Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters
Abstract A novel full bio-based ketone-containing aliphatic polyester was prepared by enzyme-catalyzed polycondensation of diethyl γ-ketopimelate (DEK) with 1,6-hexanediol (HDO) using immobilized lipase B from Candida antarctica (CALB). The influences of polymerization conditions such as temperature...
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Walter de Gruyter GmbH
2020
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Online Access: | http://dx.doi.org/10.1515/epoly-2020-0016 https://www.degruyter.com/view/journals/epoly/20/1/article-p214.xml https://www.degruyter.com/document/doi/10.1515/epoly-2020-0016/xml https://www.degruyter.com/document/doi/10.1515/epoly-2020-0016/pdf |
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crdegruyter:10.1515/epoly-2020-0016 2024-09-15T17:41:15+00:00 Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters Wu, Wan-Xia 2020 http://dx.doi.org/10.1515/epoly-2020-0016 https://www.degruyter.com/view/journals/epoly/20/1/article-p214.xml https://www.degruyter.com/document/doi/10.1515/epoly-2020-0016/xml https://www.degruyter.com/document/doi/10.1515/epoly-2020-0016/pdf en eng Walter de Gruyter GmbH http://creativecommons.org/licenses/by/4.0 e-Polymers volume 20, issue 1, page 214-225 ISSN 1618-7229 2197-4586 journal-article 2020 crdegruyter https://doi.org/10.1515/epoly-2020-0016 2024-07-15T04:11:20Z Abstract A novel full bio-based ketone-containing aliphatic polyester was prepared by enzyme-catalyzed polycondensation of diethyl γ-ketopimelate (DEK) with 1,6-hexanediol (HDO) using immobilized lipase B from Candida antarctica (CALB). The influences of polymerization conditions such as temperature, time, enzyme amount, and solvent amount on the molecular weight of poly(hexamethylene γ-ketopimelate) (PHK) were investigated. New fully bio-based poly(hexamethylene γ-ketopimelate- co -hexamethylene adipate) (poly(HK- co -HA)) copolymers with narrow polydispersity and well-defined composition were synthesized by copolymerization of DEK, HDO, and diethyl adipate. The structures of PHK and poly(HK- co -HA) copolymers were characterized by nuclear magnetic resonance, and their thermal characterization was examined by thermogravimetric analysis and differential scanning calorimetry. The degradation of PHK and poly(HK- co -HA) copolymers was studied. The post-polymerization modification of these polyketoesters via oxime click chemistry was further demonstrated. Article in Journal/Newspaper Antarc* Antarctica De Gruyter e-Polymers 20 1 214 225 |
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Open Polar |
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De Gruyter |
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crdegruyter |
language |
English |
description |
Abstract A novel full bio-based ketone-containing aliphatic polyester was prepared by enzyme-catalyzed polycondensation of diethyl γ-ketopimelate (DEK) with 1,6-hexanediol (HDO) using immobilized lipase B from Candida antarctica (CALB). The influences of polymerization conditions such as temperature, time, enzyme amount, and solvent amount on the molecular weight of poly(hexamethylene γ-ketopimelate) (PHK) were investigated. New fully bio-based poly(hexamethylene γ-ketopimelate- co -hexamethylene adipate) (poly(HK- co -HA)) copolymers with narrow polydispersity and well-defined composition were synthesized by copolymerization of DEK, HDO, and diethyl adipate. The structures of PHK and poly(HK- co -HA) copolymers were characterized by nuclear magnetic resonance, and their thermal characterization was examined by thermogravimetric analysis and differential scanning calorimetry. The degradation of PHK and poly(HK- co -HA) copolymers was studied. The post-polymerization modification of these polyketoesters via oxime click chemistry was further demonstrated. |
format |
Article in Journal/Newspaper |
author |
Wu, Wan-Xia |
spellingShingle |
Wu, Wan-Xia Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters |
author_facet |
Wu, Wan-Xia |
author_sort |
Wu, Wan-Xia |
title |
Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters |
title_short |
Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters |
title_full |
Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters |
title_fullStr |
Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters |
title_full_unstemmed |
Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters |
title_sort |
lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters |
publisher |
Walter de Gruyter GmbH |
publishDate |
2020 |
url |
http://dx.doi.org/10.1515/epoly-2020-0016 https://www.degruyter.com/view/journals/epoly/20/1/article-p214.xml https://www.degruyter.com/document/doi/10.1515/epoly-2020-0016/xml https://www.degruyter.com/document/doi/10.1515/epoly-2020-0016/pdf |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
e-Polymers volume 20, issue 1, page 214-225 ISSN 1618-7229 2197-4586 |
op_rights |
http://creativecommons.org/licenses/by/4.0 |
op_doi |
https://doi.org/10.1515/epoly-2020-0016 |
container_title |
e-Polymers |
container_volume |
20 |
container_issue |
1 |
container_start_page |
214 |
op_container_end_page |
225 |
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1810487389421830144 |