlled reaction systems which consist of two linearly independent reaction steps -one step of which is at least a reaction of second order -can not be distinguished from each other by purely spectroscopic means if their eigenvalues have the same functional dependence on the initial concentrations. The advantages of the formalism presented are demonstrated using the photoreduction of anthraquinone-2-carbonic acid in alkaline methanolic solution. |
format |
Article in Journal/Newspaper |
author |
Mauser, H. Polster, J. |
author_facet |
Mauser, H. Polster, J. |
author_sort |
Mauser, H. |
title |
Three Theorems for the Spectroscopic -Kinetic Analysis of Chemical Reactions |
title_short |
Three Theorems for the Spectroscopic -Kinetic Analysis of Chemical Reactions |
title_full |
Three Theorems for the Spectroscopic -Kinetic Analysis of Chemical Reactions |
title_fullStr |
Three Theorems for the Spectroscopic -Kinetic Analysis of Chemical Reactions |
title_full_unstemmed |
Three Theorems for the Spectroscopic -Kinetic Analysis of Chemical Reactions |
title_sort |
three theorems for the spectroscopic -kinetic analysis of chemical reactions |
publisher |
Walter de Gruyter GmbH |
publishDate |
1995 |
url |
http://dx.doi.org/10.1515/zna-1995-1109 https://www.degruyter.com/view/journals/zna/50/11/article-p1031.xml https://www.degruyter.com/document/doi/10.1515/zna-1995-1109/xml https://www.degruyter.com/document/doi/10.1515/zna-1995-1109/pdf |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Zeitschrift für Naturforschung A volume 50, issue 11, page 1031-1040 ISSN 1865-7109 0932-0784 |
op_rights |
http://creativecommons.org/licenses/by-nc-nd/3.0/ |
op_rightsnorm |
CC-BY-NC-ND |
op_doi |
https://doi.org/10.1515/zna-1995-1109 |
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Zeitschrift für Naturforschung A |
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50 |
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11 |
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1031 |
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1040 |
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1766387770911096832 |