Concentrations of trace elements in recent and preindustrial sediments from Norwegian and Russian Arctic lakes

• Published in: Canadian Journal of Fisheries and Aquatic Sciences
• Main Authors: Rognerud, Sigurd, Skotvold, Trond, Fjeld, Eirik, Norton, Stephen A, Hobæk, Anders
• Format: Article in Journal/Newspaper
• Language: English
• Published: Canadian Science Publishing 1998
• Subjects: Aquatic Science; Ecology, Evolution, Behavior and Systematics; Arctic; Svalbard
• Online Access: http://dx.doi.org/10.1139/f98-026; http://www.nrcresearchpress.com/doi/pdf/10.1139/f98-026

Cu, Hg, Ni, Pb, Se, and Zn concentrations in surface and preindustrial freshwater sediments from 66 lakes in the Norwegian and Russian Arctic were used for studying modern atmospheric deposition of these elements. Statistical analysis showed that, after adjusting for the effects of scavenging factors in sediments (organic matter, Al, and Fe), there were, in general, significantly higher concentrations of Hg and Pb in surface sediments than preindustrial sediments. The differences decreased with increasing latitude and increasing longitude to the east, and in the lakes from arctic islands of Svalbard and along the the arctic coastline of Russia, only Hg concentrations were elevated in surface sediments. We attribute this pattern to modern anthropogenic atmospheric deposition. There were no such differences or regional gradients for the other trace metals. A multivariate analysis of the sediment data showed that Hg and Se were associated with organic matter, whereas Cu, Ni, and Zn were associated with inorganic matter (Al, Fe). There was a shift in Pb association from inorganic matter in the reference sediment to organic matter in the surface sediment, which we interpret as an historic change in importance of sources (from bedrock-derived to atmospheric deposition).