XXIV.— On certain Products of Decomposition of the Fixed Oils in contact with Sulphur

• Published in: Transactions of the Royal Society of Edinburgh
• Main Author: Anderson, Thomas
• Format: Article in Journal/Newspaper
• Language: English
• Published: Cambridge University Press (CUP) 1847
• Subjects: General Earth and Planetary Sciences; General Environmental Science; Carbonic acid
• Online Access: http://dx.doi.org/10.1017/s0080456800022353; https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0080456800022353

Numerous researches have established as a general rule that the products of the decomposition of organic substances vary with the circumstances of the experiment, and the nature of the agents under the influence of which it is performed. If, for instance, we examine the action of heat alone, we find it causing a set of decompositions specially characterised by the evolution of carbonic acid, formed by the union of part of the carbon of the substance with the whole or part of its oxygen; and this action is rendered more definite, and the number of the products circumscribed by all circumstances facilitating the formation of carbonic acid, such as the presence of a base, which will even cause its evolution when heat alone is incapable of producing decomposition. Acids, on the other hand, have a precisely opposite effect, they, in some instances, altogether prevent the formation of carbonic acid, and cause the oxygen to exert its action on the hydrogen of the compound, and to eliminate one or more atoms of water which do not generally exist ready formed in it.