The crystal structure of hibbingite, orthorhombic Fe 2 Cl(OH) 3
Abstract The crystal structure of hibbingite, natural γ-Fe 2+ 2 Cl(OH) 3 , a mineral of the atacamite group, was studied on a sample from the Oktyabr’sky mine, Norilsk district, Siberia, Russia. The structure was solved by direct methods based on single crystal X-ray diffraction data and refined to...
Published in: | Zeitschrift für Kristallographie - Crystalline Materials |
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2019
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Online Access: | http://dx.doi.org/10.1515/zkri-2018-2124 http://www.degruyter.com/view/j/zkri.2019.234.issue-6/zkri-2018-2124/zkri-2018-2124.xml https://www.degruyter.com/document/doi/10.1515/zkri-2018-2124/xml https://www.degruyter.com/document/doi/10.1515/zkri-2018-2124/pdf |
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crdegruyter:10.1515/zkri-2018-2124 2024-05-12T08:07:23+00:00 The crystal structure of hibbingite, orthorhombic Fe 2 Cl(OH) 3 Zubkova, Natalia V. Pekov, Igor V. Sereda, Evgeny V. Yapaskurt, Vasiliy O. Pushcharovsky, Dmitry Yu. Russian Science Foundation 2019 http://dx.doi.org/10.1515/zkri-2018-2124 http://www.degruyter.com/view/j/zkri.2019.234.issue-6/zkri-2018-2124/zkri-2018-2124.xml https://www.degruyter.com/document/doi/10.1515/zkri-2018-2124/xml https://www.degruyter.com/document/doi/10.1515/zkri-2018-2124/pdf en eng Walter de Gruyter GmbH Zeitschrift für Kristallographie - Crystalline Materials volume 234, issue 6, page 379-382 ISSN 2196-7105 2194-4946 Inorganic Chemistry Condensed Matter Physics General Materials Science journal-article 2019 crdegruyter https://doi.org/10.1515/zkri-2018-2124 2024-04-18T06:55:49Z Abstract The crystal structure of hibbingite, natural γ-Fe 2+ 2 Cl(OH) 3 , a mineral of the atacamite group, was studied on a sample from the Oktyabr’sky mine, Norilsk district, Siberia, Russia. The structure was solved by direct methods based on single crystal X-ray diffraction data and refined to R =2.07% [520 reflections with I >2σ( I )]. The mineral is isostructural with atacamite and is orthorhombic, Pnma , a =6.3373(2), b =6.9892(2), c =9.3457(3) Å, V =413.95(3) Å 3 , Z =4. The structure contains Fe(1)(OH) 4 Cl 2 octahedra which share Cl–O(1) edges to form chains running along the b axis and cross-linked by the chains of Fe(2)(OH) 5 Cl octahedra sharing O(2)–O(2) edges and running along the a axis. Article in Journal/Newspaper norilsk Siberia De Gruyter Norilsk ENVELOPE(88.203,88.203,69.354,69.354) Zeitschrift für Kristallographie - Crystalline Materials 234 6 379 382 |
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De Gruyter |
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crdegruyter |
language |
English |
topic |
Inorganic Chemistry Condensed Matter Physics General Materials Science |
spellingShingle |
Inorganic Chemistry Condensed Matter Physics General Materials Science Zubkova, Natalia V. Pekov, Igor V. Sereda, Evgeny V. Yapaskurt, Vasiliy O. Pushcharovsky, Dmitry Yu. The crystal structure of hibbingite, orthorhombic Fe 2 Cl(OH) 3 |
topic_facet |
Inorganic Chemistry Condensed Matter Physics General Materials Science |
description |
Abstract The crystal structure of hibbingite, natural γ-Fe 2+ 2 Cl(OH) 3 , a mineral of the atacamite group, was studied on a sample from the Oktyabr’sky mine, Norilsk district, Siberia, Russia. The structure was solved by direct methods based on single crystal X-ray diffraction data and refined to R =2.07% [520 reflections with I >2σ( I )]. The mineral is isostructural with atacamite and is orthorhombic, Pnma , a =6.3373(2), b =6.9892(2), c =9.3457(3) Å, V =413.95(3) Å 3 , Z =4. The structure contains Fe(1)(OH) 4 Cl 2 octahedra which share Cl–O(1) edges to form chains running along the b axis and cross-linked by the chains of Fe(2)(OH) 5 Cl octahedra sharing O(2)–O(2) edges and running along the a axis. |
author2 |
Russian Science Foundation |
format |
Article in Journal/Newspaper |
author |
Zubkova, Natalia V. Pekov, Igor V. Sereda, Evgeny V. Yapaskurt, Vasiliy O. Pushcharovsky, Dmitry Yu. |
author_facet |
Zubkova, Natalia V. Pekov, Igor V. Sereda, Evgeny V. Yapaskurt, Vasiliy O. Pushcharovsky, Dmitry Yu. |
author_sort |
Zubkova, Natalia V. |
title |
The crystal structure of hibbingite, orthorhombic Fe 2 Cl(OH) 3 |
title_short |
The crystal structure of hibbingite, orthorhombic Fe 2 Cl(OH) 3 |
title_full |
The crystal structure of hibbingite, orthorhombic Fe 2 Cl(OH) 3 |
title_fullStr |
The crystal structure of hibbingite, orthorhombic Fe 2 Cl(OH) 3 |
title_full_unstemmed |
The crystal structure of hibbingite, orthorhombic Fe 2 Cl(OH) 3 |
title_sort |
crystal structure of hibbingite, orthorhombic fe 2 cl(oh) 3 |
publisher |
Walter de Gruyter GmbH |
publishDate |
2019 |
url |
http://dx.doi.org/10.1515/zkri-2018-2124 http://www.degruyter.com/view/j/zkri.2019.234.issue-6/zkri-2018-2124/zkri-2018-2124.xml https://www.degruyter.com/document/doi/10.1515/zkri-2018-2124/xml https://www.degruyter.com/document/doi/10.1515/zkri-2018-2124/pdf |
long_lat |
ENVELOPE(88.203,88.203,69.354,69.354) |
geographic |
Norilsk |
geographic_facet |
Norilsk |
genre |
norilsk Siberia |
genre_facet |
norilsk Siberia |
op_source |
Zeitschrift für Kristallographie - Crystalline Materials volume 234, issue 6, page 379-382 ISSN 2196-7105 2194-4946 |
op_doi |
https://doi.org/10.1515/zkri-2018-2124 |
container_title |
Zeitschrift für Kristallographie - Crystalline Materials |
container_volume |
234 |
container_issue |
6 |
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379 |
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382 |
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1798850048075759616 |