Sources of sulphur for the Proterozoic Kiggavik uranium deposit, Nunavut, Canada

• Published in: Canadian Journal of Earth Sciences
• Main Authors: Shabaga, Brandi M., Fayek, Mostafa, Quirt, David, Ledru, Patrick
• Format: Article in Journal/Newspaper
• Language: English
• Published: Canadian Science Publishing 2020
• Subjects: General Earth and Planetary Sciences; Nunavut; Canada
• Online Access: http://dx.doi.org/10.1139/cjes-2018-0318; https://cdnsciencepub.com/doi/full-xml/10.1139/cjes-2018-0318; https://cdnsciencepub.com/doi/pdf/10.1139/cjes-2018-0318

The Thelon Basin is temporally and spatially related to the Athabasca Basin in Saskatchewan, Canada, which hosts the highest-grade unconformity-related uranium deposits in the world. Several uranium deposits occur within the Aberdeen sub-basin of the Thelon Basin, and it has been suggested that they may also be unconformity-related deposits. However, the genesis of the deposits is still debated and the age of the uranium mineralization event remains loosely constrained. In this study, we use secondary ion mass spectrometry to measure three sulphur (S) isotopes in pyrite from the Kiggavik deposit to constrain the sources of sulphur. We use this information to determine whether these sulphides, if dated by the Re–Os method, would provide a better constraint on the timing of uranium mineralization. The Kiggavik deposit comprises three zones (Main, Centre, and East) that formed from ∼200 °C fluids at ∼1600 Ma. Non-hydrothermal pyrite and galena from all three zones have a wide range of δ 34 S values, from −41.2‰ to +37.4‰. The Δ 33 S values (>0‰) indicate recycling of mass independent fractionation sulphur, suggesting that pyrite from the Kiggavik deposit derived sulphur from the Neoarchean metagraywacke host rock. The preservation of these anomalous Δ 33 S values suggests that the pyrite formed from low-temperature processes rather than hydrothermal processes. Low-temperature, high-latitude fluids may have been involved in the formation of the pyrite because some of these sulphides are also associated with uranium minerals that are devoid of Pb and contain corroded calcite. Based on these data, Re–Os geochronology of these sulphides would not yield an age that would constrain the timing of hydrothermal uranium mineralization.